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41.
A method to prepare 1H-indole-2-carbaldehydes and (E)-2-(iodomethylene)indolin-3-ols by gold(I)-catalyzed cycloisomerization of 1-(2-(tosylamino)phenyl)prop-2-yn-1-ols with N-iodosuccinimide (NIS) is reported. The reactions were shown to be operationally simplistic and proceed efficiently for a wide variety of substrates, affording the corresponding products in good to excellent yields (70-99%). The mechanism is suggested to involve activation of the alkyne moiety of the substrate by the gold(I) catalyst. This triggers intramolecular addition of the tethered aniline moiety to give a vinyl gold intermediate, which undergoes iododeauration with NIS to give the (E)-2-(iodomethylene)indolin-3-ol adduct. Subsequent 1,3-allylic alcohol isomerization (1,3-AAI) followed by formylation of this vinyl iodide intermediate then gives the 1H-indole-2-carbaldehyde. 相似文献
42.
Pathik Sahoo Dr. D. Krishna Kumar Dr. Srinivasa R. Raghavan Dr. Parthasarathi Dastidar 《化学:亚洲杂志》2011,6(4):1038-1047
Easy access to a class of chiral gelators has been achieved by exploiting primary ammonium monocarboxylate ( PAM ), a supramolecular synthon. A combinatorial library comprising of 16 salts, derived from 5 l ‐amino acid methyl esters and 4 cinnamic acid derivatives, has been prepared and scanned for gelation. Remarkably, 14 out of 16 salts prepared (87.5 % of the salts) show moderate to good gelation abilities with various solvents, including commercial fuels, such as petrol. Anti‐solvent induced instant gelation at room temperature has been achieved in all the gelator salts, indicating that the gelation process is indeed an aborted crystallization phenomenon. Rheology, optical and scanning electron microscopy, small angle neutron scattering, and X‐ray powder diffraction have been used to characterize the gels. A structure‐property correlation has been attempted, based on these data, in addition to the single‐crystal structures of 5 gelator salts. Analysis of the FT‐IR and 1H NMR spectroscopy data reveals that some of these salts can be used as supramolecular containers for the slow release of certain pest sex pheromones. The present study clearly demonstrates the merit of crystal engineering and the supramolecular synthon approach in designing new materials with multiple properties. 相似文献
43.
Mild-slope (MS) type equations are depth-integrated models, which predict under appropriate conditions refraction and diffraction of linear time-harmonic water waves. By using a streamfunction formulation instead of a velocity potential one, the complementary mild-slope equation (CMSE) was shown to give better agreement with exact linear theory compared to other MS-type equations. The main goal of this work is to extend the CMSE model for solving two-layer flow with a free-surface. In order to allow for an exact reference, an analytical solution for a two-layer fluid over a sloping plane beach is derived. This analytical solution is used for validating the results of the approximated MS-type models. It is found that the two-layer CMSE model performs better than the potential based one. In addition, the new model is used for investigating the scattering of linear surface water waves and interfacial ones over variable bathymetry. 相似文献
44.
ZnO-ZnF2-B2O3 glasses containing small concentrations of TiO2 ranging from 0 to 0.6 mol% were prepared. Dielectric properties (constant ε′, loss tan δ, ac conductivity σac over a moderately wide range of frequency and temperature at room temperature in air medium) of these glasses have been studied. The results of these studies were analyzed with the aid of data on optical absorption, ESR and IR spectra of these glasses. The analysis suggests that when the concentration of TiO2>0.2 mol%, the titanium ions, in addition to Ti4+ state, co-exist in Ti3+ state, act as modifiers and reduce the breakdown strength. 相似文献
45.
A facile synthesis of 2,3-disubstituted-6-arylpyridines from enaminones using montmorillonite K10 as solid acid support is reported herein. 相似文献
46.
A. Gulyani R. Srinivasa Gopalan G. U. Kulkarni S. Bhattacharya 《Journal of Molecular Structure》2002,616(1-3)
9-Anthryl and 1-pyrenyl terpyridines (1 and 2, respectively), key precursors for the design of novel fluorescent sensors have been synthesized and characterized by 1H NMR, mass spectroscopy and X-ray crystallography. Twisted molecular conformations for each 1 and 2 were observed in their single crystal structures. Energy minimization calculations for the 1 and 2 using the semi-empirical AM1 method show that the ‘twisted’ conformation is intrinsic to these systems. We observe interconnected networks of edge-to-face CHπ interactions, which appear to be cooperative in nature, in each of the crystal structures. The two twisted molecules, although having differently shaped polyaromatic hydrocarbon substituents, show similar patterns of edge-to-face CHπ interactions.The presently described systems comprise of two aromatic surfaces that are almost orthogonal to each other. This twisted or orthogonal nature of the molecules leads to the formation of interesting multi-directional ladder like supramolecular organizations. A combination of edge-to-face and face-to-face packing modes helps to stabilize these motifs. The ladder like architecture in 1 is helical in nature. 相似文献
47.
M. Srinivasa Reddy 《Journal of Physics and Chemistry of Solids》2006,67(4):789-795
ZnO-Sb2O3-B2O3 glasses containing different concentrations of MnO ranging from 0 to 1.0 mol% were prepared. A number of studies, viz. optical absorption, infrared and ESR spectra and magnetic susceptibility, were carried out as a function of manganese ion concentration. The analysis of the results indicate that manganese ions mostly exist in Mn2+ state in these glasses when the concentration of MnO≤0.6 mol% and above this concentration, these ions seem to exist in Mn3+ state in the glass network. 相似文献
48.
V. Srinivasa Rao A. B. Samui 《Journal of polymer science. Part A, Polymer chemistry》2008,46(2):552-563
A series of photoactive liquid crystalline linear and hyperbranched polyester epoxies were synthesized by polyaddition of photoactive bis benzylidene alkanone diol monomers and terephthalic acid and trimesic acid respectively with good yield. The effect of molecular architecture (linear and hyperbranched), size of mesogenic unit (cyclic and acyclic units) on the physicochemical, thermal, mesogenic, and photoactive properties of hyperbranched polymers were studied and compared. Degree of branching of hyperbranched polymers was found to be in the range of 0.46–0.49. Monomers containing cyclic moieties only exhibited nematic mesophase, while all polymers exhibited typical nematic mesophase. Intermolecular photo cycloaddition reaction was studied by ultraviolet–visible spectra (UV–vis) and NMR spectroscopy and photo viscosity measurement of UV irradiated polymer solutions. Faster photo induced behavior of hyperbranched polymers containing acyclic alkanone moiety, as compared to polymers containing cycloalkanone moieties, was observed. The change in the refractive index was found to be in the range of 0.02–0.024. Substantial variation of refractive index indicates that this polymer could be used for optical recording. All the polymers were also found to be fluorescent in nature. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 552–563, 2008 相似文献
49.
V. Srinivasa Rao A. B. Samui 《Journal of polymer science. Part A, Polymer chemistry》2008,46(23):7637-7655
A series of photoactive liquid crystalline polyester epoxies incorporating bisbenzylidene segments as photoactive mesogenic cores were synthesized by polyaddition of diepoxy monomers and terephthalic acid/trimesic acid. To investigate the influence of structural parameters such as, molecular architecture, structural rigidity of mesogenic unit and substituents on thermal, mesogenic, and photoactive properties, the bisbenzylidene segment was incorporated into one acyclic and two cycloalkanone units with two and four substituents, respectively in both linear and hyperbranched architectures. Degree of branching of hyperbranched polymers was found to be in the range of 0.49–0.62. All polymers exhibited nematic mesophase (nematic droplets). Photo induced (2π + 2π) cycloaddition reaction, upon exposure to light at 365 nm, was examined. Inter molecular photocycloaddition was confirmed by photoviscosity measurement of UV irradiated polymer solutions. Faster photo induced reactivity of polymers in hyperbranched architecture was observed when compared to linear structure. Acyclic units facilitated photocycloaddition, and five‐membered ring showed higher photoactivity compared to six‐membered ring. The steric hindrance caused by substituents decreased the photoactivity of polymers. Refractive index change was found to be in the range of 0.015–0.024. Substantial variation of refractive index indicates that these polymers could be used for optical recording. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 7637–7655, 2008 相似文献
50.
With a view to study the pre-equilibrium effects in neutron-induced reactions, the activation cross-sections for (n, 2n) reactions at 14.2±0.2 MeV in the heavy mass region have been measured using the versatile mixed powder technique and high
resolution Ge(Li) detection. The experimental cross-sections are found to be consistently smaller than the predictions based
on the statistical theory and this is attributed to the effect of pre-equilibrium decay in these reactions. The cross-sections
due to pre-equilibrium decay were estimated using exciton, hybrid and unified models. When this cross-section was included
in comparing the experimental cross-sections with theory, we obtained better agreement, within the limitations of the present-day
preequilibrium theories.
Preliminary results of this work were reported at the Nuclear Physics and Solid State Physics Symposium, Pune (1978). 相似文献