Ring expansion of sulfur substituted p-quinamines: regiospecific synthesis of 4-aminotropones

Synthesis of 4-aminotropones through a cyclization-ring expansion process occurs in a single step and with excellent yields from 4-amino-2,5-cyclohexadienones (p-quinamines) bearing a 4-sulfinyl or sulfonyl methyl group.     

Extended mean spherical approximation for electrolyte solutions

The range of applicability of the mean spherical approximation to a primitive-model electrolyte is extended to allow for stronger Coulomb coupling. The new terms in the approximation are extracted from the HNC formalism, which is adequate for strongly coupled Coulomb systems. The new approximation satisfies the Stillinger-Lovett conditions. The new integral equation thus obtained is presented.     

Electrical resistivity of heusler alloys

The electrical resistivity of eight different Heusler alloys is discussed in terms of electron phonon and spin-disorder scattering. The systematics common to the alloys can be explained in the intermediate to high temperature range while the low temperature range still presents interpretation difficulties.     

Spectrophotometric determination of saccharin in different materials by a solvent extraction method using Nile Blue as reagent

In a slightly acidic medium (sodium acetate-acetic acid buffer, pH 4) saccharin and Nile Blue form an ion-association compound which is extractable into methyl isobutyl ketone and allows the spectrophotometric determination of saccharin. At 630 nm Beer's law is obeyed over the saccharin concentration range 0.1-3.5 microg/ml in the aqueous phase and the apparent molar absorptivity is 5.8 x 10(4) l.mole(-1).cm(-1). The method shows good selectivity and can be applied to the determination of saccharin in artificial sweeteners, soft drinks and toothpastes.     

Les séries de multipôles des physiciens et la théorie des ultradistributions

Sans résuméÀ MonsieurGottfried Köthe, à l'occasion de son 60^me anniversaire     

Precipitation chromatography fractionation: The effect of the ratio support weight/sample size

The effect of the gravimetric ratio, packing beads/polymer (r), in the chromatographic fractionation of polystyrene has been studied. Anionic polystyrene of bimodal molecular weight distribution was fractionated in three experiments with r values of 25, 50 and 130; a value of about 50 provided the most efficient separation. A GPC self-consistency analysis of this fractionation has been done with very satisfactory results. On the other hand, GPC analysis could not show any significant broadening of the molecular weight distributions of the fractions in going from r values of 130 down to 25.     

A stochastic system with MMPP input and an access function

In classical studies of loss systems with restricted availability, the utilization was suggested of a probabilistic loss function, defining the conditional probability of an incoming call being rejected, as a function of the number of occupations in the destination group of servers. This paper gives an exact analysis of stochastic processes of practical relevance, associated with a system with MMPP (Markov Modulated Poisson Process) input, finite queueing capacity and a general loss function, assuming exponential service times. In addition to the process defining the state of the system at any instant, the analysis of the overflow point process (associated with the rejected arriving customers), the accepted point process (associated with the accepted arriving customers), and of the departure process will be presented. Together with the exact analysis of this system, based on the matrix analytical methodology of Neuts, (1981), we will derive expressions for calculating some key-parameters of pertinent associated processes, which may also be used for their approximate modelling. Also, examples of applications and of blocking probability calculations in specific models of this class will be presented.