Photocatalytic degradation of benzothiophene by a novel photocatalyst,removal of decomposition fragments by MCM-41 sorbent

Research on Chemical Intermediates - In this study, a catalyst was synthesized by introduction of ZnO onto the surface of FSM-16 catalyst support (ZnO/FSM-16). Impregnation of catalyst support by...     

Asymptotic Behavior of Eigenvalues of Variance-Covariance Matrix of a High-Dimensional Heavy-Tailed Lévy Process

Methodology and Computing in Applied Probability - In this paper, we study the limiting behavior of eigenvalues of the variance-covariance matrix of a random sample from a multivariate subordinator...     

Neurological and neurobehavioral assessment of experimental subarachnoid hemorrhage

About 50% of humans with aneurysmal subarachnoid hemorrhage (SAH) die and many survivors have neurological and neurobehavioral dysfunction. Animal studies usually focused on cerebral vasospasm and sometimes neuronal injury. The difference in endpoints may contribute to lack of translation of treatments effective in animals to humans. We reviewed prior animal studies of SAH to determine what neurological and neurobehavioral endpoints had been used, whether they differentiated between appropriate controls and animals with SAH, whether treatment effects were reported and whether they correlated with vasospasm. Only a few studies in rats examined learning and memory. It is concluded that more studies are needed to fully characterize neurobehavioral performance in animals with SAH and assess effects of treatment.     

Lump and mixed rogue-soliton solutions to the 2+1 dimensional Ablowitz-Kaup-Newell-Segur equation

In this paper, the 2+1 dimensional Ablowitz-Kaup-Newell-Segur (AKNS) equation which obtained from the potential Boiti-Leon-Manna-Pempi nelli (pBLMP) equation, is introduced. Through the bilinear method and ansatz technique, the rational solutions consisting of rogue wave and lump soliton solutions are constructed, where we discuss the condition of guaranteeing the positiveness and analyticity of the lump solutions. The collection of a quadratic function with an exponential function describing rational-exponential solutions is proved, the interaction consisting of one lump and one soliton with fission and fusion phenomena. The second kind of interaction comprises the line rogue wave and soliton solution, which is inelastic. With the usage of the extended homoclinic test approach, the homoclinic breather-wave solution is derived. The characteristics of these various solutions are exhibited and illustrated graphically.     

Including sustainability criteria into inventory models

Research on sustainability performance has considerably enriched operations management literature in recent years. However, work with quantitative models is still scarce. This paper contributes by revisiting classical inventory methods taking sustainability concerns into account. We believe that reducing all aspects of sustainable development to a single objective is not desirable. We thus reformulate the classical economic order quantity model as a multiobjective problem. We refer to this model as the sustainable order quantity model. Then, a multi-echelon extension of the sustainable order quantity model is studied. For both models, the set of efficient solutions (Pareto optimal solutions) is analytically characterized. These results are used to provide some insights about the effectiveness of different regulatory policies to control carbon emissions. We also use an interactive procedure that allows the decision maker to quickly identify the best option among these solutions. The proposed interactive procedure is a new combination of multi-criteria decision analysis techniques.     

The equilibrium and kinetics of intermolecular hydrogen bonding in nitroarene anion radical–alcohol system: 1,3‐dinitro‐benzene anion radical – R–OH (R═CH3–, C2H5–, (CH3)2 CH–)

To explore the possibility of hydrogen bonding of a stable anion radical with DNA – component sugar, hormones, steroid, and so on (through hydroxyl group), as a first step, the possibility of hydrogen bonding of 1,3‐dinitrobenzene anion radical (1,3‐DNB^??) with aliphatic alcohols was studied. It was found that 1,3‐DNB^?? anion radical undergoes hydrogen bonding with alcohols: methanol, ethanol, and 2‐proponal. The hydrogen‐bonding equilibrium constant K_eq and the (hydrogen‐bonding) rate constants k₂ were evaluated through the use of linear scan and cyclic voltammetry theory and techniques. The K_eq was found to be in the range of 1.4–6.0 m ^?1, whereas the rate constants k₂ were found to be in the range of 1.5–3.6 m ^?1 s^?1, depending upon the hydrogen‐bonding agent and the equation used for the calculation of the rate constants. The hydrogen‐bonding number n was found to be around 0.5 or 1.0. The implication of this study in, for example, the replication of DNA, the prevention of the formation of super oxide, and so on is discussed. Copyright © 2012 John Wiley & Sons, Ltd.     

Synthesis of KIT-5 decorated by Bi2S3-Fe3O4 photocatalyst for degradation of parathion pesticide in aqueous media: Offering a degradation model and optimization using response surface methodology (RSM)

In this research, a novel KIT-5/Bi₂S₃-Fe₃O₄ nanocomposite was prepared. The structure and morphology properties of the nanocomposite were well characterized by XRD, FESEM-EDS-mapping, TEM, and N₂ adsorption–desorption. Benefiting from the visible light, the as-prepared KIT-5/Bi₂S₃-Fe₃O₄ nanocomposite exhibit significantly improved photocatalytic performance for the degradation of parathion. The optimum photocatalytic efficiency of KIT-5/Bi₂S₃-Fe₃O₄ nanocomposite was investigated with the central composite design using Design Expert software. The four critical variables affecting parathion degradation such as the concentration of parathion, pH, irradiation time, and amount of KIT-5/Bi₂S₃-Fe₃O₄ nanocatalyst. A polynomial function corresponding to degradation percent was obtained for the experimental data. The results showed that this catalyst has a good performance for the degradation of parathion.