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31.
The first observation of the ESR spectra of Mn2+, entering substitutionally for Fe2+ in the Van Vleck paramagnet FeS2 (polycrystals), is reported. The data from 5 to 295 K fits the spin-Hamiltonian + , with g = 2.000 ± 0.001, A/β = ?95.0 ± 0.5 Oe and D/β varying from 50 Oe (5K) to 59 Oe (295 K). The temperature dependence of D can be described in terms of a single phonon-mode with frequency ? 145 cm?1. 相似文献
32.
The elastic constantsC
11,C
12 andC
44 of sodium chlorate single crystal have been evaluated using 10 MHz ultrasonic pulse echo superposition technique. The values
areC
11=4.90,C
12=1.39,C
44=1.17 (× 1010
N/m
2) at 298 K and 6.15, 2.16, 1.32 (×1010
N/m
2) at 77 K. The data agree well with the values measured earlier up to 223 K. Brief mention is also made of the low temperature
bonding problems in these soft crystals. 相似文献
33.
The elastic constants of NaBrO3 and NaClO3 are evaluated from ultrasonic velocity measurements using pulse superposition techniques. The values of C11, C12 and C44 for NaBrO3 at 298°K are 5.578, 1.705, 1.510 (x 1010 N/m2) and for NaClO3 the values are 4.897, 1.389, 1.174. The values at 77°K are respectively 6.35, 1.98 and 1.65 for NaBrO3 and 6.15, 2.16 and 1.32 for NaClO3. 相似文献
34.
Two-unit warm standby redundant systems have been investigated extensively in the past. The most general model is the one
in which both the lifetime and repair time distributions of the units are arbitrary. However the study of standby systems
with more than two units, though very important, has received much less attention, possibly because of the built-in difficulties
in analyzing them. Such systems have been studied only when either the lifetime or the repair time is exponentially distributed.
When both these distributions are general, the problem appears to be intractable even in the case of cold standby systems.
The present contribution is an improvement in the state of art in the sense that a three unit warm standby system is shown
to be capable of comprehensive analysis. In particular we show that there are imbedded renewal points that render the analysis
possible. Using these imbedded renewal points we obtain the reliability and availability functions.
Emeritus
Deceased 23rd December 2003. 相似文献
35.
A systematic method of obtaining relative signs of hyperfine coupling constants is described. It applies to systems consisting of (a) a set of one or more nuclei coupled fairly strongly to the electron spin, and possessing a two-fold (or higher) axis of symmetry, together with (b) a set of weakly coupled nuclei defining superhyperfine transitions. ENDOR measurements for several E.P.R. hyperfine transitions, with the field oriented along the symmetry axis, give relative signs of hyperfine components for this direction. Signs for the other directions can then be obtained through ENDOR measurements on a single hyperfine transition at various field orientations. Additional double ENDOR measurements may be necessary for very weakly coupled nuclei. This method can complement double ENDOR studies in favourable cases. It is illustrated by the determination of signs of coupling constants of protons and of 75As in the AsO4 4- radical in KH2AsO4. 相似文献
36.
Ashwin Vaidya Rachmadian Wulandana 《Mathematical Methods in the Applied Sciences》2006,29(13):1555-1561
In this paper, we study the non‐linear stability of convection for a Newtonian fluid heated from below, where the viscosity of the fluid depends upon temperature. We are able to show that for Rayleigh numbers below a certain critical value, Rac, the rest state of the fluid and the steady temperature distribution remains non‐linearly stable, using the calculations of Diaz and Straughan (Continuum Mech. Thermodyn. 2004; 16 :347–352). The central contribution of this paper lies in a simpler proof of non‐linear stability, than the ones in the current literature, by use of a suitable maximum principle argument. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
37.
An Abelian gauge theory describing dynamics of massive spin one bosons is constructed. This is achieved by appending to the Maxwell action, a gauge invariant mass term. The theory is quantised in temporal as well as Lorentz gauge, and the corresponding Hilbert spaces are constructed. In both the gauges, it is found that, the theory respects Lorentz invariance, locality, causality and unitarity. 相似文献
38.
R. Srinivasan Puri Denise Morrey Andrew J. Bell John F. Durodola Evgenii B. Rudnyi Jan G Korvink 《Applied Mathematical Modelling》2009
A reduced order model is developed for low frequency, undamped, fully coupled structural–acoustic analysis of interior cavities backed by flexible structural systems. The reduced order model is obtained by applying a projection of the coupled system matrices, from a higher dimensional to a lower dimensional subspace, whilst preserving essential properties of the coupled system. The basis vectors for projection are computed efficiently using the Arnoldi algorithm, which generates an orthogonal basis for the Krylov Subspace containing moments of the original system. The key idea of constructing a reduced order model via Krylov Subspaces is to remove the uncontrollable, unobservable and weakly controllable, observable parts without affecting the transfer function of the coupled system. Three computational test cases are analyzed, and the computational gains and the accuracy compared with the direct inversion method in ANSYS. 相似文献
39.
Prabu Sakthivel Lakshmana Singh Tarunveer Kumar Chellappan Dinesh Joseph Alex Srinivasan Keloth Kaitheri 《平面色谱法杂志一现代薄层色谱法》2009,22(4):277-281
JPC – Journal of Planar Chromatography – Modern TLC - A new simple, rapid, reproducible, and stability-indicatiiig highperformance thin-layer chromatographic method for analysis of... 相似文献
40.
The reflected shock tube technique with multipass absorption spectrometric detection of OH radicals at 308 nm (corresponding to a total path length of approximately 4.9 m) has been used to study the dissociation of methanol between 1591 and 2865 K. Rate constants for two product channels [CH3OH + Kr --> CH3 + OH + Kr (1) and CH3OH + Kr --> 1CH2 + H2O + Kr (2)] were determined. During the course of the study, it was necessary to determine several other rate constants that contributed to the profile fits. These include OH + CH3OH --> products, OH + (CH3)2CO --> CH2COCH3 + H2O, and OH + CH3 --> 1,3CH2 + H2O. The derived expressions, in units of cm(3) molecule(-1) s(-1), are k(1) = 9.33 x 10(-9) exp(-30857 K/T) for 1591-2287 K, k(2) = 3.27 x 10(-10) exp(-25946 K/T) for 1734-2287 K, kOH+CH3OH = 2.96 x 10-16T1.4434 exp(-57 K/T) for 210-1710 K, k(OH+(CH3)(2)CO) = (7.3 +/- 0.7) x 10(-12) for 1178-1299 K and k(OH+CH3) = (1.3 +/- 0.2) x 10(-11) for 1000-1200 K. With these values along with other well-established rate constants, a mechanism was used to obtain profile fits that agreed with experiment to within <+/-10%. The values obtained for reactions 1 and 2 are compared with earlier determinations and also with new theoretical calculations that are presented in the preceding article in this issue. These new calculations are in good agreement with the present data for both (1) and (2) and also for OH + CH3 --> products. 相似文献