Flow visualization of compressible vortex structures using density gradient techniques

Mathematical results are derived for the schlieren and shadowgraph contrast variation due to the refraction of light rays passing through two-dimensional compressible vortices with viscous cores. Both standard and small-disturbance solutions are obtained. It is shown that schlieren and shadowgraph produce substantially different contrast profiles. Further, the shadowgraph contrast variation is shown to be very sensitive to the vortex velocity profile and is also dependent on the location of the peak peripheral velocity (viscous core radius). The computed results are compared to actual contrast measurements made for rotor tip vortices using the shadowgraph flow visualization technique. The work helps to clarify the relationships between the observed contrast and the structure of vortical structures in density gradient based flow visualization experiments.Nomenclature a Unobstructed height of schlieren light source in cutoff plane, m - c Blade chord, m - f Focal length of schlieren focusing mirror, m - C _T Rotor thrust coefficient, T/( ² R ⁴) - I Image screen illumination, Lm/m ² - l Distance from vortex to shadowgraph screen, m - n _b Number of blades - p Pressure,N/m ² - p Ambient pressure, N/m ² - r, , z Cylindrical coordinate system - r _c Vortex core radius, m - Non-dimensional radial coordinate, (r/r _c ) - R Rotor radius, m - Tangential velocity, m/s - Specific heat ratio of air - Circulation (strength of vortex), m ²/s - Non-dimensional quantity, ² 8²p r _c ² - Refractive index of fluid medium - ₀ Refractive index of fluid medium at reference conditions - Gladstone-Dale constant, m ³/kg - Density, kg/m ³ - Density at ambient conditions, kg/m ³ - Non-dimensional density, (/ ) - Rotor solidity, (n _b c/ R) - Rotor rotational frequency, rad/s     

A Magneto-Mechanically Coupled Phase-Field Model at Large Deformation

The aggregate magneto-mechanical behavior of magneto-rheological elastomers (MREs) stems from the magnetic properties of the ferromagnetic inclusion and the mechanical properties of the matrix material. We propose a large deformation micro-magnetic theory, to predict the behavior and interaction of ferromagnetic particles inside an elastomeric matrix. A rate-type variational principle, with the magnetization as the order parameter is proposed. A large deformation Landau-Lifshitz-Gilbert equation for the time evolution of the magnetization, is obtained directly from the proposed variational principle. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Production of ROS by photosensitized anthracene under sunlight and UV-R at ambient environmental intensities

The aim of this study was to analyze the photostability and phototoxicity mechanism of anthracene (ANT) in a human skin epidermal cell line (HaCaT) at ambient environmental intensities of sunlight/UV‐R (UV‐A and UV‐B). Photomodification of ANT under sunlight/UV‐R exposure produced two photoproducts, anthrone and 9,10 anthracenedione. Generation of ¹O₂, O₂^?? and ^?OH was measured under UV‐R/sunlight exposure. Involvement of reactive oxygen species (ROS) was further substantiated by their quenching with free radical quenchers. Photodegradation of 2‐deoxyguanosine and linoleic acid peroxidation showed that ROS were mainly responsible for ANT phototoxicity. ANT generates significant amount of intracellular ROS in cell line. Maximum cell viability (85%) was reduced under sunlight exposure (30 min). Results of MTT assay accord NRU assay. ANT (0.01 μg mL^?1) induced cell‐cycle arrest at G1 phase. RT‐PCR demonstrated constitutive inducible mRNA expression of CYP 1A1 and 1B1 genes. Photosensitive ANT upregulates CYP 1A1 (2.2‐folds) and 1B1 (4.1‐folds) genes. Thus, the study suggests that ROS and DNA damage were mainly responsible for ANT phototoxicity. ANT exposure may be deleterious to human health at ambient environmental intensities reaching the earth’s surface through sunlight.     

Fluorescent zinc(II) complex exhibiting "on-off-on" switching toward Cu2+ and Ag+ ions

Binuclear zinc(II) and copper(II) complexes based on a new Schiff base ligand N,N'-bis(2-hydroxybenzilidene)-2,4,6-trimethylbenzene-1,3-diamine (H(2)L) have been synthesized. The ligand H(2)L and complexes under investigation have been characterized by elemental analyses, spectral (FT-IR, (1)H, (13)C NMR, ESI-MS, electronic absorption, emission), and electrochemical studies. The structures of H(2)L and complexes [{Zn(C(23)H(18)N(2)O(2))}(2)] (1) and [{Cu(C(23)H(18)N(2)O(2))}(2)]·H(2)O (2) have been determined crystallographically. Selective "On-Off-On" switching behavior of the fluorescent complex 1 has been studied. The fluorescence intensity of 1 quenches (turns-off) upon addition of Cu(2+), while enhances (turns-on) in the presence of Ag(+) ions. The mechanisms of "On-Off-On" signaling have been supported by (1)H NMR, ESI-MS, electronic absorption, and emission spectral studies. Job's plot analysis supported 1:1 and 1:2 stoichiometries for Cu(2+) and Ag(+) ions, respectively. Association and quenching constants have been estimated by the Benesi-Hildebrand method and Stern-Volmer plot. Moreover, 1 mimics a molecular keypad lock that follows correct chemical input order to give maximum output signal.     

Mössbauer studies of solid state decomposition of methyl methacrylate-ethyl methacrylate copolymers containing ferric chloride

Methyl methacrylate (MMA)-ethyl methacrylate (EMA) copolymers of different monomer concentrations containing anhydrous ferric chloride were prepared by bulk polymerization at 70°C. TGA studies showed that inclusion of iron salt increases the thermal stability of copolymers by 50°C. Mössbauer spectra of copolymers heated at different temperatures showed the presence of Fe³⁺ species only, in different environments. The mechanism of thermal stabilization of copolymer has been proposed on the basis of IR, TGA and Mössbauer spectroscopy studies.     

Energy transfer in CaSiO3 phosphors doped with Ce3+ and Tb3+

Calcium metasilicate phosphors activated by Ce³⁺ and Tb³⁺ have been studied for their emission characteristics. In two series of phosphors, one activator was kept at its optimum value while the other was varied. In another two series, one activator was kept below its optimum value and the other was varied. Concentration quenching effects start when each activator gives its maximum emission. There is clear evidence of an energy transfer from Ce³⁺ to Tb³⁺ because the⁵ D ₃ lines appear on addition of Ce³⁺ while they were conspicuously absent when Tb³⁺ alone was present. Their absence in singly activated phosphors could not have been due to cross-relaxation. Obviously X-ray excitation does not lead to⁵ D ₃ transitions which are achieved only by energy transfer. Further, considering the features of the emission spectra and the concentrations of activators used, the transfer could only be of the dipole-dipole type.     

Methyl methacrylate-n-butyl methacrylate copolymer containing ferric chloride: Mössbauer study

Methyl methacrylate /MMA/-n-butyl methacrylate /nBuMA/ copolymer containing anhydrous ferric chloride was prepared by free radical polymerization at 70 °C. TGA studies showed that the addition of ferric chloride increases the thermal stability of copolymer by 90 °C. Mössbauer studies of the copolymer were carried out to determine the oxidation state and environments of iron in the copolymer. Mössbauer studies of the copolymer heated at 150 °C, 300 °C and 500 °C for 1 h showed that during the thermal degradation, no reduction of Fe³⁺ takes place.     

Joule–Thomson inversion curves of mixtures by molecular simulation in comparison to advanced equations of state: Natural gas as an example

Molecular modelling and simulation as well as four equations of state (EOS) are applied to natural gas mixtures regarding Joule–Thomson (JT) inversion. JT inversion curves are determined by molecular simulation for six different natural gas mixtures consisting of methane, nitrogen, carbon dioxide and ethane. These components are also regarded as pure fluids, leading to a total of 10 studied systems. The results are compared to four advanced mixture EOS: DDMIX, SUPERTRAPP, BACKONE and the recent GERG-2004 Wide-Range Reference EOS. It is found that molecular simulation is competitive with state-of-the-art EOS in predicting JT inversion curves. The molecular based approaches (simulation and BACKONE) are superior to DDMIX and SUPERTRAPP.