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31.
In the present paper, we consider Mond-Weir type nondifferentiable second order fractional symmetric dual programs over arbitrary cones and derive duality results under second order K?F-convexity/K?F-pseudoconvexity assumptions. Our results generalize several known results in the literature. 相似文献
32.
We show that the velocity correlations in uniform dense granular flows inside a silo are similar to the hydrodynamic response of an elastic hard-sphere liquid. The measurements are made using a fluorescent refractive-index-matched interstitial fluid in a regime where the flow is dominated by grains in enduring contact and fluctuations scale with the distance traveled, independent of flow rate. The velocity autocorrelation function of the grains in the bulk shows a negative correlation at short time and slow oscillatory decay to zero similar to simple liquids. Weak spatial velocity correlations are observed over several grain diameters. The mean square displacements show an inflection point indicative of caging dynamics. The observed correlations are qualitatively different at the boundaries. 相似文献
33.
Flow visualization of compressible vortex structures using density gradient techniques 总被引:2,自引:0,他引:2
Mathematical results are derived for the schlieren and shadowgraph contrast variation due to the refraction of light rays passing through two-dimensional compressible vortices with viscous cores. Both standard and small-disturbance solutions are obtained. It is shown that schlieren and shadowgraph produce substantially different contrast profiles. Further, the shadowgraph contrast variation is shown to be very sensitive to the vortex velocity profile and is also dependent on the location of the peak peripheral velocity (viscous core radius). The computed results are compared to actual contrast measurements made for rotor tip vortices using the shadowgraph flow visualization technique. The work helps to clarify the relationships between the observed contrast and the structure of vortical structures in density gradient based flow visualization experiments.Nomenclature
a
Unobstructed height of schlieren light source in cutoff plane, m
-
c
Blade chord, m
-
f
Focal length of schlieren focusing mirror, m
-
C
T
Rotor thrust coefficient, T/(
2
R
4)
-
I
Image screen illumination, Lm/m
2
-
l
Distance from vortex to shadowgraph screen, m
-
n
b
Number of blades
-
p
Pressure,N/m
2
-
p
Ambient pressure, N/m
2
-
r, , z
Cylindrical coordinate system
-
r
c
Vortex core radius, m
-
Non-dimensional radial coordinate, (r/r
c
)
-
R
Rotor radius, m
-
Tangential velocity, m/s
-
Specific heat ratio of air
-
Circulation (strength of vortex), m
2/s
-
Non-dimensional quantity,
2
82p
r
c
2
-
Refractive index of fluid medium
-
0
Refractive index of fluid medium at reference conditions
-
Gladstone-Dale constant, m
3/kg
-
Density, kg/m
3
-
Density at ambient conditions, kg/m
3
-
Non-dimensional density, (/
)
-
Rotor solidity, (n
b
c/ R)
-
Rotor rotational frequency, rad/s 相似文献
34.
The aggregate magneto-mechanical behavior of magneto-rheological elastomers (MREs) stems from the magnetic properties of the ferromagnetic inclusion and the mechanical properties of the matrix material. We propose a large deformation micro-magnetic theory, to predict the behavior and interaction of ferromagnetic particles inside an elastomeric matrix. A rate-type variational principle, with the magnetization as the order parameter is proposed. A large deformation Landau-Lifshitz-Gilbert equation for the time evolution of the magnetization, is obtained directly from the proposed variational principle. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
35.
Mujtaba SF Dwivedi A Mudiam MK Ali D Yadav N Ray RS 《Photochemistry and photobiology》2011,87(5):1067-1076
The aim of this study was to analyze the photostability and phototoxicity mechanism of anthracene (ANT) in a human skin epidermal cell line (HaCaT) at ambient environmental intensities of sunlight/UV‐R (UV‐A and UV‐B). Photomodification of ANT under sunlight/UV‐R exposure produced two photoproducts, anthrone and 9,10 anthracenedione. Generation of 1O2, O2?? and ?OH was measured under UV‐R/sunlight exposure. Involvement of reactive oxygen species (ROS) was further substantiated by their quenching with free radical quenchers. Photodegradation of 2‐deoxyguanosine and linoleic acid peroxidation showed that ROS were mainly responsible for ANT phototoxicity. ANT generates significant amount of intracellular ROS in cell line. Maximum cell viability (85%) was reduced under sunlight exposure (30 min). Results of MTT assay accord NRU assay. ANT (0.01 μg mL?1) induced cell‐cycle arrest at G1 phase. RT‐PCR demonstrated constitutive inducible mRNA expression of CYP 1A1 and 1B1 genes. Photosensitive ANT upregulates CYP 1A1 (2.2‐folds) and 1B1 (4.1‐folds) genes. Thus, the study suggests that ROS and DNA damage were mainly responsible for ANT phototoxicity. ANT exposure may be deleterious to human health at ambient environmental intensities reaching the earth’s surface through sunlight. 相似文献
36.
37.
38.
Pandey R Kumar P Singh AK Shahid M Li PZ Singh SK Xu Q Misra A Pandey DS 《Inorganic chemistry》2011,50(8):3189-3197
Binuclear zinc(II) and copper(II) complexes based on a new Schiff base ligand N,N'-bis(2-hydroxybenzilidene)-2,4,6-trimethylbenzene-1,3-diamine (H(2)L) have been synthesized. The ligand H(2)L and complexes under investigation have been characterized by elemental analyses, spectral (FT-IR, (1)H, (13)C NMR, ESI-MS, electronic absorption, emission), and electrochemical studies. The structures of H(2)L and complexes [{Zn(C(23)H(18)N(2)O(2))}(2)] (1) and [{Cu(C(23)H(18)N(2)O(2))}(2)]·H(2)O (2) have been determined crystallographically. Selective "On-Off-On" switching behavior of the fluorescent complex 1 has been studied. The fluorescence intensity of 1 quenches (turns-off) upon addition of Cu(2+), while enhances (turns-on) in the presence of Ag(+) ions. The mechanisms of "On-Off-On" signaling have been supported by (1)H NMR, ESI-MS, electronic absorption, and emission spectral studies. Job's plot analysis supported 1:1 and 1:2 stoichiometries for Cu(2+) and Ag(+) ions, respectively. Association and quenching constants have been estimated by the Benesi-Hildebrand method and Stern-Volmer plot. Moreover, 1 mimics a molecular keypad lock that follows correct chemical input order to give maximum output signal. 相似文献
39.
Calcium metasilicate phosphors activated by Ce3+ and Tb3+ have been studied for their emission characteristics. In two series of phosphors, one activator was kept at its optimum value while the other was varied. In another two series, one activator was kept below its optimum value and the other was varied. Concentration quenching effects start when each activator gives its maximum emission. There is clear evidence of an energy transfer from Ce3+ to Tb3+ because the5 D 3 lines appear on addition of Ce3+ while they were conspicuously absent when Tb3+ alone was present. Their absence in singly activated phosphors could not have been due to cross-relaxation. Obviously X-ray excitation does not lead to5 D 3 transitions which are achieved only by energy transfer. Further, considering the features of the emission spectra and the concentrations of activators used, the transfer could only be of the dipole-dipole type. 相似文献
40.
Molecular modelling and simulation as well as four equations of state (EOS) are applied to natural gas mixtures regarding Joule–Thomson (JT) inversion. JT inversion curves are determined by molecular simulation for six different natural gas mixtures consisting of methane, nitrogen, carbon dioxide and ethane. These components are also regarded as pure fluids, leading to a total of 10 studied systems. The results are compared to four advanced mixture EOS: DDMIX, SUPERTRAPP, BACKONE and the recent GERG-2004 Wide-Range Reference EOS. It is found that molecular simulation is competitive with state-of-the-art EOS in predicting JT inversion curves. The molecular based approaches (simulation and BACKONE) are superior to DDMIX and SUPERTRAPP. 相似文献