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21.
Synthesis and Properties of the Layered Perovskite Phase Sr3Mo1.5Zn0.5O7‐δ The new layered perovskite phase Sr3Mo1.5Zn0.5O7‐δ was synthesized by solid state reaction using a Zn/ZnO oxygen buffer. The crystal structure was refined from X‐ray powder pattern by the Rietveld method. The compound crystallizes tetragonal in the space group I4/mmm (no. 139) with the lattice parameters a = 3.9631(3) Å, c = 20.583(1) Å. An oxygen deficiency corresponding to δ ≈ 0.25 was determinated, indicating the presence of molybdenum in mixed valence (Mo4+ and Mo6+). 相似文献
22.
Frank W. Schmidt 《Linear and Multilinear Algebra》1991,30(3):229-230
This section appears from time to time. Contributions are invited, and should be submitted to R. C. Thompson, Mathematics Department, University of California, Santa Barbara, CA 93106. 相似文献
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H. Falk R. Geerling B. Hattendorf K. Krengel-Rothensee K. P. Schmidt 《Analytical and bioanalytical chemistry》1997,359(4-5):352-356
An ICP-MS method for the determination of ultra-traces of 24 Elements (Li, Be, Mg, Al, Cr, Mn, Co, Zn, Cu, Ga, As, Se, Rb, Sr, Mo, Ag, Cd, Sn, Sb, Ba, Tl, Pb, Bi, U) at ng/L to μg/L levels in highly saline solutions (up to 30 g/L NaCl) was developed. Calculated to the salt content of the samples, limits of detection at the sub-μg/kg level were obtained. This allows the measurement of samples like sea water, or clinical samples like urine, serum and whole blood, with few or without sample preparation and a drastic improvement to the limits of detection. Compared to the determination in solutions of 1 g/L NaCl the limits of detection in the original sample were improved by one order of magnitude. Improvements in instrumental stability are achieved by the use of an additional gas, that is introduced to the aerosol stream and avoids salt deposition in the aerosol tube of the torch, the use of High Matrix Content (HMC) cones, that show no clogging even at NaCl-concentrations up to 50 g/L. With this setup the long term stability for measurements with changing matrix concentrations is < 10% without and < 5% with use of an internal standard for the individual samples. Cleaning up is necessary after 2 days of operation. The direct analysis of the Nearshore Seawater Reference Material NRC-CNRC CASS3 showed a good agreement with the certified and measured concentrations. Elements, that do not suffer from an isobaric overlap of matrix compounds can be determined clearly at ng/L levels. Measurement of different matrix concentrations showed, that acceptable results can be achieved with a single calibration for concentrations from 5 g/L NaCl to 30 g/L NaCl, though matrix matching shows the best results. 相似文献
27.
The decomposition of AlDy6Ni10 and AlDy8Ni6Co2 glasses prepared by melt spinning after different pre-aging regimes was investigated. The modelling of the transformation at the glass transition and the crystallisation was tested by a more general Johnson-Mehl-Avrami-Kolmogorov model and by the determination of the local kinetic parameter. The relaxation was tested with an lnt kinetic model after Gibbs. 相似文献
28.
D. Boilley A. Marchix B. Jurado K. -H. Schmidt 《The European Physical Journal A - Hadrons and Nuclei》2007,33(1):47-52
We propose a new formula for the saddle-to-scission time that is more general that the one based on Kramers' approach. Its
validity and applicability is then studied in detail. Such a formula is useful for the evaluation of the fission time of very
heavy nuclei. 相似文献
29.
W.G. Schmidt 《Applied Physics A: Materials Science & Processing》2002,75(1):89-99
There has been renewed interest in the structure of III-V compound semiconductor (001) surfaces caused by recent experimental
and theoretical findings, which indicate that geometries different from the seemingly well-established dimer models describe
the surface ground state for specific preparation conditions. I review briefly the structure information available on the
(001) surfaces of GaP, InP, GaAs and InAs. These data are complemented with first-principles total-energy calculations. The
calculated surface phase diagrams are used to explain the experimental data and reveal that the stability of specific surface
structures depends largely on the relative size of the surface constituents. Several structural models for the Ga-rich GaAs (001)(4×6)
surface are discussed, but dismissed on energetic grounds. I discuss in some detail the electronic properties of the recently
proposed cation-rich GaAs (001)ζ(4×2) geometry.
Received: 18 May 2001 / Revised version: 23 July 2001 / Published online: 3 April 2002 相似文献
30.
E. Casarejos P. Armbruster L. Audouin J. Benlliure M. Bernas A. Boudard R. Legrain S. Leray B. Mustapha S. Czajkowski T. Enqvist B. Fernandez J. Pereira M. Pravikoff F. Rejmund K. -H. Schmidt C. Stephan J. Taieb L. Tassan-Got C. Villagrasa C. Volant W. Wlazlo 《Physics of Atomic Nuclei》2003,66(8):1413-1420
The isotopic production cross sections of heavy residues in relativistic heavy-ion collisions have been investigated in inverse kinematics. The primary reaction products were fully identified in mass and atomic number prior to beta decay using the fragment separator FRS. The huge collection of data obtained helps in the understanding of the two main reaction mechanisms involved: fragmentation and fission. These data provide basic information for future radioactive ion beam facilities and for technical applications like intense neutron sources by means of spallation targets. 相似文献