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51.
We present the framework for convergent beam Bragg ptychography, and, using simulations, we demonstrate that nanocrystals can be ptychographically reconstructed from highly convergent x-ray Bragg diffraction. The ptychographic iterative engine is extended to three dimensions and shown to successfully reconstruct a simulated nanocrystal using overlapping raster scans with a defocused curved beam, the diameter of which matches the crystal size. This object reconstruction strategy can serve as the basis for coherent diffraction imaging experiments at coherent scanning nanoprobe x-ray sources. 相似文献
52.
Algorithms are presented which find a basis of the vector space of cuspidal cohomology of certain congruence subgroups of SL(3, ) and which determine the action of the Hecke operators on this space. These algorithms were implemented on a computer. Four pairs of cuspidal classes were found with prime level less than 100. Tables are given of the eigenvalues of the first few Hecke operators on these classes. 相似文献
53.
Christopher J. Ash 《Mathematical Logic Quarterly》1994,40(3):393-397
We give a plausible-sounding conjecture involving the number of n-equivalence classes of structures of size m which would imply that the complement of a spectrum is also a spectrum. Mathematics Subject Classification : 03B10, 03D15, 68Q15. 相似文献
54.
Chemical shift anisotropy (CSA) has been an invaluable probe of structure and dynamics for a variety of systems in NMR spectroscopy. Unfortunately, the presence of strong quadrupolar couplings has severely limited the ability to measure CSA in nuclei with spins I > 1/2. Here we show that these two interactions can be refocused at different times in a 2D multiple-quantum NMR experiment on polycrystalline samples. Combining this experiment with appropriate affine transformations allows these interactions to be cleanly separated into orthogonal dimensions. The 1D projection onto each axis can be fit to extract the respective principal tensor components. These components can then be used to fit the 2D spectrum for the relative orientation between the CSA and quadrupolar-coupling tensors. The necessary affine transformation parameters are given for all possible I values. Illustrative examples of spectra and analyses are given for 63Cu in K3[Cu(CN)4], 59Co in K3[Co(CN)6], and 87Rb in RbCrO4. 相似文献
55.
J. Marshall Ash Stefan Catoiu 《Transactions of the American Mathematical Society》2008,360(2):959-987
For , a one-parameter family of symmetric quantum derivatives is defined for each order of differentiation as are two families of Riemann symmetric quantum derivatives. For , symmetrization holds, that is, whenever the th Peano derivative exists at a point, all of these derivatives of order also exist at that point. The main result, desymmetrization, is that conversely, for , each symmetric quantum derivative is a.e. equivalent to the Peano derivative of the same order. For and , each th symmetric quantum derivative coincides with both corresponding th Riemann symmetric quantum derivatives, so, in particular, for and , both th Riemann symmetric quantum derivatives are a.e. equivalent to the Peano derivative.
56.
Catherine Paradis-Bleau Adrian Lloyd François Sanschagrin Tom Clarke Ann Blewett Timothy DH Bugg Roger C Levesque 《BMC biochemistry》2008,9(1):33
Background
To develop antibacterial agents having novel modes of action against bacterial cell wall biosynthesis, we targeted the essential MurF enzyme of the antibiotic resistant pathogen Pseudomonas aeruginosa. MurF catalyzes the formation of a peptide bond between D-Alanyl-D-Alanine (D-Ala-D-Ala) and the cell wall precursor uridine 5'-diphosphoryl N-acetylmuramoyl-L-alanyl-D-glutamyl-meso-diaminopimelic acid (UDP-MurNAc-Ala-Glu-meso-A2pm) with the concomitant hydrolysis of ATP to ADP and inorganic phosphate, yielding UDP-N-acetylmuramyl-pentapeptide. As MurF acts on a dipeptide, we exploited a phage display approach to identify peptide ligands having high binding affinities for the enzyme. 相似文献57.
Lemire SW Ash DH Johnson RC Barr JR 《Journal of the American Society for Mass Spectrometry》2007,18(8):1364-1374
Bis(2-hydroxyethylthio)alkanes and bis(2-hydroxyethylthioalkyl)ethers are important biological and environmental degradation products of sulfur mustard analogs known as sesqui- and oxy-mustards. We used atmospheric pressure chemical ionization mass spectrometry (APCI MS) to acquire characteristic spectra of these compounds in positive and negative ionization modes. Positive APCI mass spectra exhibited [M + H](+); negative APCI MS generated [M + O(2)](-), [M - H](-), and [M - 3H](-); and both positive and negative APCI mass spectra contained fragment ions due to in-source collision-induced dissociation. Product ion scans confirmed the origin of fragment ions observed in single-stage MS. Although the spectra of these compounds were very similar, positive and negative APCI mass spectra of the oxy-mustard hydrolysis product, bis(2-hydroxyethylthiomethyl)ether, differed from the spectra of the other compounds in a manner that suggested a rearrangement to the sesqui-mustard hydrolysis product, bis(2-hydroxyethylthio)methane. We evaluated the [M + O(2)](-) adduct ion for quantification via liquid chromatography-MS/MS in the multiple-reaction monitoring (MRM) mode by constructing calibration curves from three precursor/product ion transitions for all the analytes. Analytical figures of merit generated from the calibration curves indicated the stability and suitability of these transitions for quantification at concentrations in the low ng/mL range. Thus, we are the first to propose a quantitative method predicated on the measurement of product ions generated from the superoxide adduct anion of the sesqui-and oxy-mustard hydrolysis products. 相似文献
58.
59.
The paper classifies multilincnr algebras, known as comlrans algebras, that are determined by pairs of matrices and have dimensions which are less than or equal to two. The comtrans algebras are isomophic if and only if the corresponding pairs of matrices arc multiplicatively cogredient by a matrix M. 相似文献
60.
Christian G Frank N Ash S Baumann T Bazin D Brown J DeYoung PA Finck JE Gade A Grinyer GF Grovom A Hinnefeld JD Lunderberg EM Luther B Mosby M Mosby S Nagi T Peaslee GF Rogers WF Smith JK Snyder J Spyrou A Strongman MJ Thoennessen M Warren M Weisshaar D Wersal A 《Physical review letters》2012,108(3):032501
The technique of invariant mass spectroscopy has been used to measure, for the first time, the ground state energy of neutron-unbound (28)F, determined to be a resonance in the (27)F+n continuum at 220(50) keV. States in (28)F were populated by the reactions of a 62 MeV/u (29)Ne beam impinging on a 288 mg/cm(2) beryllium target. The measured (28)F ground state energy is in good agreement with USDA/USDB shell model predictions, indicating that pf shell intruder configurations play only a small role in the ground state structure of (28)F and establishing a low-Z boundary of the island of inversion for N=19 isotones. 相似文献