Novel protecting groups in carbohydrate chemistry

Protecting groups play a pivotal role in carbohydrate chemistry. This review describes a selection of protecting groups and protecting group strategies that have been introduced since the beginning of this century.     

Effect of heat transfer on a third grade fluid in a flat channel

The heat transfer analysis on the laminar flow of an incompressible third grade fluid through a porous flat channel is examined. The lower plate is assumed to be at a higher temperature than the upper plate. Analytical solution for temperature distribution is obtained for various values of the controlling parameters and discussed. The obtained analytical solution is also compared with the numerical solution. The comparison shows the fact that the accuracy is remarkable. Copyright © 2009 John Wiley & Sons, Ltd.     

Characteristics of mass and nuclear charge distributions of229th(nth,f). implications for fission dynamics

The mass and nuclear charge distributions of fission fragments from²²⁹Th(n_{th, f}) have been measured at several kinetic energies with the mass spectrometer Lohengrin (ILL-Grenoble). The average proton e-o effect, which reaches 41%, induces large oscillations in the parameters of the isotopic charge distribution. A comparison of the data from different fissile nuclei shows the importance of the last stage of the process for intrinsic excitations.     

Squeezed flow and heat transfer over a porous surface for viscous fluid

Flow and heat transfer over a permeable sensor surface placed in a squeezing channel is analyzed. A constant transpiration through the sensor surface is assumed. Locally non-similar momentum and energy equations are solved by three different methods, against the transpiration parameter τ, for different values of the squeezing parameter b, and Prandtl number Pr. From the investigation, it is found that when the channel being squeezed, the skin-friction reduces but the heat transfer coefficient increases. Increase in the value of the squeezing parameter onsets reverse flow at the sensor surface when fluid is being injected and the affect is enhanced with the increase of injection through the surface. It is further observed that increase of suction of fluid through the sensor thins the thermal and the momentum boundary layer regions, whereas injection of fluid leads to thickening of both the thermal and the momentum boundary layer regions. Heat transfer from the surface of the sensor increases with the increase of the value of Pr for the entire range of surface mass-flux parameter τ. M. A. Hossain is on leave of absence from University of Dhaka.     

Interlaminar hygrothermal stresses in laminated plates

Within the elasticity formulation the most general displacement field for hygrothermal problems of long laminated composite plates is presented. The equivalent single-layer theories are then employed to determine the global deformation parameters appearing in the displacement fields of general cross-ply, symmetric, and antisymmetric angle-ply laminates under thermal and hygroscopic loadings. Reddy’s layerwise theory is subsequently used to determine the local deformation parameters of various displacement fields. An elasticity solution is also developed in order to validate the efficiency and accuracy of the layerwise theory in predicting the interlaminar normal and shear stress distributions. Finally, various numerical results are presented for edge-effect problems of several cross-ply, symmetric, and antisymmetric angle-ply laminates subjected to uniform hygrothermal loads. All results indicate high stress gradients of interlaminar normal and shear stresses near the edges of laminates.     

Ion-pair-based surfactant-assisted dispersive liquid–liquid microextraction for the determination of cadmium in water samples: Optimization using response surface methodology

A sensitive, simple, and rapid method is developed for ion-pair-based surfactant-assisted dispersive liquid–liquid microextraction (IPSA-DLLME) and flame atomic absorption spectrometric determination of cadmium in water samples. In this procedure, trace amounts of Cd²⁺ were converted to CdI ₄ ^2– , and after addition of a tetrabutylammonium bromide (TBAB) solution as cationic surfactant the analyte was transformed to the ion-pair state. This cadmium species was extracted by fast injection of a solution containing 200 μL of chloroform and 800 μL of methanol as extraction and disperser solvents, respectively. The pH of the sample solution, concentration of iodide, TBAB amount, and the extractant volume were optimized using a 27-run Box–Behnken design with a triplicate central point. Under the optimized conditions, the calibration curve was linear in the range 1–200 μg L^–1 (R ² = 0.9959); with the detection limit (signal/noise = 3) of 0.28 μg L^–1. The relative standard deviations (RSD) for eight runs (Cd²⁺ = 10 μg L^–1) and enrichment factor were found to be 3.04 % and 50, respectively.     

Effect of alkaline pretreatment on delignification of wheat straw

This study was conducted to analyse structural changes through scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) after alkaline pretreatment of wheat straw for optimum steaming period. During the study, 2 mm size of substrate was soaked in 2.5% NaOH for 1 h at room temperature and then autoclaved at 121°C for various steaming time (30, 60, 90 and 120 min). Results revealed that residence time of 90 min at 121°C has strong effect on substrate, achieving a maximum cellulose content of 83%, delignification of 81% and hemicellulose content of 10.5%. Further SEM and FTIR spectroscopy confirmed structural modification caused by alkaline pretreatment in substrate. Maximum saccharification yield of 52.93% was achieved with 0.5% enzyme concentration using 2.5% substrate concentration for 8 h of incubation at 50°C. This result indicates that the above-mentioned pretreatment conditions create accessible areas for enzymatic hydrolysis.     

Formation of Heterocyclic and Polycyclic Compounds from Amino Alcohols and Dialdehydes

Amino alcohols typically react with aldehydes to produce oxazolidines. It was hypothesized that the condensation of several commercially available amino alcohols with dialdehydes would produce a series of bicyclic oxazolidines containing two secondary amines. However, there were remarkable differences in the type of products formed depending on the structure of the dicarbonyl compounds and the reaction conditions. When linear aliphatic dialdehydes such as glyoxal were used, the expected bis‐oxazolidines were not produced; instead, polycyclic structures or oxazines were formed. However, when cyclic dialdehydes such as 1,3/1,4 cyclohexane dicarboxaldehyde were used, they resulted in products bearing the desired oxazolidine moieties.     

Multiple solutions for non-homogeneous degenerate Schrödinger equations in cone Sobolev spaces

The present paper deals with the study of semilinear and non-homogeneous Schrödinger equations on a manifold with conical singularity. We provide a suitable constant by Sobolev embedding constant and for p ∈ (2, 2?) with respect to non-homogeneous term g(x) ∈ L ₂ ^n/2 (B), which helps to find multiple solutions of our problem. More precisely, we prove the existence of two solutions to the problem 1.1 with negative and positive energy in cone Sobolev space H _2,0 ^1,n/2 (B). Finally, we consider p = 2 and we prove the existence and uniqueness of Fuchsian-Poisson problem.     

Rotating flow of a third grade fluid in a porous space with Hall current

This study investigates the rotating magnetohydrodynamic (MHD) flow of a third-grade fluid in a porous space. Modified Darcy's law has been utilized for the flow modeling. The Hall effects are taken into consideration. The basic equations governing the flow are reduced to a highly nonlinear ordinary differential equation. This equation has been solved analytically by employing the homotopy analysis method (HAM). The effects of the various interesting parameters on the velocity distribution have been discussed.