Cyclotriphosphazene grafted silica: a novel support for immobilizing the oxo-vanadium Schiff base moieties for hydroxylation of benzene

The first report on the use of chlorotriphosphazenyl anchored mesoporous silica as a novel support for the immobilization of oxo-vanadium Schiff base moieties is described. The resulting heterogeneous material showed better catalytic activity than homogeneous as well as silica immobilized oxo-vanadium Schiff base for the hydroxylation of benzene with hydrogen peroxide.     

Solvent effect on the optical property of uranyl acetylacetonate monohydrate

The lability of the [UO2(acac)2H2O] complex has been exploited to decipher solvent composition of a medium. Successive blue shift of the π-π* band (λmax=282 nm) is observed due to alcohol substitution of increasing chain length in place of water. This observation helps to quantify the chain lengths of normal alcohol. The result has been accounted theoretically. However, in non-coordinating solvent, irregular red shift of the π-π* band is observed because of the molecular complexity. Again, charge transfer (CT) band at 211 nm has been identified employing polar-polar and polar coordinating-non-coordinating solvent systems.     

Imbalance of positive and negative links induces regularity

We investigate the effect of the interplay of positive and negative links, on the dynamical regularity of a random weighted network, with neuronal dynamics at the nodes. We investigate how the mean $\overline{J}$ and the variance of the weights of links, influence the spatiotemporal regularity of this dynamical network. We find that when the connections are predominantly positive (i.e. the links are mostly excitatory, with $\overline{J}>0$) the spatiotemporal fixed point is stable. A similar trend is observed when the connections are predominantly negative (i.e. the links are mostly inhibitory, with $\overline{J}<0$). However, when the positive and negative feedback is quite balanced (namely, when the mean of the connection weights is close to zero) one observes spatiotemporal chaos. That is, the balance of excitatory and inhibitory connections preserves the chaotic nature of the uncoupled case. To be brought to an inactive state one needs one type of connection (either excitatory or inhibitory) to dominate. Further we observe that larger network size leads to greater spatiotemporal regularity. We rationalize our observations through mean field analysis of the network dynamics.     

Comparison of protein expression profiles between monolayer and spheroid cell culture of HT-29 cells revealed fragmentation of CK18 in three-dimensional cell culture

The use of three-dimensional cell culture models, so-called multicellular tumor spheroids, is a special approach in experimental cancer research, because spheroids are similar to in vivo tumors in structural as well as functional sense. Cells grown in spheroids exhibit alterations of cell cycle regulation, induction of apoptosis and differentiation and can acquire multidrug resistance. In this study we investigated the protein expression in human colorectal cancer cells grown in monolayer and in spheroid cultures using proteomics. Evaluation by computer-assisted image analysis revealed overexpression of three cytokeratin 18 fragments that were generated in vivo. Cytokeratin 18 has previously been described as a target for caspase-mediated cleavage during apoptosis and our results indicate that apoptosis may take place in spheroids. Other proteins upregulated in spheroids include calreticulin precursor, a rho GDP dissociation inhibitor variant, several cytokeratins and peroxiredoxin 4. Some of these proteins have already been linked to chemoresistance and apoptotic phenomena.     

FAIR@Germany

The proposed international Facility for Antiproton and Ion Research (FAIR) at GSI-Darmstadt, will be a source of exotic radionuclidic beam and is expected to be operational in 2016. The facility will deliver 2 GeV/u to 45 GeV/u beam covering the entire range of the periodic table with the intensities three orders of magnitude higher than that available anywhere in the world today. This facility will serve all areas of fundamental sciences including nuclear physics, physics at extreme density conditions like neutron stars, plasma and laser physics, hadron physics and applied areas in chemistry, biology and material sciences. In this article, we discuss briefly the FAIR facility, with special emphasis on Indian participation.     

Mechanical, thermal, and fire properties of polylactide/starch blend/clay composites

Polylactide (PLA)/starch blend/clay and PLA/clay composites are prepared by melt blending. Structural and thermal characterizations are performed by differential scanning calorimetry, X-ray diffraction analysis, and thermogravimetric analysis. The fire properties are assessed on a dual cone calorimeter. Combustion residue and char formation is characterized by optical microscopy and attenuated total reflection infrared spectroscopy. Although the clay is not fully intercalated/exfoliated, the composites exhibit a higher thermal stability and much reduced peak heat release rate, and the PLA/starch blend composite retains its mechanical properties. For the PLA/starch blend composite, smoke release is also considerably reduced. Catalyzed, oxidative decomposition is shown to occur early in the thermal decomposition of the composites, prior to increased thermal stability. The inclusion of clay promotes char formation and increases the quantity of carbonaceous char in the combustion residue. There is minimal migration of the clay to the surface prior to ignition and char is formed mainly after ignition and during burning. During the later stages of burning some of the char formed is converted to CO₂.     

and Norms Error Estimates in Finite Element Method for Linear Parabolic Interface Problems

We derive new a priori error estimates for linear parabolic equations with discontinuous coefficients. Due to low global regularity of the solutions the error analysis of the standard finite element method for parabolic problems is difficult to adopt for parabolic interface problems. A finite element procedure is, therefore, proposed and analyzed in this paper. We are able to show that the standard energy technique of finite element method for non-interface parabolic problems can be extended to parabolic interface problems if we allow interface triangles to be curved triangles. Optimal pointwise-in-time error estimates in the L ²(Ω) and H ¹(Ω) norms are shown to hold for the semidiscrete scheme. A fully discrete scheme based on backward Euler method is analyzed and pointwise-in-time error estimates are derived. The interfaces are assumed to be arbitrary shape but smooth for our purpose.     

Template Synthesis of Three‐Dimensional Hexakisimidazolium Cages

A procedure for the synthesis of three‐dimensional hexakisimidazolium cage compounds has been developed. The reaction of the trigonal trisimidazolium salts H₃L(PF₆)₃, decorated with three N‐olefinic pendants, and silver oxide yielded trinuclear trisilver(I) hexacarbene molecular cylinders of the type [Ag₃L₂]³⁺ with the olefinic pendants from the two different tricarbene ligands arranged in three pairs. Subsequent UV irradiation gave three cyclobutane links between the two tris‐NHC ligands in three [2+2] cycloaddition reactions, thereby generating a three‐dimensional hexakis‐NHC ligand. Removal of the metal ions resulted in the formation of three‐dimensional hexakisimidazolium cages with a large internal cavity.     

An all-optical comparison scheme between two multi-bit data with optical nonlinear material

Over the last few decades, several all-optical circuits have been proposed to meet the need of high-speed data processing. In some information processing architectures, the role of various analog and digital data comparisons is very important. In this letter, we proposed a multi-bit data comparison scheme. The scheme is based on the switching property of optical nonlinear material. Ultrafast operational speed larger than gigahertz can be expected from this all-optical scheme.OCIS codes: 190.0190, 200.0200, 200.1130, 200.3760.     

Dirac spinors in an inhomogeneous cosmological model

Solutions of the Dirac equation in the Senovilla inhomogeneous cosmological model, which is free of a big-bang singularity, are presented. It is found that the energy density of the spinors is initially zero, but attains a maximum at some time and then decreases.