Electrochemical processes in a wire-in-a-capillary bulk-loaded, nano-electrospray emitter

Experiments are described that illustrate solvent oxidation, emitter electrode corrosion, and analyte oxidation in positive ion mode nano-electrospray mass spectrometry using a wire-in-a-capillary, bulk-loaded nano-electrospray emitter geometry. Time-lapsed color photography of pH and metal specific indicator solutions within operating nano-electrospray emitters, as well as temporal changes in the ions observed in the nano-electrospray mass spectra, are used to probe these reactions, judge their magnitude, and study the time dependent changes in solution composition and gas-phase ion signal brought about as a result of these electrochemical reactions. The significance of these observations for analytical applications of nano-electrospray mass spectrometry are discussed.     

Design of Photostable,Activatable Near‐Infrared Photoacoustic Probes Using Tautomeric Benziphthalocyanine as a Platform

Near‐infrared (NIR) imaging techniques have attracted significant attention for biological and medicinal applications due to the ability of NIR to penetrate deeply into tissues. However, there are very few stable, activatable molecular probes that can utilize NIR light in the wavelength range beyond 800 nm. Herein, we report a new activatable NIR system for photoacoustic imaging based on tautomeric benziphthalocyanines (BPcs). We found that the existence of a free hydroxyl group is crucial for NIR absorption of BPcs. Synthesized water‐soluble hydroxy BPcs exhibited high photostability and no fluorescence, which are desirable features for photoacoustic imaging. We synthesized BPcs in which the free hydroxyl group was masked by an esterase‐labile or an H₂O₂‐labile group. The photoacoustic signals of these hydroxy‐masked BPcs were increased upon NIR excitation at 880 nm in the presence of esterase or H₂O₂, respectively. These are rare examples of activatable probes utilizing NIR light at around 900 nm.     

Experiment at SPring-8

The GeV photon beam at SPring-8 is produced by backward-Compton scattering of laser photons from 8 GeV electrons. The maximum energy of the photon will be above 3 GeV, and the beam intensity will be 10⁷ photons/sec. Polarization of the photon beam will be 100 % at the maximum energy with fully polarized laser photons. We report the outline of the quark nuclear physics project with this high-quality high-intensity beam.     

Aliphatic/aromatic polyimide ionomers as a proton conductive membrane for fuel cell applications

To produce a proton conductive and durable polymer electrolyte membrane for fuel cell applications, a series of sulfonated polyimide ionomers containing aliphatic groups both in the main and in the side chains have been synthesized. The title polyimide ionomers 1 with the ion exchange capacity of 1.78-2.33 mequiv/g were obtained by a typical polycondensation reaction as transparent, ductile, and flexible membranes. The proton conductivity of 1 was slightly lower than that of the perfluorinated ionomer (Nafion) below 100 degrees C, but comparable at higher temperature and 100% RH. The highest conductivity of 0.18 S cm(-)(1) was obtained for 1 at 140 degrees C. Ionomer 1 with high IEC and branched chemical structure exhibited improved proton conducting behavior without sacrificing membrane stability. Microscopic analyses revealed that smaller (<5 nm) and well-dispersed hydrophilic domains contribute to better proton conducting properties. Hydrogen and oxygen permeability of 1 was 1-2 orders of magnitude lower than that of Nafion under both dry and wet conditions. Fuel cell was fabricated with 1 membrane and operated at 80 degrees C and 0.2 A/cm(2) supplying H(2) and air both at 60% or 90% RH. Ionomer 1 membrane showed comparable performance to Nafion and was durable for 5000 h without distinct degradation.     

Observation of B(+/-) --> p(-)pK(+/-)

We report the observation of the decay mode B(+/-) --> p(-)pK(+/-)based on an analysis of 29.4 fb(-1) of data collected by the Belle detector at KEKB. This is the first example of a b-->s transition with baryons in the final state. The p(-)p mass spectrum in this decay is inconsistent with phase space and is peaked at low mass. The branching fraction for this decay is measured to be B(B+/--->p(-)pK+/-) = [4.3(+1.1)(-0.9)(stat)+/-0.5(syst)]x 10(-6). We also report upper limits for the decays B(0)-->p(-)pK(S) and B(+/-)-->p(-)p pi(+/-).     

Radiative B meson decays into kpigamma and kpipigamma final states

We report observations of radiative B meson decays into the K+pi(-)gamma and K+pi(-)pi(+)gamma final states. In the B0-->K+pi(-)gamma channel, we present evidence for decays via an intermediate tensor meson state with a branching fraction of B(B0-->K(*)(2)(1430)(0)gamma)=[1.3+/-0.5(stat)+/-0.1(syst)]x10(-5). We measure the branching fraction B(B+-->K+pi(-)pi(+)gamma)=[2.4+/-0.5(stat) +0.4-0.2(syst)]x10(-5), in which the B+-->K(*0)pi(+)gamma and B+-->K+rho(0)gamma channels dominate. The analysis is based on a data set of 29.4 fb(-1) recorded by the Belle experiment at the KEKB collider.     

Study of CP-violating asymmetries in B0-->pi(+)pi(-) decays

We present a measurement of CP-violating asymmetries in B0-->pi(+)pi(-) decays based on a 41.8 fb(-1) data sample collected at the Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric-energy e(+)e(-) collider. We fully reconstruct one neutral B meson as a B0-->pi(+)pi(-) CP eigenstate and identify the flavor of the accompanying B meson from its decay products. From the asymmetry in the distribution of the time intervals between the two B meson decay points, we obtain the CP-violating asymmetry parameters S(pipi)=-1.21(+0.38)(-0.27)(stat)+0.16-0.13(syst) and A(pipi)=+0.94(+0.25)(-0.31)(stat)+/-0.09(syst).     

Measurement of the lifetime difference in D0 meson decays

We report a measurement of the D0-D macro(0) mixing parameter y(CP) using 23.4 fb(-1) of data collected near the Upsilon(4S) resonance with the Belle detector at KEKB. y(CP) is measured from the lifetime difference of D0 mesons decaying into the K(-)pi(+) state and the CP-even eigenstate K(-)K(+). We find y(CP) = (-0.5+/-1.0(+0.7)(-0.8))x10(-2), where the first error is statistical and the second is systematic, corresponding to a 95% confidence interval -0.030相似文献   

Optical waveguide spectrometer based on thin-film glass plates

Commercially available thin-film glass plates have been successfully used for optical waveguide spectroscopy of chemical and biological films adsorbed upon the plates' surfaces. A 50-mum -thick glass plate was placed in contact with two parallel strips of silicone rubber supported on a slide glass. The plate area between the rubber strips served as the waveguiding region, eliminating the negative effect of the substrate on absorbance sensitivity. We coupled white light into the waveguide by focusing the light from a xenon lamp onto one end of a glass fiber and then inserting the other end into a glycerol drop overlaid upon the plate's surface. With a CCD detector, light at wavelengths as short as 360 nm was found to transmit out of the plate's end face. The propagation loss of the waveguide was measured to be 相似文献