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61.
S. Wohlfahrt M. Fischer M. Saraji-Bozorgzad G. Matuschek T. Streibel E. Post T. Denner R. Zimmermann 《Analytical and bioanalytical chemistry》2013,405(22):7107-7116
Comprehensive multi-dimensional hyphenation of a thermogravimetry device (i.e. a thermobalance) to gas chromatography and single photon ionization–time-of-flight mass spectrometry (TG–GC×SPI–MS) has been used to investigate two crude oil samples of different geographical origin. The source of the applied vacuum ultraviolet radiation is an electron beam pumped rare gas excimer lamp (EBEL). The soft photoionization favors the formation of molecular ions. Introduction of a fast, rapidly modulated gas chromatographic separation step in comparison with solely TG–SPI–MS enables strongly enhanced detection especially with such highly complex organic matrices as crude oil. In contrast with former TG–SPI–MS measurements, separation and identification of overlying substances is possible because of different GC retention times. The specific contribution of isobaric compounds to one mass signal is determined for alkanes, naphthalenes, alkylated benzenes, and other compounds. Figure
Specific characteristics of a two-dimensional TG–GC×SPI–MS contour plot obtained from Turkish crude oil. The complete m/z and TG temperature ranges are displayed in a. The magnified region from m/z 50–250 and 140–170 °C reveals the “pixilated” structure (b). Parts c and d reveal the system’s ability to investigate compounds in a broad m/z range with limitations for very-high and very-low boiling compounds as shown for m/z 260 and m/z 70, respectively 相似文献
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63.
The complexity of technical products increases significantly, due to an increasing number of interacting design variables of many components and subsystems. At the same time, the need for separated development processes is increasing due to specialization and outsourcing. Solution space methods are designed to solve this conflict. The requirements from an upper level, e.g. performance measures of the whole system, can be cascaded down to requirements on a lower level, e.g. performance measures of the subsystems or components, as it is done in the V-model approach. The method does not only take the numerous interactions into account but also guarantees the resulting intervals of different parameters to be independent of each other. Unfortunately, the computational cost of the state-of-the-art stochastic approach is high. The approach in this paper shows that the computational effort can be reduced considerably using a gradient based optimization approach for constraint problems. We demonstrate that the approach reduces the required number of function evaluations for a chassis design problem by a factor of 30, but more important, the CPU time for solving the problem by a factor of 20. (© 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
64.
Ben Ali K Lafon O Zimmermann H Guittet E Lesot P 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2007,187(2):205-215
We describe several homo- and heteronuclear 2D NMR strategies dedicated to the analysis of anisotropic (2)H spectra of a mixture of dideuterated unlike/like stereoisomers with two remote stereogenic centers, using weakly orienting chiral liquid crystals. To this end, we propose various 2D correlation experiments, denoted "D(H)(n)D" or "D(H)(n)C" (with n=1, 2), that involve two heteronuclear polarization transfers of INEPT-type with one or two proton relays. The analytical expressions of correlation signals for four pulse sequences reported here were calculated using the product-operators formalism for spin I=1 and S=1/2. The features and advantages of each scheme are presented and discussed. The efficiency of these 2D sequences is illustrated using various deuterated model molecules, dissolved in organic solutions of polypeptides made of poly-gamma-benzyl-L-glutamate (PBLG) or poly-epsilon-carbobenzyloxy-L-lysine (PCBLL) and NMR numerical simulations. 相似文献
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66.
Paola Zimmermann Crocomo Takahito Kaihara Soki Kawaguchi. Dr. Patrycja Stachelek Prof. Dr. Satoshi Minakata Prof. Dr. Piotr de Silva Prof. Dr. Przemyslaw Data Prof. Dr. Youhei Takeda 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(53):13390-13398
Novel electron donor–acceptor–donor (D-A-D) compounds comprising dibenzo[a,j]phenazine as the central acceptor core and two 7-membered diarylamines (iminodibenzyl and iminostilbene) as the donors have been designed and synthesized. Investigation of their physicochemical properties revealed the impact of C2 insertion into well-known carbazole electron donors on the properties of previously reported twisted dibenzo[a,j]phenazine-core D-A-D triads. Slight structural modification caused a drastic change in conformational preference, allowing unique photophysical behavior of dual emission derived from room-temperature phosphorescence and triplet–triplet annihilation. Furthermore, electrochemical analysis suggested sigma-dimer formation and electrochemical polymerization on the electrode. Quantum chemical calculations also rationalized the experimental results. 相似文献
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68.
Houssine Sehaqui Uxua Perez de Larraya Peng Liu Numa Pfenninger Aji P. Mathew Tanja Zimmermann Philippe Tingaut 《Cellulose (London, England)》2014,21(4):2831-2844
Biobased nanofibers are increasingly considered in purification technologies due to their high mechanical properties, high specific surface area, versatile surface chemistry and natural abundance. In this work, cellulose and chitin nanofibers functionalized with carboxylate entities have been prepared from pulp residue (i.e., a waste product from the pulp and paper production) and crab shells, respectively, by chemically modifying the initial raw materials with the 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) mediated oxidation reaction followed by mechanical disintegration. A thorough investigation has first been carried out in order to evaluate the copper(II) adsorption capacity of the oxidized nanofibers. UV spectrophotometry, X-ray photoelectron spectroscopy and wavelength dispersive X-rays analysis have been employed as characterization tools for this purpose. Pristine nanofibers presented a relatively low content of negative charges on their surface thus adsorbing a low amount of copper(II). The copper adsorption capacity of the nanofibers was enhanced due to the oxidation treatment since the carboxylate groups introduced on the nanofibers surface constituted negative sites for electrostatic attraction of copper ions (Cu2+). The increase in copper adsorption on the nanofibers correlated both with the pH and carboxylate content and reached maximum values of 135 and 55 mg g?1 for highly oxidized cellulose and chitin nanofibers, respectively. Furthermore, the metal ions could be easily removed from the contaminated nanofibers through a washing procedure in acidic water. Finally, the adsorption capacity of oxidized cellulose nanofibers for other metal ions, such as nickel(II), chromium(III) and zinc(II), was also demonstrated. We conclude that TEMPO oxidized biobased nanofibers from waste resources represent an inexpensive and efficient alternative to classical sorbents for heavy metal ions removal from contaminated water. 相似文献
69.
Johanne Heitmann Solheim Boris Zimmermann Valeria Tafintseva Simona Dzurendov Volha Shapaval Achim Kohler 《Molecules (Basel, Switzerland)》2022,27(6)
Extended multiplicative signal correction (EMSC) is a widely used preprocessing technique in infrared spectroscopy. EMSC is a model-based method favored for its flexibility and versatility. The model can be extended by adding constituent spectra to explicitly model-known analytes or interferents. This paper addresses the use of constituent spectra and demonstrates common pitfalls. It clarifies the difference between analyte and interferent spectra, and the importance of orthogonality between model spectra. Different normalization approaches are discussed, and the importance of weighting in the EMSC is demonstrated. The paper illustrates how constituent analyte spectra can be estimated, and how they can be used to extract additional information from spectral features. It is shown that the EMSC parameters can be used in both regression tasks and segmentation tasks. 相似文献
70.
微波消解-ICP-AES测定鄱阳湖流域沉积物中微量元素 总被引:8,自引:0,他引:8
为了研究鄱阳湖沉积物中微量元素近几年来随季节、年度及沿程的变化情况,对2003年和2005年不同季节采集的鄱阳湖流域各采样点底泥进行了ICP-AES测定.结果表明,鄱阳湖沉积物中各元素的含量随着季节和年度变化而发生一定改变,枯水期普遍大于丰水期;南矶山2005年Cu和Pb含量较2003年有所降低;蔡家湾则与南矶山相反;姚公渡2005年Cu含量也较2003年低,Pb含量则高于2003年;与鄱阳湖流域底泥背景值相比,所测几个样点的Cu,Pb,Cr和Zn含量均在一定程度上超标;除大坞河外,其余各样点As含量均在背景值范围内;从饶河到鄱阳湖入湖口处,各元素含量呈逐渐降低趋势.文章提出的研究方法操作简便,效率高,劳动强度低. 相似文献