全文获取类型
收费全文 | 1133篇 |
免费 | 48篇 |
国内免费 | 1篇 |
专业分类
化学 | 841篇 |
晶体学 | 15篇 |
力学 | 35篇 |
数学 | 76篇 |
物理学 | 215篇 |
出版年
2023年 | 7篇 |
2022年 | 25篇 |
2021年 | 23篇 |
2020年 | 32篇 |
2019年 | 26篇 |
2018年 | 29篇 |
2017年 | 29篇 |
2016年 | 54篇 |
2015年 | 40篇 |
2014年 | 51篇 |
2013年 | 82篇 |
2012年 | 98篇 |
2011年 | 74篇 |
2010年 | 41篇 |
2009年 | 41篇 |
2008年 | 87篇 |
2007年 | 48篇 |
2006年 | 47篇 |
2005年 | 42篇 |
2004年 | 39篇 |
2003年 | 27篇 |
2002年 | 33篇 |
2001年 | 8篇 |
2000年 | 6篇 |
1998年 | 4篇 |
1997年 | 6篇 |
1996年 | 12篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1991年 | 7篇 |
1990年 | 5篇 |
1986年 | 8篇 |
1985年 | 10篇 |
1984年 | 10篇 |
1983年 | 5篇 |
1982年 | 3篇 |
1981年 | 8篇 |
1980年 | 5篇 |
1979年 | 5篇 |
1978年 | 10篇 |
1977年 | 4篇 |
1969年 | 6篇 |
1968年 | 6篇 |
1964年 | 4篇 |
1963年 | 6篇 |
1962年 | 6篇 |
1961年 | 12篇 |
1958年 | 7篇 |
1957年 | 3篇 |
1955年 | 5篇 |
排序方式: 共有1182条查询结果,搜索用时 15 毫秒
121.
Murtaza Bohra Arun Showry Bandaru Panagiotis Grammatikopoulos Vidyadhar Singh 《Materials Today Chemistry》2020
An increasing trend toward integration of polymers in microelectronics and organic electronics has recently boosted research focusing in metal-polymer interfaces. These two materials differ vastly, with the former forming dense, crystalline, cohesive structures and the latter forming open structures bound together by weak van der Waals forces. As a result, there is dire need to assess their surface features (e.g., roughness) and correlate them with corresponding growth parameters, as metal-polymer interfaces are mainly determined by the preparation process. Here, we report a laboratory-based grazing-incidence small-angle x-ray scattering (GISAXS) study on distinct gold-polymer interfaces fabricated with different growth mechanisms, utilizing in-plane and oblique sputter geometries. GISAXS provided an improved analytic scheme for the buried surface in free-standing 2D gold-polymer nanosheets (with 19% porosity) revealing their fractal structure (Porod slope: ?1.71). Two quantitative approaches (Height-Height Correlation and Power Spectral Density functions) were used to describe rough surfaces characterized by Atomic Force Microscopy (AFM) in consort with GISAXS data; different correlation length dependencies on growth time were revealed for gold rough surfaces grown on bare and polymerized Si. The results are considered pertinent to interfacial nanoscience and engineering, enabling statistical data collection from large surface areas, in a fast and nondestructive manner. 相似文献
122.
Ajay K. Bose Maghar S. Manhas Suhas Pednekar Subhendu N. Ganguly Hoang Dang William He Arun Mandadi 《Tetrahedron letters》2005,46(11):1901-1903
An important stage in process development is kilo scale preparation of the target compound. For this reason, a procedure involving water-based biphasic reaction media has been developed for conducting some exothermic reactions on a large scale. This protocol is illustrated by the energy-efficient and rapid preparation of dihydropyrimidinones by a solvent-free, green chemistry procedure applied to the Biginelli reaction using p-toluenesulfonic acid as catalyst. 相似文献
123.
Dutta D Sarma TK Chowdhury D Chattopadhyay A 《Journal of colloid and interface science》2005,283(1):153-159
In this paper we report a new idea for synthesizing polyaniline in an ordinary filter paper. The synthesis was carried out by a process in which aqueous acidic aniline solution and the oxidizing agent H(2)O(2) was added to the paper drop by drop and in sequence. Uniform polymerization could be obtained with the addition of reagents in either sequence. The polymer formation led to a green coloration of the paper. Formation of the emeraldine salt of polyaniline was confirmed by UV-vis and FTIR spectroscopy. Scanning electron microscopic measurements were made for surface characterization of the polymer formed in the paper. The same paper was used as a sensor for ammonia in vapor and in solution, for acid and base as well as endpoint indication, and also to filter acids and bases. We found that, using the polymer-containing paper, ammonia concentrations in a solution as low as 14 ppm could be measured. 相似文献
124.
Majumdar G Goswami M Sarma TK Paul A Chattopadhyay A 《Langmuir : the ACS journal of surfaces and colloids》2005,21(5):1663-1667
In this letter, we report the synthesis of Au nanoparticles (NPs) and polyaniline (PANI) on the same cation-exchange resin beads and demonstrate their use in catalyzing the oxidation of glucose to gluconic acid by Au NPs and simultaneously in detecting the formation of the acid by the color change of PANI. The synthesis was carried out by exchanging the cations of the resins with HAuCl4 and anilinuium chloride and then reducing the metal ions by NaBH4 to produce Au NPs followed by polymerization of aniline using H2O2. The green emeraldine salt form of PANI thus obtained was treated with NaOH to be converted to blue emeraldine base before use. The deposition of Au NPs was confirmed by a change in color of the bead, visible spectroscopy, X-ray diffraction, and scanning electron microscopic measurements. On the other hand, the presence of PANI was confirmed by Fourier transform infrared (FTIR) and ultraviolet-visible (UV-vis) spectroscopy. The formation of gluconic acid from glucose was confirmed by FTIR spectroscopy. We could detect the presence of glucose of a minimum 1.0 mM concentration in water, using the present method. Our experimental observations demonstrate the possibility of the incorporation of multifunctional components on the surfaces of resins for carrying out a chemical reaction as well as detection of the product. 相似文献
125.
Castelino K Kannan B Majumdar A 《Langmuir : the ACS journal of surfaces and colloids》2005,21(5):1956-1961
The surface grafting density of biomolecules is an important factor for quantitative assays using a wide range of biological sensors. We use a fluorescent measurement technique to characterize the immobilization density of thiolated probe DNA on gold and hybridization efficiency of target DNA as a function of oligonucleotide length and salt concentration. The results indicate the dominance of osmotic and hydration forces in different regimes of salt concentration, which was used to validate previous simulations and to optimize the performance of surface-stress based microcantilever biosensors. The difference in hybridization density between complementary and mismatched target sequences was also measured to understand the response of these sensors in base-pair mismatch detection experiments. Finally, two different techniques for immobilizing proteins on gold were considered and the surface densities obtained in both cases were compared. 相似文献
126.
Photocatalytic polypyrrole-TiO2-nanoparticles composite thin film generated at the air-water interface 总被引:1,自引:0,他引:1
Chowdhury D Paul A Chattopadhyay A 《Langmuir : the ACS journal of surfaces and colloids》2005,21(9):4123-4128
Herein, we report a new method of generation of TiO(2) nanoparticles (NPs) incorporated thin films of polypyrrole (PPy) at the air-water interface. Aqueous TiO(2) NPs when treated with H(2)O(2) and left in a chamber of pyrrole vapor resulted in the formation of a film at the interface, in addition to bulk precipitate. Spectroscopic, X-ray diffraction, and electron microscopic measurements establish the formation of a thin film of PPy with the incorporation of TiO(2) NPs. The TiO(2)-containing PPy films when transferred onto glass substrates were able to photo catalyze the decomposition of aqueous organic dyes: methyl orange and methylene blue. Further, these films could also photo catalyze the oxidation of iodide to triiodide ions in aqueous potassium iodide solution. We find that the PPy-TiO(2) composite films catalyze the reactions in the presence of light more efficiently than a suspension of TiO(2) NPs. 相似文献
127.
128.
A high-performance thin layer chromatographic (HPTLC) method for the rapid and simple quantification of the four major anthraquinone derivatives i.e. physcion, chrysophanol, emodin and chrysophanol glycoside in Rheum emodi is described. HPTLC of anthraquinone derivatives was performed on pre-coated RP-18 F254S HPTLC plates. For achieving good separation, the mobile phase of methanol-water-formic acid (80:19:1, v/v/v) was used. The densitometric determination of anthraquinone derivatives was carried out at 445 nm in reflection/absorption mode. The calibration curves were linear in the range of 20-100 ng for physcion, 80-400 ng for chrysophanol and emodin, and 200-1000 ng for chrysophanol glycoside. The method was found to be reproducible and convenient for quantitative analysis of anthraquinone derivatives in the methanolic extract of rhizomes of R. emodi collected from three different locations of Western Himalaya, India. 相似文献
129.
(E)-4-(2',4',5'-trimethoxyphenyl)but-1,3-diene (4) and (E)-4-(2',4',5'-trimethoxyphenyl)but-1-ene (6), bioactive phenylbutanoids of Zingiber cassumunar, were synthesized exclusively with trans geometry. Treatment of methylmagnesium iodide with (E)-2',4',5'-trimethoxycinnamaldehyde (2), an oxidized product of abundantly available toxic (Z)-phenylpropanoid (1) of Acorus calamus, gave (E)-4-(2',4',5'-trimethoxyphenyl)but-3-en-2-ol (3) which upon dehydration with copper sulphate/silica gel under microwave irradiation for 3 min afforded 4 in 58% yield. Further, catalytic hydrogenation of 4 with 10% Pd/C afforded 4-(2',4',5'-trimethoxyphenyl)butane (5) which upon dehydrogenation with DDQ/SiO2 afforded hypolipidemic 6 in 54% yield. 相似文献
130.
DeSouza Arun H. G. Wilson David J. Tanner Robert D. 《Applied biochemistry and biotechnology》1990,24(1):565-578
Applied Biochemistry and Biotechnology - Extracellular proteins produced by yeast have been observed to stratify in the extracellular fluid of a batch bioreactor, thus creating a vertical... 相似文献