全文获取类型
收费全文 | 612篇 |
免费 | 22篇 |
国内免费 | 3篇 |
专业分类
化学 | 394篇 |
晶体学 | 2篇 |
力学 | 20篇 |
数学 | 102篇 |
物理学 | 119篇 |
出版年
2023年 | 3篇 |
2022年 | 8篇 |
2021年 | 20篇 |
2020年 | 8篇 |
2019年 | 7篇 |
2018年 | 10篇 |
2017年 | 11篇 |
2016年 | 19篇 |
2015年 | 19篇 |
2014年 | 20篇 |
2013年 | 39篇 |
2012年 | 38篇 |
2011年 | 44篇 |
2010年 | 27篇 |
2009年 | 20篇 |
2008年 | 40篇 |
2007年 | 45篇 |
2006年 | 37篇 |
2005年 | 43篇 |
2004年 | 23篇 |
2003年 | 20篇 |
2002年 | 21篇 |
2001年 | 7篇 |
2000年 | 4篇 |
1999年 | 6篇 |
1998年 | 4篇 |
1997年 | 5篇 |
1996年 | 8篇 |
1995年 | 2篇 |
1994年 | 4篇 |
1993年 | 4篇 |
1992年 | 5篇 |
1991年 | 5篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 7篇 |
1987年 | 4篇 |
1986年 | 2篇 |
1985年 | 8篇 |
1984年 | 3篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1973年 | 3篇 |
1972年 | 2篇 |
1897年 | 1篇 |
1880年 | 1篇 |
排序方式: 共有637条查询结果,搜索用时 125 毫秒
61.
Márcio José Horta Dantas José Manoel Balthazar 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2007,28(1):940-958
In this work, motivated by non-ideal mechanical systems, we investigate the following O.D.E.
[(x)\dot] = f (x) + eg (x, t) + e2[^(g)] (x, t, e){\dot{x} = f (x) + \varepsilon g (x, t) + \varepsilon^{2}\widehat{g} (x, t, \varepsilon)}
, where
x ? W ì \mathbbRn{x \in \Omega \subset \mathbb{R}^n}
,
g,[^(g)]{g,\widehat{g}}
are T periodic functions of t and there is a
0 ∈ Ω such that f ( a
0) = 0 and f ′( a
0) is a nilpotent matrix. When n = 3 and f (x) = (0, q (x
3) , 0) we get results on existence and stability of periodic orbits. We apply these results in a non ideal mechanical system:
the Centrifugal Vibrator. We make a stability analysis of this dynamical system and get a characterization of the Sommerfeld
Effect as a bifurcation of periodic orbits. 相似文献
62.
Arturo Magidin 《Algebra Universalis》2002,48(2):133-143
We determine the dominion (in the sense of Isbell) of a subgroup H of a finite nonabelian simple group S in Var(S). We also obtain necessary and suficient conditions for H to be epimorphically embedded in S, and derive several examples, which generalize an example of B. H. Neumann. Finally, we extend the results to a variety generated
by a family of finite nonabelian simple groups.
Received May 12, 1999; accepted in final form April 9, 2002. 相似文献
63.
We compare the exact and perturbative results in two metrics and show that the spurious effects due to the perturbation method do not survive for physically relevant quantities such as the vacuum expectation value of the stress-energy tensor. 相似文献
64.
Arturo Quirantes 《Journal of Quantitative Spectroscopy & Radiative Transfer》2005,92(3):373-381
A computer code is described for the calculation of light-scattering properties of randomly oriented, axially symmetric coated particles, in the framework of the T-matrix theory. The underlying mathematical background is outlined briefly and convergence procedures are discussed. After outlining the input-output interaction between user and code, benchmark results are presented for two distinct shapes: coated, centered spheroids and offset coated spheres. 相似文献
65.
David Y. Song Arturo A. Pizano Patrick G. Holder JoAnne Stubbe Daniel G. Nocera 《Chemical science》2015,6(8):4519-4524
Proton-coupled electron transfer (PCET) is a fundamental mechanism important in a wide range of biological processes including the universal reaction catalysed by ribonucleotide reductases (RNRs) in making de novo, the building blocks required for DNA replication and repair. These enzymes catalyse the conversion of nucleoside diphosphates (NDPs) to deoxynucleoside diphosphates (dNDPs). In the class Ia RNRs, NDP reduction involves a tyrosyl radical mediated oxidation occurring over 35 Å across the interface of the two required subunits (β2 and α2) involving multiple PCET steps and the conserved tyrosine triad [Y356(β2)–Y731(α2)–Y730(α2)]. We report the synthesis of an active photochemical RNR (photoRNR) complex in which a Re(i)-tricarbonyl phenanthroline ([Re]) photooxidant is attached site-specifically to the Cys in the Y356C-(β2) subunit and an ionizable, 2,3,5-trifluorotyrosine (2,3,5-F3Y) is incorporated in place of Y731 in α2. This intersubunit PCET pathway is investigated by ns laser spectroscopy on [Re356]-β2:2,3,5-F3Y731-α2 in the presence of substrate, CDP, and effector, ATP. This experiment has allowed analysis of the photoinjection of a radical into α2 from β2 in the absence of the interfacial Y356 residue. The system is competent for light-dependent substrate turnover. Time-resolved emission experiments reveal an intimate dependence of the rate of radical injection on the protonation state at position Y731(α2), which in turn highlights the importance of a well-coordinated proton exit channel involving the key residues, Y356 and Y731, at the subunit interface. 相似文献
66.
Aurora Molinari Alfonso Oliva Marlene Arismendi Elizabeth Imbarack Cristian Glvez Javier Maldonado Arturo San Feliciano 《Journal of heterocyclic chemistry》2015,52(2):620-622
New fused pyrazolo‐1,4‐naphthoquinones were prepared from the reaction of hydrazines with 6‐(4‐methyl‐3‐pentenyl)‐1,4‐naphthoquinone. The reaction was extended to hydroxylamine to afford the corresponding isoxazolo‐1,4‐napthoquinone compound. 相似文献
67.
Two of the most challenging problems that scientists and researchers face when they want to experiment with new cutting‐edge algorithms are the time‐consuming for encoding and the difficulties for linking them with other technologies and devices. In that sense, this article introduces the artificial organic networks toolkit for LabVIEW? (AON‐TL) from the implementation point of view. The toolkit is based on the framework provided by the artificial organic networks technique, giving it the potential to add new algorithms in the future based on this technique. Moreover, the toolkit inherits both the rapid prototyping and the easy‐to‐use characteristics of the LabVIEW? software (e.g., graphical programming, transparent usage of other softwares and devices, built‐in programming event‐driven for user interfaces), to make it simple for the end‐user. In fact, the article describes the global architecture of the toolkit, with particular emphasis in the software implementation of the so‐called artificial hydrocarbon networks algorithm. Lastly, the article includes two case studies for engineering purposes (i.e., sensor characterization) and chemistry applications (i.e., blood–brain barrier partitioning data model) to show the usage of the toolkit and the potential scalability of the artificial organic networks technique. © 2015 Wiley Periodicals, Inc. 相似文献
68.
Arturo Fernández Arias 《Complex Analysis and Operator Theory》2017,11(8):1653-1668
The study of meromorphic functions without multiple values in the plane started by F. Nevanlinna is extended to meromorphic functions in the punctured plane \({\mathbb {C}}^{{*}}.\) It is a classical result that a meromorphic function \(f\left( z\right) \) can be obtained as quotient of solutions of the second order differential equation \(u^{{\prime \prime }}+\left\{ f\left( z\right) ,z\right\} u=0,\) where \(\left\{ f\left( z\right) ,z\right\} \) is the Schwarzian derivative of \(f\left( z\right) \). In our hypothesis of meromorphic functions of finite order without multiple values in the puntured plane, the Schwarzian derivative \(\left\{ f\left( z\right) , z\right\} \) turns out to be a rational function with only possible poles at 0 and \(\infty \). In these conditions the asymptotic behaviour of \(f\left( z\right) \) can be described by a result of Hille (Lectures on Ordinary Differential Equations in the complex plane, Addison Wesley, Boston, 1969) on ordinary differential equations in the complex plane. The results obtained are framed in the value distribution theory of meromorphic functions, in particular in the punctured plane we shall consider the work of Khrystiyanin and Kondratyuk (Mat Stud 23(1):19–30, 2005; Mat Stud 23(1):57–68, 2005) and Korhonen (Nevanlinna theory on an annulus. Value distribution theory and related topics. Adv. Complex analysis and applications, Kluwer Academic Publishers, Dordrecht, 2004). 相似文献
69.
Franco Cataldo Pietro Ragni Susana Iglesias-Groth Arturo Manchado 《Journal of Radioanalytical and Nuclear Chemistry》2011,287(2):573-580
The sulphur-containing proteinaceous amino acids l-cysteine, l-cystine and l-methionine were irradiated in the solid state to a dose of 3.2 MGy. This dose corresponds to that delivered by radionuclide
decay in a timescale of 1.05 × 109 years to the organic matter buried at a depth >20 m in comets and asteroids. The purity of the sulphur-containing amino acids
was studied by differential scanning calorimetry (DSC) before and after the solid state radiolysis and the preservation of
the chirality after the radiolysis was studied by chirooptical methods (optical rotatory dispersion, ORD) and by FT-IR spectroscopy.
Although the high radiation dose of 3.2 MGy delivered, all the amino acids studied show a high radiation resistance. The best
radiation resistance was offered by l-cysteine. The radiolysis of l-cysteine leads to the formation of l-cystine. The radiation resistance of l-methionine is not at the level of l-cysteine but also l-methionine is able to survive the dose of 3.2 MGy. Furthermore in all cases examined the preservation of chirality after
radiolysis was clearly observed by the ORD spectroscopy although a certain level of radioracemization was measured in all
cases. The radioracemization is minimal in the case of l-cysteine and is more pronounced in the case of l-methionine. In conclusion, the study shows that the sulphur-containing amino acids can survive for 1.05 × 109 years and, after extrapolation of the data, even to the age of the Solar System i.e. to 4.6 × 109 years. 相似文献
70.
Arturo González-Hernández 《Journal of organometallic chemistry》2011,696(21):3436-3439
The reaction between the dihydride of decacarbonyltriosmium [H2Os3(CO)10] and phenyl arsine oxide (PAO) in benzene yields only one product [Os3(O)9(μ-H){μ-PhAs(O)OAsPh}] (1), which is characterized by high resolution mass spectrometry (HRMS), Fast Atomic Bombardment Mass Spectrometry (FAB)+, IR, 1H and 13C NMR, and single crystal X-ray diffraction. The solid state X-ray diffraction study of compound (1) shows that the molecule is polycyclic and has an osmium triangle with a bridging hydride bonded to a PhAs(O)-O-AsPh ligand. 相似文献