Structure-based tuning of T(m) in lipid-like ionic liquids. Insights from Tf2N- salts of gene transfection agents

Ionic liquids of cations bearing two lipid-like aliphatic tails are shown to have values of T(m) that can be very low, and that can be tuned up or down by the addition, deletion, or combination of dipolar modules and side-chain double bonds.     

Proposed method of partial discharge allocation with acoustic emission sensors within power transformers

Employing acoustic emission sensors for detection of partial discharge, PD, introduces many advantages. Besides easy installation and replacement, they are non-invasive and immune to electromagnetic noise and interference and their sensitivity does not vary with object capacitance. For PD allocating utilizing AE sensors, distance calculations are based on the arrival time of acoustic waves to the sensors. Considering structure-borne waves of higher speed, the peaks of some of indirect path AE signals with significant contribution are mistakenly considered as peaks of direct path AE signals. Furthermore, the acoustic signals are propagating through certain parts of the transformer, such as the windings, and this complicates the partial discharge detection and allocation. These would imply an incorrect distance between the source and sensor. A method based on a heuristic algorithm has been proposed which considering all possible indirect paths with the relevant propagation times and all the barriers on the travel path of acoustic signal, calculates the more precise arrival times to sensors. A test chamber has been utilized and artificial PD signals are produced at various points. Output results of algorithm have been compared with results of classic method. It has been shown that proposed method significantly reduces the positioning errors.     

Conjectures pertaining to repeated partitioning of a triangle

This note describes two conjectures pertaining to repeated partitioning of an arbitrary triangle. The first conjecture turns out to be true, and hence gives rise to a new, more general, conjecture that is also addressed in this article. Both conjectures can be explored in a dynamic geometry environment. The proofs to the conjectures addressed in this article require knowledge of high school Euclidean geometry.     

Acetylene based short route from 2,2,6,6-tetramethylpiperidin-4-one oxime to 2-(pyrazol-5-yl)-4,5,6,7-tetrahydropyrrolo[3,2-c]pyridines

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Morphologically Divergent Development of SnS Photocatalysts from Under-Utilized Ionic Precursors of SILAR Process

Journal of Cluster Science - Successive ionic layer adsorption and reaction (SILAR) process has been diversely used for deposition of various metal chalcogenides. SnS is one of them. Owing to the...     

The kinetics of photostabilization of cyanocobalamin in liposomal preparations

Cyanocobalamin (B₁₂) is a photosensitive vitamin, and its photodegradation to hydroxocobalamin (B_12b) in liposomes has been investigated. The values of apparent first-order rate constants (k_obs) for the photodegradation of B₁₂ in liposomes (nine preparations) are in the range of (0.52-2.24) × 10^–3 min^–1, compared to 3.21 × 10^–3 min^–1 for B₁₂ in aqueous solution (pH 5.0). The entrapment efficiency of B₁₂ in liposomes is 26.4-38.8%. The values of k_obs show a linear relation with phosphatidylcholine (PC) content in liposomes, indicating the influence of PC in inhibiting the rate of photolysis of B₁₂. The value of the bimolecular rate constant for photochemical interaction of B₁₂ and PC is 0.32 M^–1 min^–1, indicating the stabilizing effect of PC on the photolysis of B₁₂. The ratio of B₁₂ stabilization in liposomal preparations is in the range 2-6 compared to that of the unentrapped vitamin The stabilization of B₁₂ is mediated by a photoinduced charge-transfer B₁₂-PC complex that leads to the reduction of B₁₂ to B_12r, which is then oxidized to B_12b that has low susceptibility to photolysis. The extent of stabilization of B₁₂ probably depends on the degree of interaction between the two compounds under the reaction conditions, indicated by the loss of B₁₂ fluorescence.     

Dynamic geometry as a context for exploring conjectures

The purpose of this paper is to provide examples of ‘non-traditional’ proof-related activities that can explored in a dynamic geometry environment by university and high school students of mathematics. These propositions were encountered in the dynamic geometry environment. The author believes that teachers can ask their students to construct proofs for these propositions.     

Solvent Moisture-Controlled Self-Assembly of Fused Benzoimidazopyrrolopyrazines with Different Ring’s Interposition

This article shows that two extremely important families of fused heterocyclic assemblies, namely 6-methylbenzo[4,5]imidazo[1,2-a]pyrrolo[2,1-c]pyrazine and 5a-methyl-5a,6-dihydro-5H,12H-benzo[4,5]imidazo[1,2-a]pyrrolo[1,2-d]pyrazine, can be synthesized from only two available building blocks (N-allenylpyrrole-2-carbaldehyde and o-phenylenediamine) by controlling only one reaction parameter (water content of the medium). It should be emphasized that the latter class of compounds (with an a/d arrangement) is previously unknown. If the allene group is introduced not into the starting compound, but during the reaction (in superbase media), a heterocyclic ensemble, 5-methylbenzo[4,5]imidazo[1,2-a]pyrrolo[2,1-c]pyrazines, with a different position of the methyl group is formed.     

Convergence analysis of the product integration method for solving the fourth kind integral equations with weakly singular kernels

Numerical Algorithms - In this paper, we consider product integration method based on orthogonal polynomials to solve mixed system of Volterra integral equations of the first and second kind with...