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Arsalan Wares Iwan Elstak 《International Journal of Mathematical Education in Science & Technology》2017,48(2):317-324
The purpose of this paper is to describe the mathematics that emanates from the construction of an origami box. We first construct a simple origami box from a rectangular sheet and then discuss some of the mathematical questions that arise in the context of geometry and algebra. The activity can be used as a context for illustrating how algebra and geometry, like other branches of mathematics, are interrelated. 相似文献
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Sophia J. Bailey Erik Hopkins Kiara D. Rael Arsalan Hashmi Juan Manuel Urueña Prof. Maxwell Z. Wilson Prof. Javier Read de Alaniz 《Angewandte Chemie (International ed. in English)》2023,62(16):e202301157
Spatiotemporally functionalized hydrogels have exciting applications in tissue engineering, but their preparation often relies on radical-based strategies that can be deleterious in biological settings. Herein, the computationally guided design, synthesis, and application of a water-soluble cyclopentadienone-norbornadiene (CPD-NBD) adduct is disclosed as a diene photocage for radical-free Diels-Alder photopatterning. We show that this scalable CPD-NBD derivative is readily incorporated into hydrogel formulations, providing gels that can be patterned with dienophiles upon 365 nm uncaging of cyclopentadiene. Patterning is first visualized through conjugation of cyanine dyes, then biological utility is highlighted by patterning peptides to direct cellular adhesion. Finally, the ease of use and versatility of this CPD-NBD derivative is demonstrated by direct incorporation into a commercial 3D printing resin to enable the photopatterning of structurally complex, printed hydrogels. 相似文献
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Adeel Arsalan Iqbal Ahmad Syed Abid Ali Kiran Qadeer Shaukat Mahmud Fozia Humayun Anwar Ejaz Beg 《国际化学动力学杂志》2020,52(3):207-217
Cyanocobalamin (B12) is a photosensitive vitamin, and its photodegradation to hydroxocobalamin (B12b) in liposomes has been investigated. The values of apparent first-order rate constants (kobs) for the photodegradation of B12 in liposomes (nine preparations) are in the range of (0.52-2.24) × 10–3 min–1, compared to 3.21 × 10–3 min–1 for B12 in aqueous solution (pH 5.0). The entrapment efficiency of B12 in liposomes is 26.4-38.8%. The values of kobs show a linear relation with phosphatidylcholine (PC) content in liposomes, indicating the influence of PC in inhibiting the rate of photolysis of B12. The value of the bimolecular rate constant for photochemical interaction of B12 and PC is 0.32 M–1 min–1, indicating the stabilizing effect of PC on the photolysis of B12. The ratio of B12 stabilization in liposomal preparations is in the range 2-6 compared to that of the unentrapped vitamin The stabilization of B12 is mediated by a photoinduced charge-transfer B12-PC complex that leads to the reduction of B12 to B12r, which is then oxidized to B12b that has low susceptibility to photolysis. The extent of stabilization of B12 probably depends on the degree of interaction between the two compounds under the reaction conditions, indicated by the loss of B12 fluorescence. 相似文献
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Arsalan Mirjafari Niloufar Mobarrez James H. Davis Jr Jalil Noei 《Comptes Rendus Chimie》2011,14(12):1065-1070
A wide variety of oximes were prepared from different types of alcohols with hydroxylamine hydrochloride using 1-methylimidaziloum nitrate, [Hmim][NO3], ionic liquid as a reaction medium and promoter under microwave irradiation. This protocol provides a one-pot oxime synthesis with high yields that is facile, eco-friendly and the ionic liquid can be recovered and reused. 相似文献
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In this study, an organic solvent‐free microextraction technique termed liquid–gas–liquid microextraction (LGLME) was applied for cleanup and preconcentration of volatile short chain fatty acids in beverages and dairy products. Various parameters affecting the extraction efficiency such as extraction time, stirring speed, sodium chloride content, concentration and volume of donor and acceptor phases, and extraction temperature were studied. Repeatability (RSD, 4.2–8.5%), correlation coefficients (0.998–0.999), LODs (10–20 μg/L) and enrichment factors (152–249) were also investigated. Recoveries were achieved in the range of 90–102% in different matrices. The presented method was applied for the analysis of target analytes in some samples such as grape juice, vinegar and dairy products. 相似文献
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Mirjafari A Murray SM O'Brien RA Stenson AC West KN Davis JH 《Chemical communications (Cambridge, England)》2012,48(60):7522-7524
Ionic liquids of cations bearing two lipid-like aliphatic tails are shown to have values of T(m) that can be very low, and that can be tuned up or down by the addition, deletion, or combination of dipolar modules and side-chain double bonds. 相似文献