Attempted synthesis of ethyl 3,4‐dihydro‐2H‐1,4‐benzoxazine‐3‐carboxylate and 3‐acetate derivatives

Ethyl 3,4‐dihydro‐2H‐1,4‐benzoxazine‐3‐carboxylate derivatives 2 were obtained and isolated in low yields from the condensation of 2‐aminophenol and ethyl 2,3‐dibromopropanoate. They can be obtained by hydrogenation of ethyl 2H‐1,4‐benzoxazine‐3‐carboxylate in satisfactory yield. Using 2‐iminophenol did not direct the condensation with ethyl 2,3‐dibromopropanoate towards 2 but was fruitfull for the preparation of ethyl 2‐(4‐benzyl‐3,4‐dihydro‐2H‐1,4‐benzoxazin‐3‐yl)acetate from ethyl bromocrotonate.     

Topological signature of deterministic chaos in short nonstationary signals from an optical parametric oscillator

Although deterministic chaos has been predicted to occur in the triply resonant optical parametric oscillator (TROPO) 15 years ago, experimental evidence of chaotic behavior in this system has been lacking so far, in marked contrast with most nonlinear systems, where chaos has been actively tracked and found. This situation is probably linked to the high sensitivity of the TROPO to perturbations, which adversely affects stationary operation at high power. We report the experimental observation in this system of a burst of irregular behavior of duration 80 micros. Although the system is highly nonstationary over this time interval, a topological analysis allows us to extract a clear-cut signature of deterministic chaos from a time series segment of only nine base cycles (3 micros). This result suggests that nonstationarity is not necessarily an obstacle to the characterization of chaos.     

Dual-polarization microchip laser at 1.53 microm

Two-frequency operation of a composite Er,Yb:glass-LiTaO3 monolithic microlaser is demonstrated at 1.53 microm. The thermo-optic effect of the intracavity birefringent crystal makes it possible to control the wavelengths of the two orthogonal linearly polarized eigenstates. It provides a tunable beat note from 0 to 60 GHz. Direct evaluation of the Lamb-type coupling constant C between the two eigenstates is obtained from a single intensity noise spectrum measurement, yielding values from 0.33 to 0.86, depending on transverse and axial distributions of the eigenstates. Applications to radar and telecommunication systems are discussed.     

Lithium solvation and diffusion in the 1‐butyl‐3‐methylimidazolium bis(trifluoromethanesulfonyl)imide ionic liquid

The Raman spectra of (1 − x)(BMITFSI), xLiTFSI ionic liquids, where 1‐butyl‐3‐methylimidazolium cation (BMI⁺) and bis(trifluoromethane‐sulfonyl)imide anion (TFSI⁻) are analyzed for LiTFSI mole fractions x < 0.4. As expected from previous studies on similar TFSI‐based systems, most lithium ions are shown to be coordinated within [Li(TFSI)₂]⁻ anionic clusters. The variation of the self‐diffusion coefficients of the ¹H, ¹⁹F, and ⁷Li nuclei, measured by pulsed‐gradient spin‐echo NMR (PGSE‐NMR) as a function of x, can be rationalized in terms of the weighted contribution of BMI⁺ cations, TFSI⁻ ‘free’ anions, and [Li(TFSI)₂]⁻ anionic clusters. This implies a negative transference number for lithium. Copyright © 2008 John Wiley & Sons, Ltd.