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171.
The role of extra-framework and framework aluminium in wet-ion exchanged Fe-ZSM5 has been studied using 29Si NMR and 27Al triple quantum magic angle spinning (3QMAS) NMR. A series of samples were studied, the parent material, the wet ion exchanged Fe-ZSM5 and Fe-ZSM5 that has been used in the decomposition of N2O with varying reaction conditions. Various framework and extra-framework aluminium species have been identified. It was found that cationic Fe species prefer to replace the Brønsted acid protons in their charge balancing role at those aluminium sites associated with the largest quadrupolar product. The framework aluminium atoms that pertain to the smaller quadrupolar product, which are either charge balanced by extra-framework aluminium or a proton, are much less prone to exchange. In the catalytic decomposition of N2O it seemed that water present in small amounts enhances the catalytic activity. However, water also decreases the long term stability and performance by dealuminating the zeolite framework. With a high amount of water present, Fe-ZSM5 was destabilised and catalytically inferior. 相似文献
172.
We give sufficient conditions on a real number β and on a closed set F in a general space of homogeneous type (X,d,μ) in such a way that μ(B(x,d(x,F)))β becomes a Muckenhoupt weight. In order to prove our result, we modify the underlying space so that it becomes 1-Ahlfors regular. 相似文献
173.
Alexandre Plastino Hugo Barbalho Luis Filipe M. Santos Richard Fuchshuber Simone L. Martins 《Journal of Heuristics》2014,20(1):39-74
Metaheuristics represent an important class of techniques to solve, approximately, hard combinatorial optimization problems for which the use of exact methods is impractical. Some researches have been combining machine learning techniques with metaheuristics to adaptively guide and improve the search for near optimal solutions. An example of such development is the DM-GRASP, a hybrid version of the Greedy Randomized Adaptative Search Procedures (GRASP) metaheuristic which incorporates a data mining process. In this hybrid proposal, after executing half of the total number of iterations, the data mining process extracts patterns from an elite set of sub-optimal solutions for the optimization problem. These patterns present characteristics of near optimal solutions and can be used to guide the following half GRASP iterations in the search through the solution space. In this work, we explore new versions of the DM-GRASP metaheuristic to experiment, not a single activation, but multiple and adaptive executions of the data mining process during the metaheuristic execution. We also applied the data mining technique into a reactive GRASP to show that a more sophisticated and not memoryless GRASP approach can also benefit from the use of this technique. In order to evaluate these new proposals, we adopted the server replication for reliable multicast problem since the best known results for this problem were obtained by GRASP and DM-GRASP implementations. The computational experiments, comparing traditional GRASP, DM-GRASP, and the new proposals, showed that multiple and adaptive executions of the data mining process can improve the results obtained by the DM-GRASP hybrid metaheuristic—the new proposals were able to find better results in less computational time for the reliable multicast problem. 相似文献
174.
Claudete J. Valduga Denise B. Santis Hugo S. Braibante Mara E. F. Braibante 《Journal of heterocyclic chemistry》1999,36(2):505-508
The condensation of 4-phenyl substituted β-enamino ketones 1a-d and β-enamino esters 5a-d with hydroxylamine hydrochloride using K-10 as the solid support under sonication was studied to evaluate the formation of isoxazole and 5-isoxazolone rings from β-enamino compounds with a substituted aromatic ring. Isoxazoles 2a-c, 3c-d and 5-isoxazolones 6a-c and 7a-d were obtained. The use of K-10/ultrasound in this reaction furnished novel results in some cases. 相似文献
175.
Ohne Zusammenfassung 相似文献
176.
Ohne Zusammenfassung 相似文献
177.
Wahl Pierre Ly-Gagnon Dany-Sebastien Debaes Christof Miller David A. B. Thienpont Hugo 《Optical and Quantum Electronics》2012,44(3-5):285-290
Numerical calculations with finite-difference time-domain (FDTD) on metallic nanostructures in a broad optical spectrum require an accurate approximation of the permittivity of dispersive materials. In this paper, we present the algorithms behind B-CALM (Belgium-California Light Machine), an open-source 3D-FDTD solver operating on Graphical Processing Units with multi-pole dispersion models. Our modified architecture shows a reduction in computing times for multi-pole dispersion models. We benchmark B-CALM by computing the absorption efficiency of a metallic nanosphere on a broad spectral range with a six-poles Drude-Lorentz model and compare it with Mie theory.
相似文献178.
179.
Hugo Schiff 《Fresenius' Journal of Analytical Chemistry》1894,33(1):723-724
Ohne Zusammenfassung 相似文献
180.