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741.
Ricardo Saraiva de Camargo Gilberto de Miranda Arne Løkketangen 《Applied Mathematical Modelling》2013,37(12-13):7465-7480
An important problem of the freight industry is the parcel delivery network design, where several facilities are responsible for assembling flows from several origins, re-routing them to other facilities where the flows are disassembled and the packages delivered to their final destinations. In order to provide this service, local tours are established for the vehicles assigned to each of the processing facilities, which are then responsible for the pickup and delivery tasks. This application gives rise to the many-to-many hub location routing problem that is the combination of two well known problems: the vehicle routing problem and the single assignment hub location problem. In this work, a new formulation for this important problem is proposed and solved by a specially tailored Benders decomposition algorithm. The proposed method is robust enough to solve instances up to 100 nodes having 4 million integer variables. 相似文献
742.
743.
Roger Appelqvist György Marko-Varga Lo Gorton Arne Torstensson Gillis Johansson 《Analytica chimica acta》1985
A chemically modified electrode for detection of dihydronicotinamide adenine dinucleotide (NADH) and dihydronicotinamide adenine dinucleotide phosphate (NADPH) is described. Graphite rods were modified by dipping them into solutions of-dimethylamino-1,2-benzophenoxzinium salt (Meldola blue). The modified electrodes were mounted in a flow-through cell in a flow-injection manifold. Samples (50 μl) of pure nicotinamide coenzymes produced strictly linear calibration graphs from 1 μM to 10 mM with a repeatability of 0.2–0.6% RSD. A packed-bed enzyme reactor (210 μl) containing immobilized glucose dehydrogenase was inserted in the manifold for glucose determinations. Oxidized coenzyme was also added to the carrier electrolyte. Straight calibration graphs were again obtained up to 1mM β-d-glucose. The detection limit was 0.25 μM β-d-glucose for 50-μl samples. The electrode was kept at ?50 to 0 m V vs. SCE which was low enough to avoid interferences from ascorbic acid, uric acid or quinones. 相似文献
744.
Matthias Koch Almuth Liebich Tin Win Irene Nehls Arne Lund Kvernheim Oddvar Ringstad Frøydis Oreld 《Accreditation and quality assurance》2006,11(3):122-129
The 2-year international joint project HYCREF (Contract-No. G6RD-CT-2002-00854), funded by the European Commission in the 5th Framework programme, aimed to develop methods to prepare homogenous and stable water-, soil- and waste reference materials contaminated with mineral oil hydrocarbons and to test certify the mineral oil content by gas chromatographic methods. As mineral oil products are important sources for environmental contaminations, appropriate reference materials certified by using the new gas chromatographic methods (soil: ISO/FDIS 16703, waste: prEN 14039 and KW/04, water: ISO 9377-2) are highly needed. Additional to the HYCREF-results presented in part I–mineral contaminated soils–this second paper gives an overview of the feasibility study for the preparation and test certification of three waste reference materials (offshore marine sediment, building material and industrial waste). The following specifications, which had been defined in the project work plan, were reached successfully: uncertainty of the mineral oil content resulting from the certification exercise ≤5% and a between-bottle inhomogeneity of ≤3%. All three materials have been evaluated for long- and short term stability. They contain different levels and types of mineral oil and cover the full application range of ISO/FDIS 16703 and prEN 14039 (100–10,000 mg/kg). The expanded uncertainties U
cert of the three materials are about 6%. In this way, they are comparable to ERM®-CC015a (U
cert=7.1%, mineral oil in a river sediment) and are suited to close the present gap of commercially available CRM for mineral oil determination in waste. 相似文献
745.
Optoelectronic devices made from semiconductor polymers often employ partially phase-separated binary polymer blends with "distributed heterojunctions" in the polymer film, and the migration of bulk excitons towards these heterojunctions crucially influences the device performance. Here, we investigate exciton migration in blend films of two polyfluorene derivatives. Localized exciplex states form in electron-hole capture at the heterojunction between the two polymers and these can be thermally excited to transfer to bulk excitons. Rapid radiative emission from these excitons can then allow efficient light-emitting diode operation. We show here that when these excitons migrate to another heterojunction site within their lifetime they are re-trapped at the interface and again form exciplex states or dissociate completely. We demonstrate that in polymer blend light-emitting diodes this can reduce the exciton population by more than 54% and can strongly influence the emission spectrum. We then analyze exciton re-trapping in detail using time-resolved photoluminescence spectroscopy on blends with different morphologies and find that for nanometer-scale phases exciton emission is completely suppressed. We show that the data agree well with a simple kinetic model which confirms the importance of the blend morphology for the exciton trapping efficiency. 相似文献
746.
Huvaere K Andersen ML Olsen K Skibsted LH Heyerick A De Keukeleire D 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(19):4693-4699
trans-Isohumulones, dihydroisohumulones, tetrahydroisohumulones, and humulinones, which are important hop-derived flavor components of beer, were found, by using electrolysis of organic solutions, to be stable against oxidation, like weak acids; however, they are readily oxidized in their anionic forms as present in beer. Oxygen- and carbon-centered radicals were formed by oxidation and identified by using spin trapping under aerobic and anaerobic conditions, followed by EPR (electron paramagnetic resonance) spectroscopy. Generated radicals were reactive, most likely degrading into products lacking the tricarbonyl chromophore; this is typical of five-membered-ring hop derivatives. Thus, flavor-active beer constituents may degrade oxidatively in the absence of oxygen, thereby leading to reaction products that escape UV detection. 相似文献
747.
748.
It is well known that orientational correlations appear in polymer chain models when the subunits are linked by ball-socket joints implemented as rigid constraint conditions. These correlations do not appear when the subunits are connected by springlike potential forces, even in the limit of infinitely stiff springs. In a widely used class of algorithms for Brownian dynamics simulations, inertia effects are ignored. However, in the recently introduced needle chain and nugget chain algorithms, the rigid constraint correlations depend on the mass and moment of inertia. This inconsistency does not appear in the bead-rod (Kramers) polymer chain model, which also has orientational correlations introduced by rigid constraint conditions. Explicit expressions for the correlation functions are given for thermodynamic equilibrium states. Analytical expressions for the associated forces ("metric forces") and simulation results showing how the rigid constraint correlations influence dynamical properties, are also presented. Further we discuss the physical relevance of these correlations and show via simulations that their influence on stationary and dynamical properties depend significantly on chain length. We further show that if the metric forces are removed, algorithms designed with rigid constraint conditions describe a chain of segments connected by infinitely stiff springs. Finally we show that the results presented here for needle chains are relevant also for the bead-rod (Kramers) chain model, making it possible to simulate a bead-spring chain with infinitely stiff springs. 相似文献
749.
Abdul K. Labban Edgar F. Westrum Jr. Helmer Fjellvg Fredrik Grnvold Arne Kjekshus Svein Stlen 《Journal of solid state chemistry》1987,70(2)
The heat capacity of MnAs0.88P0.12 has been measured by adiabatic shield calorimetry from 10 to 500 K. It is shown that very small energy changes are connected with two magnetic order-order transitions, indicating that these can be regarded as mainly “noncoupled” magnetic transitions. At higher temperatures contributions to the excess heat capacity arises from a magnetic order-disorder transition, a conversion from low- to high-spin state for manganese, and a MnP- to NiAs-type structural transition. The observed heat capacity is resolved into contributions from the different physical phenomena, and the character of the transitions is discussed. In particular it is substantiated that the dilational contribution, which includes magnetoelastic and magnetovolume terms as well as normal anharmonicity terms, plays a major role in MnAs0.88P0.12. The entropy of the magnetic order-disorder transition is smaller than should be expected from a complete randomization of the spins, assuming a purely magnetic transition. Thermodynamic functions have been evaluated and the respective values of Cp, {SOm(T) - SOm(0)}, and -{GOm(T) - HOm(0)}/T at 298.15 K are 68.74, 72.09, and 32.30 J K−1 mole−1, and at 500 K 56.05, 108.12, and 56.64 J K−1 mole−1. 相似文献
750.
The empirical Lewis picture of the chemical bond dominates the view chemists have of molecules, of their stability and reactivity. Within the mathematical framework of quantum mechanics, all this chemical information is hidden in the many-particle wave function . Thus, to reveal and understand it, there is great interest in enhancing the Lewis model and connecting it to computable quantities. As has previously been shown, the Lewis picture can often be recovered from the probability density with probabilities in agreement with valence bond weights: the structures appear as most likely positions in the all-electron configuration space. Here, we systematically expand this topological probability density analysis to molecules with multiple bonds and lone pairs, employing correlated Slater-Jastrow wave functions. In contrast to earlier studies, non-Lewis structures are obtained that disagree with the prevalent picture and have a potentially better predictive capability. While functional groups are still recovered with these ab initio structures, the boundary between bonds and lone pairs is mostly blurred or non-existent. In order to understand the newly found structures, the Lewis electron pairs are replaced with spin-coupled electron motifs as the fundamental electronic fragment. These electron motifs—which coincide with Lewis’ electron pairs for many single bonds—arise naturally from the generally applicable analysis presented. An attempt is made to rationalize the geometry of the newly-found structures by considering the Coulomb force and the Pauli repulsion. 相似文献