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11.
Meissner U Gatsogiannis C Moeller A Depoix F Harris JR Markl J 《Micron (Oxford, England : 1993)》2007,38(7):754-765
Hemocyanins are giant extracellular proteins that transport oxygen in the hemolymph of many molluscs. Molluscan hemocyanins are cylindrical decamers or didecamers of a 350-400 kDa subunit that contains seven or eight different covalently linked globular functional units (FUs), arranged in a linear manner. Each FU carries a single copper active site and reversibly binds one dioxygen molecule. As a consequence, the decamer can carry up to 70 or 80 O(2) molecules. Although complete sequence information is now available from several molluscan hemocyanins, many details of the quaternary structure are still unclear, including the topology of the 10 subunits within the decamer. Here we show 3D reconstructions from cryo-electron micrographs of the hemocyanin decamer of Nautilus pompilius (Cephalopoda) and Haliotis tuberculata (Gastropoda) at a resolution of 11A (FSC(1/2-bit) criterion). The wall structure of both hemocyanins is very similar and shows, as in previous reconstructions, three tiers with 20 functional units each that encircle the cylinder wall, and the 10 oblique minor and major wall grooves. However, the six types of wall FUs of the polypeptide subunit, termed a-b-c-d-e-f, are now for the first time individually discernable by their specific orientation, shape, and connections. Also, the internal collar complex of the decamers shows superior resolution which, in this case, reveals striking differences between the two hemocyanins. The five arcs (FU-g pairs) of the central collar (in both hemocyanins) and the five slabs (FU-h pairs) of the peripheral collar (only present in Haliotis hemocyanin), as well as their connections to the wall and to each other are now more clearly defined. The arc is attached to the wall through a feature termed the anchor, a previously undescribed structural element of the hemocyanin wall. 相似文献
12.
Son Tung Dang Ernst Arne Meese John Christian Morud Stein Tore Johansen 《国际流体数值方法杂志》2019,91(9):419-447
In this paper, we introduce numerical methods that can simulate complex multiphase flows. The finite volume method, applying Cartesian cut-cell is used in the computational domain, containing fluid and solid, to conserve mass and momentum. With this method, flows in and around any geometry can be simulated without complex and time consuming meshing. For the fluid region, which involves liquid and gas, the ghost fluid method is employed to handle the stiffness of the interface discontinuity problem. The interaction between each phase is treated simply by wall function models or jump conditions of pressure, velocity and shear stress at the interface. The sharp interface method “coupled level set (LS) and volume of fluid (VOF)” is used to represent the interface between the two fluid phases. This approach will combine some advantages of both interface tracking/capturing methods, such as the excellent mass conservation from the VOF method and good accuracy of interface normal computation from the LS function. The first coupled LS and VOF will be generated to reconstruct the interface between solid and the other materials. The second will represent the interface between liquid and gas. 相似文献
13.
Arne Pfeilsticker 《Fuzzy Sets and Systems》1981,6(3):209-233
Ideas are presented to show how fuzzy mathematics can be applied in macro-economics in combination with the systems approach in order to bridge the gap between mathematical and language-oriented economists.Two reasons are given.From a mathematical point of view, fuzzy sets, fuzzy relations and fuzzy logic are not fuzzy at all. They are all well defined, but tend to be more complicated than traditional, mathematical concepts used in economics.From a language-oriented economist's point of view, fuzzy sets, etc. are used to express mathematically the type of concepts which are typical in language and most valuable in dealing with complex systems like an economy.The paper deals with economics in general terms, but examples are provided to illustrate the ideas. 相似文献
14.
Progressive hedging and tabu search applied to mixed integer (0,1) multistage stochastic programming
Many problems faced by decision makers are characterized by a multistage decision process with uncertainty about the future and some decisions constrained to take on values of either zero or one (for example, either open a facility at a location or do not open it). Although some mathematical theory exists concerning such problems, no general-purpose algorithms have been available to address them. In this article, we introduce the first implementation of general purpose methods for finding good solutions to multistage, stochastic mixed-integer (0, 1) programming problems. The solution method makes use of Rockafellar and Wets' progressive hedging algorithm that averages solutions rather than data. Solutions to the induced quadratic (0,1) mixed-integer subproblems are obtained using a tabu search algorithm. We introduce the notion of integer convergence for progressive hedging. Computational experiments verify that the method is effective. The software that we have developed reads standard (SMPS) data files. 相似文献
15.
Arne Van Antwerpen 《Journal of Pure and Applied Algebra》2018,222(11):3379-3394
In this paper, we show that all Coleman automorphisms of a finite group with self-central minimal non-trivial characteristic subgroup are inner; therefore the normalizer property holds for these groups. Using our methods we show that the holomorph and wreath product of finite simple groups, among others, have no non-inner Coleman automorphisms. As a further application of our theorems, we provide partial answers to questions raised by M. Hertweck and W. Kimmerle. Furthermore, we characterize the Coleman automorphisms of extensions of a finite nilpotent group by a cyclic p-group. Finally, we note that class-preserving Coleman automorphisms of p-power order of some nilpotent-by-nilpotent groups are inner, extending a result by J. Hai and J. Ge, where p is a prime number. 相似文献
16.
The observation of isolated positive and negative charges, but not isolated magnetic north and south poles, is an old puzzle. Instead, evidence of effective magnetic monopoles has been found in the abstract momentum space. Apart from Hall-related effects, few observable consequences of these abstract monopoles are known. Here, we show that it is possible to manipulate the monopoles by external magnetic fields and probe them by universal conductance fluctuation measurements in ferromagnets with strong spin-orbit coupling. The observed fluctuations are not noise, but reproducible quasiperiodic oscillations as a function of magnetization direction, a novel Berry phase fingerprint of the magnetic monopoles. 相似文献
17.
Calculations on Rydberg states are performed using quantum Monte Carlo methods. Excitation energies and singlet-triplet splittings are calculated for two model systems, the carbon atom (3P and 1P) and carbon monoxide ((1Sigma and 3Sigma). Kohn-Sham wave functions constructed from open-shell localized Hartree-Fock orbitals are used as trial and guide functions. The fixed-node diffusion quantum Monte Carlo (FN-DMC) method depends strongly on the wave function's nodal hypersurface. Nodal artefacts are investigated for the ground state of the carbon atom. Their effect on the FN-DMC results can be analyzed quantitatively. FN-DMC leads to accurate excitation energies but to less accurate singlet-triplet splittings. Variational Monte Carlo calculations are able to reproduce the experimental results for both the excitation energies and the singlet-triplet splittings. 相似文献
18.
Holger Ott Christoph Matthes Dr. Arne Ringe Dr. Jörg Magull Prof. Dr. Dietmar Stalke Prof. Dr. Uwe Klingebiel Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(18):4602-4609
Borenes and boranes : Silylaminoiminoborenes, such as depicted, were isolated after treatment of halogen triels with silylaminofluoroboranes. In addition, novel aryl‐ and silyl‐substituted diaminofluoroboranes were also prepared in order to substantiate this reaction route.
19.
This paper describes the stereoselective outcome of the intramolecular Diels-Alder furan (IMDAF) reaction of substituted (2S,3S)-ethanolamides 9-13, which were synthesised from a furyl substituted cyanohydrin. The latter was obtained from 2-furaldehyde with high enantioselectivity by an oxynitrilase catalysed addition of hydrogen cyanide. The stereochemistry of the IMDAF products was shown to be dependent on the size of the ethanolamide substituents R. Small substituents (H, Me, CN) gave exclusively exo-cycloaddition, whereas more bulky ones (Ph, Et) gave both evo- and endo-addition, the larger phenyl substituent giving a high endo-exo-ratio. 相似文献
20.