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121.
122.
Shah U Chackalamannil S Ganguly AK Chelliah M Kolotuchin S Buevich A McPhail A 《Journal of the American Chemical Society》2006,128(39):12654-12655
The first total synthesis of (-)-himgaline and a highly enantioselective synthesis of its congener (-)-GB 13 are described. Decarboxylative aza-Michael reaction of the hexacyclic lactone precursor under acidic conditions, followed by basic workup, yielded (-)-GB 13 in 80% yield. Cyclization of (-)-GB 13 to oxohimgaline under acidic conditions, followed by internally coordinated sodium triacetoxyborohydride reduction, gave (-)-himgaline as the exclusive product. 相似文献
123.
The design and construction of nanostructured materials using proper self-assembling molecular building blocks is a real challenge to scientists. Here, we present the formation of a new nano-architecture, i.e., nanostaircase in the solid state by using molecular building blocks, which are amenable to self-assembly in a directed manner to form the specific nanostructure. The molecular building blocks are terephthalamides 1-4, which are bis-terephthalamides of methyl esters of various α-amino acids including l-leucine 1, d-leucine 2, l-isoleucine 3, and α-aminoisobutyric acid (Aib) 4. All terephthalamides presented here, irrespective of their different side chain residues or stereochemistry, self-assemble to form supramolecular nanostaircase structures in crystals. Each terephthalamide contains two good hydrogen-bond donors and two hydrogen-bond acceptors. Two N-H?O hydrogen bonds and C-H?π interactions are responsible for the formation and stabilization of the nanostaircase structures in crystals. The molecular building blocks are packed orthogonally to each other in crystals and this arrangement can help the formation of nanostaircase structure upon self-assembly. 相似文献
124.
Moloy Kumar Banerjee Debabrata Nag Ranjan Ganguly 《International Journal of Computational Fluid Dynamics》2013,27(9):609-610
A numerical analysis of blood flow in a rigid artery has been performed to observe the variations in flow pattern and haemodynamic parameters under the influence of multiple (double) stenoses. The interspacing distance, degree of stenotic severity and Reynolds number of flow have been varied. It is found that two stenoses interact when the interspacing distance is lower than a critical value that corresponds to the redevelopment length of fully developed flow after the proximal stenosis. In the case of non-interacting stenoses the haemodynamic parameters, like the peak centreline velocity (representing the peak systolic velocity ratio in medical term), the maximum wall shear stress, region of low shear stress and the irrecoverable pressure drop at the stenosis site, repeat themselves at each individual stenosis. However, when the stenoses interact hydrodynamically because of their proximity, the parameters behave differently, which can lead to a different haemodynamic profile in the arteries and pose difficulties in their pathological interpretation. This work evaluates the influence of double stenoses on the variations in the key haemodynamic features under different degree of stenoses and interspacing distance between the stenoses. 相似文献
125.
We report an incipient exploration of the Lense‐Thirring precession effect in a rotating acoustic analogue black hole spacetime. An exact formula is deduced for the precession frequency of a gyroscope due to inertial frame dragging, close to the ergosphere of a ‘Draining Bathtub’ acoustic spacetime which has been studied extensively for acoustic Hawking radiation of phonons and also for ‘superresonance’. The formula is verified by embedding the two dimensional spatial (acoustic) geometry into a three dimensional one where the similarity with standard Lense‐Thirring precession results within a strong gravity framework is well known. Prospects of experimental detection of this new ‘fixed‐metric’ effect in acoustic geometries, are briefly discussed. 相似文献
126.
Kar P Banerjee T Verma S Sen A Das A Ganguly B Ghosh HN 《Physical chemistry chemical physics : PCCP》2012,14(22):8192-8198
We have synthesized a new photoactive rhenium(i)-complex having a pendant catechol functionality [Re(CO)(3)Cl(L)] (1) (L is 4-[2-(4'-methyl-2,2'-bipyridinyl-4-yl)vinyl]benzene-1,2-diol) for studying the dynamics of the interfacial electron transfer between nanoparticulate TiO(2) and the photoexcited states of this Re(i)-complex using femtosecond transient absorption spectroscopy. Our steady state absorption studies revealed that complex 1 can bind strongly to TiO(2) surfaces through the catechol functionality with the formation of a charge transfer (CT) complex, which has been confirmed by the appearance of a new red-shifted CT band. The longer wavelength absorption band for 1, bound to TiO(2) through the proposed catecholate functionality, could also be explained based on the DFT calculations. Dynamics of the interfacial electron transfer between 1 and TiO(2) nanoparticles was investigated by studying kinetics at various wavelengths in the visible and near infrared regions. Electron injection into the conduction band of the nanoparticulate TiO(2) was confirmed by detection of the conduction band electron in TiO(2) ([e(-)](TiO(2)(CB))) and the cation radical of the adsorbed dye (1˙(+)) in real time as monitored by transient absorption spectroscopy. A single exponential and pulse-width limited (<100 fs) electron injection was observed. Back electron transfer dynamics was determined by monitoring the decay kinetics of 1˙(+) and . 相似文献
127.
Ganguly HK Majumder B Chattopadhyay S Chakrabarti P Basu G 《Journal of the American Chemical Society》2012,134(10):4661-4669
Although weak interactions play subtle but important roles in dictating protein structures, their experimental detection is nontrivial. From NOE experiments we provide direct evidence for the presence of CH···π interaction, operational between the C(α)-H of the first Pro and the aromatic (Aro) side chain of Xaa, in a peptide series with the general sequence Ac-Pro-Pro-Xaa-NH(2). Indirect evidence of CH···π interaction is provided from ring current-induced upfield displacement of Pro(1) C(α)-H chemical shifts and restriction of side-chain (χ1) rotation of Xaa. A consequence of this interaction is the enhanced stability of the Pro-cisPro conformer in Ac-Pro-Pro-Xaa-NH(2) when Xaa is aromatic. The free energies associated with trans to cis transformation of the Pro-Pro moiety are 0.35, 0.59, 0.64, and 0.82 kcal/mol when Xaa is Tyr, Trp, Phe, and His (pH of 8.4), respectively. In comparison, the corresponding free energy is ~1.55 kcal/mol when Xaa is nonaromatic. The observed population of Pro-cisPro-His and the pH-induced perturbation of electron density of the His side chain were correlated, providing further evidence for a direct role of CH···π interaction in modulating the stability of Pro-cisPro population in Ac-Pro-Pro-Aro-NH(2). Our study establishes Pro-Pro-Aro to be a new sequence motif that can stabilize Pro-cisPro peptide bonds. This study not only identifies a new structurally biased sequence motif but also directly demonstrates the role played by CH···π interactions in subtly altering conformational preferences of three-residue peptide sequences with implications on the role played by cis-peptide bonds in unfolded proteins. 相似文献
128.
Pranabendu Ganguly 《Optics Communications》2012,285(21-22):4347-4352
Lithium niobate (LiNbO3) photonic wires are of growing interest in the field of nonlinear optics and to fabricate micro-ring resonators. In this paper the design and analysis of LiNbO3 photonic wires by a semi-analytical technique is presented. The two-dimensional refractive index profile of the waveguide is transformed into lateral one-dimensional equivalent-index profile by the effective-index method. A transfer matrix method is then applied to this lateral equivalent-index profile of the waveguide to determine the propagation constants and electric-field distributions of the guided modes. Single mode photonic wires at 1.31 μm transmitting wavelength are designed for both TE and TM polarizations and finally, the matrix method is employed along with the conformal mapping technique to determine the bending loss of the curved photonic wires for different radii of curvature. The process needs less computation power, both in terms of elapsed time and memory, and can also be applicable to other photonic materials. 相似文献
129.
J Mondal A Modak A Dutta S Basu SN Jha D Bhattacharyya A Bhaumik 《Chemical communications (Cambridge, England)》2012,48(64):8000-8002
Surface functionalization of SBA-15 followed by its reaction with Cu(OAc)(2) has been carried out to develop a new Cu-grafted functionalized mesoporous material, which catalyzes one-pot three component coupling of different aryl halides with thiourea and benzyl bromide in aqueous medium to produce aryl thioethers in very good yields (80-88%). 相似文献
130.
Mainak Ganguly Dr. Anjali Pal Dr. Yuichi Negishi Prof. Tarasankar Pal 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(49):15845-15855
The condensation products of salicylaldehyde and different diamines constitute an important class of diiminic Schiff bases (DSBs). This class of compounds has been rediscovered as reducing as well as capping agents under UV irradiation. UV irradiation of alkaline DSB solutions in the presence of water‐soluble copper salts has been employed to produce copper nanoparticles (CuNPs). Intriguing CuNP‐stimulated fluorescence behavior of the solution has been observed. Depending upon the nature of the spacer in between two iminic bonds, fluorescence enhancement or quenching is observed. Such surprising fluorescence contrast has been ascribed to far‐field radiation and lossy surface waves. 相似文献