Completely random nanoporous Cu4O3–CuO–C composite thin films for potential application as multiple channel photonic band gap based filter in the telecommunication wavelengths

In 2003, Babin et al. theoretically predicted (J. Appl. Phys. 94:4244, 2003) that fabrication of organic–inorganic hybrid materials would probably be required to implement structures with multiple photonic band gaps. In tune with their prediction, we report synthesis of such an inorganic–organic nanocomposite, comprising Cu₄O₃–CuO–C thin films that experimentally exhibit the highest (of any known material) number (as many as eleven) of photonic band gaps in the near infrared. On contrary to the report by Wang et al. (Appl. Phys. Lett. 84:1629, 2004) that photonic crystals with multiple stop gaps require highly correlated structural arrangement such as multilayers of variable thicknesses, we demonstrate experimental realization of multiple stop gaps in completely randomized structures comprising inorganic oxide nanocrystals (Cu₄O₃ and CuO) randomly embedded in a randomly porous carbonaceous matrix. We report one step synthesis of such nanostructured films through the metalorganic chemical vapor deposition technique using a single source metalorganic precursor, Cu₄(deaH)(dea)(oAc)₅???(CH₃)₂CO. The films displaying multiple (4/9/11) photonic band gaps with equal transmission losses in the infrared are promising materials to find applications as multiple channel photonic band gap based filter for WDM technology.     

Determination of the orientational order parameter of the homologous series of 4-cyanophenyl 4-alkylbenzoate (n.CN) by different methods

The orientational order parameters of a homologous series of 4-cyanophenyl 4-alkylbenzoates have been determined at different temperatures from (13)C-NMR, x-ray diffraction, optical birefringence, high resolution density and diamagnetic susceptibility anisotropy measurements. To determine the temperature dependence of the orientational order parameter from the (13)C chemical shift values, the two-dimensional polarization inversion spin exchange at the magic angle (PISEMA) method was also used for the measurement of (13)C-(1)H dipolar couplings at different sites in the oriented phase. The nematic order parameters determined from each of these methods have been compared. Apart from a slight shift in their values their trends with temperature are very similar. The differences among the results obtained by these five different methods have been discussed. From the high resolution density data, the values of the critical exponents near the T(N-I) transition are found to lie between the Ising model and tricritical behaviour.     

Testing the sign-changing superconducting gap in iron-based superconductors with quasiparticle interference and neutron scattering

We present a phenomenological calculation of the quasiparticle interference (QPI) pattern and inelastic neutron scattering (INS) spectra in iron-pnictide and layered iron-selenide compounds by using material specific band structure and superconducting (SC) gap properties. As both the QPI and the INS spectra arise due to scattering of the Bogolyubov quasiparticles, they exhibit a one-to-one correspondence of the scattering vectors and the energy scales. We show that these two spectroscopies complement each other in such a way that a comparative study allows one to extract quantitative and unambiguous information about the underlying pairing structure and the phase of the SC gap. Due to the nodeless and isotropic nature of the SC gaps, both the QPI and INS maps are concentrated at only two energies in pnictide (two SC gaps) and one energy in iron-selenide, while the associated scattering vectors q for scattering of sign-changing and same sign of the SC gaps change between these spectroscopies. The results presented, particularly for the newly discovered iron-selenide compounds, can be used to test the nodeless d-wave pairing in this class of high temperature superconductor.     

On properties of <Emphasis Type="Italic">G</Emphasis>-expansive homeomorphisms

We show that LUB of the set of G-expansive constants for a G-expansive homeomorphism h on a compact metric G-space, G compact, is not a G-expansive constant for h. We obtain a result regarding projecting and lifting of G-expansive homeomorphisms having interesting applications. We also prove that the G-expansiveness is a dynamical property for homeomorphisms on compact metric G-spaces and study G-periodic points.     

Cosine of angle and center of mass of an operator

We consider the notion of real center of mass and total center of mass of a bounded linear operator relative to another bounded linear operator and explore their relation with cosine and total cosine of a bounded linear operator acting on a complex Hilbert space. We give another proof of the Min-max equality and then generalize it using the notion of orthogonality of bounded linear operators. We also illustrate with examples an alternative method of calculating the antieigenvalues and total antieigenvalues for finite dimensional operators.     

Restricting statistical convergence

We first introduce a new notion called statistical convergence of order α and primarily show that it gives rise to a decreasing chain of closed linear subspaces of the space of all bounded real sequences with sup norm which never coincides with the class of convergent sequences and in fact their intersection properly contains the class of convergent sequences. We then show that the same method can be applied for double sequences also and introduce the notion of statistical convergence of order (α,β).     

Novel approach for modelling of nanomachining using a mesh-less method

In this paper, a mesh-less method, called Smoothed Particle Hydrodynamics (SPH) is used to simulate the nanomachining operation in order to assist with the understanding of the fundamental mechanisms of nano scale material deformation and the characteristics of the post machined surface. An elasto-plastic nano-machining analysis is used to form a nano-groove using a conical tool on a copper specimen. The SPH solutions are validated against nano scale machining experiments conducted using a nanoindenter. The simulated results showed that the normal force is greater than the cutting force in this nano scale machining operation, which is consistent with the experimental results. Both the ploughing and cutting mechanisms were observed in these machining conditions and increased with the increase of the depth of cut. Moreover, the results reveal that the larger negative rake angle reduced the ploughing mechanism and caused higher residual stress and strain along the machined surface. Therefore, the effect of machining parameters on the nano deformation mechanism and the quality of the machined surface can be rapidly assessed using SPH.     

Design,synthesis, preliminary pharmacological evaluation,and docking studies of pyrazoline derivatives

Ten derivatives of N1 substituted/unsubstituted 5-(4-chlorophenyl)-3-(2-thienyl) pyrazoline were synthesised from chalcone-like intermediate and substituted phenyl hydrazines, hydrazine hydrate, and semi/thiosemicarbazide. The chemical structure of compounds was confirmed by means of IR, ¹H NMR, mass spectroscopy, and elemental analysis. The antidepressant and anticonvulsant activities were investigated by Porsolt’s behavioural despair test (forced swimming) and maximum electroshock seizure test, respectively. Rota-Rod test was performed to assess any probable changes in motor coordination induced by the test compounds. Four compounds (IId, IIg, IIi, and IIj) exhibited good activity profile against depression and docking studies confirmed their consensual interaction with monoamine oxidase A. In addition, compounds IIc and IIe showed protection against MES-induced seizures.