排序方式: 共有79条查询结果,搜索用时 15 毫秒
51.
Lubricating oils are used to decrease wear and friction of movable parts of engines and turbines, being in that way essential for the performance and the increase of that equipment lifespan. The presence of some metals shows the addition of specific additives such as detergents, dispersals and antioxidants that improve the performance of these lubricants. In this work, a method for determination of calcium, magnesium and zinc in lubricating oil by flame atomic absorption spectrometry (F AAS) was developed. The samples were diluted with a small quantity of aviation kerosene (AVK), n-propanol and water to form a three-component solution before its introduction in the F AAS. Aqueous inorganic standards diluted in the same way have been used for calibration. To assess the accuracy of the new method, it was compared with ABNT NBR 14066 standard method, which consists in diluting the sample with AVK and in quantification by F AAS. Two other validating methods have also been used: the acid digestion and the certified reference material NIST (SRM 1084a). The proposed method provides the following advantages in relation to the standard method: significant reduction of the use of AVK, higher stability of the analytes in the medium and application of aqueous inorganic standards for calibration. The limits of detection for calcium, magnesium and zinc were 1.3 μg g−1, 0.052 μg g−1 and 0.41 μg g−1, respectively. Concentrations of calcium, magnesium and zinc in six different samples obtained by the developed method did not differ significantly from the results obtained by the reference methods at the 95% confidence level (Student's t-test and ANOVA). Therefore, the proposed method becomes an efficient alternative for determination of metals in lubricating oil. 相似文献
52.
Popescu DL Vrabel M Brausam A Madsen P Lente G Fabian I Ryabov AD van Eldik R Collins TJ 《Inorganic chemistry》2010,49(24):11439-11448
Stopped-flow kinetic studies of the oxidation of Fe(III)-TAML catalysts, [ F e{1,2-X(2)C(6)H(2)-4,5-( NCOCMe(2) NCO)(2)CMe(2)}(OH(2))](-) (1), by t-BuOOH and H(2)O(2) in water affording Fe(IV) species has helped to clarify the mechanism of the interaction of 1 with primary oxidants. The data collected for substituted Fe(III)-TAMLs at pH 6.0-13.8 and 17-45 °C has confirmed that the reaction is first order both in 1 and in peroxides. Bell-shaped pH profiles of the effective second-order rate constants k(I) have maximum values in the pH range of 10.5-12.5 depending on the nature of 1 and the selected peroxide. The "acidic" part is governed by the deprotonation of the diaqua form of 1 and therefore electron-withdrawing groups move the lower pH limit of the reactivity toward neutral pH, although the rate constants k(I) do not change much. The dissection of k(I) into individual intrinsic rate constants k(1) ([FeL(OH(2))(2)](-) + ROOH), k(2) ([FeL(OH(2))OH)](2-) + ROOH), k(3) ([FeL(OH(2))(2)](-) + ROO(-)), and k(4) ([FeL(OH(2))OH)](2-) + ROO(-)) provides a model for understanding the bell-shaped pH-profiles. Analysis of the pressure and substituent effects on the reaction kinetics suggest that the k(2) pathway is (i) more probable than the kinetically indistinguishable k(3) pathway, and (ii) presumably mechanistically similar to the induced cleavage of the peroxide O-O bond postulated for cytochrome P450 enzymes. The redox titration of 1 by Ir(IV) and electrochemical data suggest that under basic conditions the reduction potential for the half-reaction [Fe(IV)L(=O)(OH(2))](2-) + e(-) + H(2)O → [Fe(III)L(OH)(OH(2))](2-) + OH(-) is close to 0.87 V (vs NHE). 相似文献
53.
54.
Bjoern Moosmann Stefan Kneisel Ariane Wohlfarth Volker Brecht Volker Auwärter 《Analytical and bioanalytical chemistry》2013,405(12):3929-3935
In the age of the Internet, the variety of drugs offered online is constantly increasing, and new drugs emerge every month. One group of drugs showing such an enormous increase is that of synthetic cannabinoids. Since their first identification in ‘herbal mixtures’, new structural modifications continue to appear on the market. In order to keep up with this process, toxicological screening methods need to be up to date. This can become extremely difficult if no reference material is available. In this article, a fast and effective way to extract and purify synthetic cannabinoids from ‘herbal mixtures’ is presented. This method opens a new opportunity for a timely reaction by obtaining reference material straight out of the ‘herbal mixtures’ ordered via the Internet. Isolation was carried out on a flash chromatography system with gradient elution on a C18 column using methanol and 0.55 % formic acid as mobile phases. The obtained purity of all compounds exceeded 99 %. In addition to the isolation of single compounds, the method proved to be suitable for the separation of various synthetic cannabinoids in one mixture, including the diastereomers cis- and trans-CP-47,497-C8. This approach for obtaining pure standards of new drugs proved to be effective, inexpensive and much quicker than waiting for the substances to be commercially available as reference material. Figure
Flash chromatography method for the isolation of synthetic cannabinoids from ‘herbal mixtures’ to obtain pure reference standards. 相似文献
55.
Valérie Marvaud Juan M. Herrera Thomas Barilero Fabien Tuyeras Raquel Garde Ariane Scuiller Caroline Decroix Martine Cantuel Cédric Desplanches 《Monatshefte für Chemie / Chemical Monthly》2003,134(2):149-163
This paper points out some recent achievements in the chemistry and physics of high spin and anisotropic molecules based
on polycyanometalate complexes. Following a step by step synthetic strategy and using a localized electron orbital model,
isotropic high spin molecules were obtained with ground spin states ranging from S = 9/2 to 27/2. In the same way, anisotropic molecules with various nuclearities (bi, tri, tetra, hexa, and hepta-nuclear
complexes) have been synthesized. Mixing these two approaches, it has been possible to obtained anisotropic high spin molecules
that behave as single molecule magnets. The paper reviews some of the steps that lead to these findings and some of the prospects
opened in the field of single molecule magnets.
Corresponding author. E-mail: marvaud@ccr.jussieu.fr
Received July 19, 2002; accepted July 23, 2002 相似文献
56.
LetC be a generically smooth, locally complete intersection curve defined over an algebraically closed fieldk of characteristicp≥0. LetG⊃ Aut
k
C be a finite group of automorphisms ofC. We develop a theory ofG-equivariant deformations of the Galois coverC→C/G. We give a thorough study of the local obstructions, those localized at singular or widely ramified points, to deform equivariantly
a cover. As an application, we discuss the case ofG-equivariant deformations of semistable curves.
相似文献
57.
Fuchs Beate Schiller Jürgen Süß Rosmarie Nimptsch Ariane Schürenberg Martin Suckau Detlev 《平面色谱法杂志一现代薄层色谱法》2009,22(1):35-42
JPC – Journal of Planar Chromatography – Modern TLC - Lipids are important natural products and essential in nutrition, cosmetic formulations, pharmaceuticals, etc. Lipids and,... 相似文献
58.
Let X/S be a semistable curve equipped with the action of a finite group G and let H be a normal subgroup of G. The main result of this paper is the following. If the action of G is free on an open dense set on any geometric fiber, then for any base change TS, (X/G)×ST is isomorphic to (X×ST)/G. As an application, this allows us to define induction and restriction morphisms between the G-equivariant deformation functor of X and the G/H-equivariant (resp. H-equivariant) deformation functor of X/H (resp. X).
Résumé. Soit X/S une courbe semi-stable munie de laction dun groupe fini G. Soit H un sous-groupe normal de G. Nous proposons une nouvelle condition sous laquelle (X/G)×ST est isomorphe à (X×ST)/G quel que soit le changement de base TS : il suffit que sur toutes les fibres géométriques, laction de G soit libre sur un ouvert dense. Comme application de ce résultat nous définissons des morphismes dinduction et de restriction entre le foncteur de déformations G-équivariantes de X et le foncteur de déformations G/H-équivariantes (resp. H-équivariantes) de X/H (resp. X).相似文献
59.
Marvaud V Decroix C Scuiller A Guyard-Duhayon C Vaissermann J Gonnet F Verdaguer M 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(8):1677-1691
Following a bottom-up approach to nanomaterials, we present a rational synthetic route from hexacyanometalates [M(CN)(6)](3-) (M=Cr(III), Co(III)) cores to well-defined heptanuclear complexes. By changing the nature of the metallic cations and using a localised orbital model it is possible to control and to tune the ground state spin value. Thus, with M=Cr(III), d(3), S=3/2, three heptanuclear species were built and characterised by mass spectrometry in solution, by single-crystal X-ray diffraction and by powder magnetic susceptibility measurements, [Cr(III)(CNbondM'L(n))(6)](9+) (M'=Cu(II), Ni(II), Mn(II), L(n)=polydentate ligand), showing spin ground states S(G)=9/2 [Cu(II)], with ferromagnetic interactions J(Cr,Cu)=+45 cm(-1), S(G)=15/2 [Ni(II)] and J(Cr,Ni)=+17.3 cm(-1), S(G)=27/2 [Mn(II)], with an antiferromagnetic interaction J(Cr,Mn)=-9 cm(-1), (interaction Hamiltonian H=-J(Cr,M) [S(Cr)Sigma(i)S(M)(i)], i=1-6). With M=Co(III), d(6), S=0, the heptanuclear analogues [Co(III)(CN-M'L(n))(6)](9+) (M'=Cu(II), Ni(II), Mn(II)) were similarly synthesised and studied. They present a singlet ground state and allow us to evaluate the weak antiferromagnetic coupling constant between two next-nearest neighbours M'-Co-M'. 相似文献
60.
Molecules that associate to form porous networks can be made by attaching multiple hydrogen-bonding sites to suitable cores. Pentaerythrityl tetraphenyl ether, a four-armed core, is the progenitor of dendritic derivatives with more arms, including dipentaerythrityl hexaphenyl ether 7. An advantage of such dendritic derivatives is that the resulting networks are held together by larger numbers of intermolecular hydrogen bonds. [structure: see text] 相似文献