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71.
Nanocrystalline samples of Pb1−yLay(Ti1−xMnx)(1−y/4)O3 (PLMT) (y=0.06, x=0, 0.04, 0.07 and 0.10) were prepared by mechanical activation process (i.e., ball milling) followed by some annealing. The formation of single phase tetragonal crystal structure is confirmed by high-resolution X-ray diffraction study and by High resolution transmission electron micrographs (HRTEM), nano-scale compounds. The electrical behavior (i.e., impedance (Z) and electrical modulus (M)) of PLMT ceramics was studied by impedance spectroscopy technique in high temperature range. This study was carried out by means of the simultaneous analysis of the complex impedance (Z?) and electrical modulus (M*) functions in a wide frequency range (1 kHz-1 MHz). Impedance analysis has shown the grain and grain boundary contributions by an equivalent circuit model. Modulus analysis has provided vast information on charge transport processes. The simultaneous representation of the imaginary part of impedance and electric modulus (Z″, M″) vs. frequency revealed the localization of relaxation. The activation energy obtained from relaxation data may be attributed to oxygen ion vacancies. 相似文献
72.
We report ab-initio calculations of the structural, electronic, magnetic and optical properties of the alloy Cd1-xMnxTe as a function of the Mn concentration ‘x’. Ab-initio calculations are based on the density functional theory (DFT) within the generalized gradient approximation (GGA). The calculated lattice constants of the Cd1-xMnxTe alloys exhibit Vegard's law downward bowing parameter. For the minority spin channel the Fermi level shifts toward higher energy with the value of ‘x’ in Cd1-xMnxTe. The spin-exchange splitting energy Δx(d) increases with increasing ‘x’ in Cd1-xMnxTe and the values of p-d exchange splitting energy Δx(pd) of Cd1-xMnxTe show that the effective potential for the minority spin is more attractive than that for the majority spin. The values of exchange constants N0α and N0β obtained for Cd1-xMnxTe are in agreement with the reported data. The magnetic moment per Mn atom reduces from its free space charge value of 5μB to around 4μB due to p-d hybridization and this results into an appearance of small local magnetic moments on the non-magnetic Cd and Te sites. The absorption threshold shifts toward higher energy and the static refractive index decreases with the increasing value of ‘x’ in Cd1-xMnxTe. 相似文献
73.
U.P. Verma Sonu SharmaNisha Devi P.S. BishtP. Rajaram 《Journal of magnetism and magnetic materials》2011,323(5):394-399
We have investigated the structural, electronic and magnetic properties of the diluted magnetic semiconductor (DMS) Cd1−xMnxTe (for x=0.75 and 1.0) in the zinc blende (B3) phase by employing the ab-initio method. Calculations were performed by using the full potential linearized augmented plane wave plus local orbitals (FP-L/APW+lo) method within the frame work of spin-polarized density functional theory (SP-DFT). The electronic exchange-correlation energy is described by generalized gradient approximation (GGA). We have calculated the lattice parameters, bulk modulii and the first pressure derivatives of the bulk modulii, spin-polarized band structures, and total and local densities of states. We estimated the spin-exchange splitting energies Δx(d) and Δx(pd) produced by the Mn3d states, and we found that the effective potential for the minority spin is more attractive than that of the majority spin. We determine the s-d exchange constant N0α (conduction band) and p-d exchange constant N0β (valence band) and these somewhat agree with a typical magneto-optical experiment. The value of calculated magnetic moment per Mn impurity atom is found to be 4.08 μB for Cd0.25Mn0.75Te and 4.09 μB for Cd0.0Mn1.0Te. Moreover, we found that p-d hybridization reduces the local magnetic moment of Mn from its free space charge value of 5.0 μB and produces small local magnetic moments on the nonmagnetic Cd and Te sites. 相似文献
74.
75.
Dehydration of 1,4-dioxane through blend membranes of poly(vinyl alcohol) and chitosan by pervaporation 总被引:1,自引:0,他引:1
D. Anjali Devi B. Smitha S. Sridhar T.M. Aminabhavi 《Journal of membrane science》2006,280(1-2):138-147
Blend membranes prepared from poly(vinyl alcohol) (PVA) and chitosan (CS) were crosslinked with glutaraldehyde and used in the pervaporation dehydration of 1,4-dioxane. Membranes were characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and X-ray diffraction (X-RD) to assess, respectively, the intermolecular interactions, thermal stability and crystallinity. Equilibrium sorption studies were carried out in pure liquids and binary mixtures of different compositions of water + 1,4-dioxane mixtures to assess the polymer–liquid interactions. The crosslinked membrane showed a good potential in breaking the azeotrope of 82 wt.% aqueous 1,4-dioxane giving a selectivity of 117 with a reasonable water flux of 0.37 kg/m2 h. The effect of operating parameters such as feed composition, membrane thickness and permeate pressure was evaluated. 相似文献
76.
P Sujatha Devi 《Journal of Non》2004,336(2):128-134
Vanadium doped silica gels were prepared from tetraethyl orthosilicate and three different inorganic vanadium precursors with formal oxidation states of V3+, V4+ and V5+ respectively. Optical and EPR studies were carried out on the dried gels to understand the changes in the oxidation state and coordination of vanadium in the doped silica gel matrix. The observed optical and EPR results provide very strong evidence to establish that irrespective of the starting material, vanadium is stabilized as vanadyl ion in the gel monoliths. EPR studies on the powdered samples corroborate the optical data on the gel samples and confirmed that the stabilized vanadyl ion is situated in a distorted octahedral geometry in these silica gels. 相似文献
77.
Shiva Raj Sarala Devi Ch. Seshikala G. Ram Reddy M. G. 《Journal of Chemical Sciences》1992,104(1):15-20
The proton ligand constants of 4-chloro and 4-amino picolinic acid N-oxide and the formation constants of corresponding binary
chelates of Cu(II) and Ni(II) have been measured at 30°C and 0.1M ionic strength in varying percentages of dioxane-water,
acetone-water, ethanol-water and isopropanol-water. The results are discussed with reference to the change in dielectric constants
of water in the presence of organic solvent, change in the structuredness of water, change in hydrogen bonding ability of
the organic solvent in water, solvent basicity and proton solvation by organic solvent. The values have been compared with
aqueous and mixed aqueous systems of picolinic acid N-oxide and 4-methoxy picolinic acid N-oxide. 相似文献
78.
A. R. Usha Devi R. Prabhu M. S. Uma 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,40(1):133-138
Production and analysis of non-Gaussian radiation fields has evinced a lot of attention recently.
Simplest way of generating such non-Gaussians is through adding (subtracting) photons to
Gaussian fields.
Interestingly, when photons are added to classical Gaussian fields, the resulting states exhibit
non-classicality.
Two important classical Gaussian radiation fields are coherent and thermal states. Here, we
study the non-classical features of
such states when photons are added to them. Non-classicality of these states shows up in the
negativity of the
Wigner function. We also work out the entanglement potential, a recently proposed measure
of non-classicality for these states. Our analysis reveals that photon added coherent states are
non-classical for all seed beam intensities; their non-classicality increases with the addition
of more number of photons. Thermal state exhibits non-classicality at all temperatures, when a
photon is added; lower the temperature, higher is their non-classicality. 相似文献
79.
Nonsteroidal Anti‐inflammatory Drug‐based N‐Allylidene Benzohydrazides and 1‐Acyl‐2‐pyrazolines: Their Synthesis as Potential Cytotoxic Agents In Vitro 下载免费PDF全文
Kavitha Kankanala V. Ranga Reddy Yumnam Priyadarshini Devi Lakshmi Narasu Mangamoori D. Rambabu K. Mukkanti Sarbani Pal 《Journal of heterocyclic chemistry》2015,52(1):105-113
A series of 1‐acyl‐2‐pyrazoline derivatives derived from nonsteroidal anti‐inflammatory drugs was designed as potential anticancer agents. Synthesis of these compounds was carried out via the condensation reaction of chalcones and acid hydrazides under heating. The methodology did not require the use of any costly reagents or catalysts, and the acid hydrazide reactants were readily prepared from mefenamic acid or ibuprofen. A variety of 1‐acyl‐2‐pyrazolines was prepared in good to excellent yields. An N‐allylidene benzohydrazide intermediate was isolated during the reaction optimization study, the structure of which was confirmed unambiguously by X‐ray single crystal data. A range of N‐allylidene benzohydrazides were also prepared in good yields. Some of the compounds synthesized showed promising cytotoxic activities when tested against HCT‐15 human colon cancer cell line in vitro. 相似文献
80.
Study of the forced degradation behavior of prasugrel hydrochloride by liquid chromatography with mass spectrometry and liquid chromatography with NMR detection and prediction of the toxicity of the characterized degradation products 下载免费PDF全文
Dilip Kumar Singh Archana Sahu Tarun Handa Mallikarjun Narayanam Saranjit Singh 《Journal of separation science》2015,38(17):2995-3005
Prasugrel was subjected to forced degradation studies under conditions of hydrolysis (acid, base, and neutral), photolysis, oxidation, and thermal stress. The drug showed liability in hydrolytic as well as oxidative conditions, resulting in a total of four degradation products. In order to characterize the latter, initially mass fragmentation pathway of the drug was established with the help of mass spectrometry/time‐of‐flight, multiple stage mass spectrometry and hydrogen/deuterium exchange data. The degradation products were then separated on a C18 column using a stability‐indicating volatile buffer method, which was later extended to liquid chromatography‐mass spectrometry studies. The latter highlighted that three degradation products had the same molecular mass, while one was different. To characterize all, their mass fragmentation pathways were established in the same manner as the drug. Subsequently, liquid chromatography‐nuclear magnetic resonance (NMR) spectroscopy data were collected. Proton and correlation liquid chromatography with NMR spectroscopy studies highlighted existence of diastereomeric behavior in one pair of degradation products. Lastly, toxicity prediction by computer‐assisted technology (TOPKAT) and deductive estimation of risk from existing knowledge (DEREK) software were employed to assess in silico toxicity of the characterized degradation products. 相似文献