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81.
Fe3O4–Schiff base of Cu(II) is found to be a recyclable and heterogeneous catalyst for the rapid and efficient synthesis of various 2,3‐dihydroquinazolin‐4(1H)‐one derivatives from the two‐component condensation of 2‐aminobenzamide and an aldehyde. This reaction is simple, green and cost‐effective. Separation and recycling can also be easily done by magnetic decantation of the Fe3O4 nanoparticles with an external magnet. The prepared catalyst was characterized using thermogravimetry, Fourier transform infrared spectroscopy, vibrating sample magnetometry, inductively coupled plasma analysis, X‐ray diffraction and scanning electron microscopy. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
82.
Journal of Thermal Analysis and Calorimetry -  相似文献   
83.
Synthetic polymers represent a modifiable class of materials that can serve as adjuvants to address challenges in numerous biomedical and medicinal chemistry applications including the delivery of siRNA. Polymer‐based therapeutics offer unique challenges in both synthesis and characterization as compared to small molecule therapeutics. The ability to control the structure of the polymer is critical in creating a therapeutic. Reported herein, are batch and flow polymerization processes to produce amphiphilic terpolymers through a Lewis acid BF3OEt2‐catalyzed polymerization. These processes focus on controlling reaction variables, which affect polymer structure in this rapid, exothermic, nonliving cationic polymerization. In addition to analytical characterization of the polymers, the in vivo activity of the polymer‐siRNA conjugates is also highlighted—demonstrating that the method of synthesis does affect the in vivo activity of the resulting polymer conjugate. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1119–1129  相似文献   
84.
Research on Chemical Intermediates - 3-[(3-(Trisilyloxy)propyl)chloride]-1-methylimidazolium tribromide ionic liquid supported on MCM-41 [nano-MCM-41@(CH2)3-1-methylimidazole]Br3 as a novel...  相似文献   
85.
For digraphs D and H, a mapping f:V(D)→V(H) is a homomorphism ofDtoH if uvA(D) implies f(u)f(v)∈A(H). For a fixed directed or undirected graph H and an input graph D, the problem of verifying whether there exists a homomorphism of D to H has been studied in a large number of papers. We study an optimization version of this decision problem. Our optimization problem is motivated by a real-world problem in defence logistics and was introduced recently by the authors and M. Tso.Suppose we are given a pair of digraphs D,H and a cost ci(u) for each uV(D) and iV(H). The cost of a homomorphism f of D to H is ∑uV(D)cf(u)(u). Let H be a fixed digraph. The minimum cost homomorphism problem for H, MinHOMP(H), is stated as follows: For input digraph D and costs ci(u) for each uV(D) and iV(H), verify whether there is a homomorphism of D to H and, if it does exist, find such a homomorphism of minimum cost. In our previous paper we obtained a dichotomy classification of the time complexity of when H is a semicomplete digraph. In this paper we extend the classification to semicomplete k-partite digraphs, k≥3, and obtain such a classification for bipartite tournaments.  相似文献   
86.
87.
A wide range of aliphatic or aromatic sulfides are selectively oxidized to the corresponding sulfoxides using ammonium cerium (IV) nitrate (CAN) and a catalytic amount of KBr or NaBr in the presence of wet SiO2 in CH2Cl2 under heterogeneous conditions in moderate to high yields.  相似文献   
88.
A wide range of aliphatic or aromatic sulfides are selectively oxidized to the corresponding sulfoxides using ammonium cerium (IV) nitrate (CAN) and a catalytic amount of KBr or NaBr in the presence of wet SiO2 in CH2Cl2 under heterogeneous conditions in moderate to high yields. Correspondence: Mohammad Ali Zolfigol, Faculty of Chemistry, Bu-Ali Sina University, P.O. Box 6517838683, Hamadan, Iran; Kamal Amani, Department of Chemistry, Faculty of Science, University of Kurdistan, P.O. Box 6617715175, Sanandaj, Iran.  相似文献   
89.
In this study, a novel flat-type synergic-supported liquid membrane was evaluated with a mixture of N-methyl-N,N,N-trioctylammonium chloride (Aliquat 336) and tributyl phosphate (TBP) as the carrier and kerosene as the diluent to remove Cr(VI) from synthetic waste water. The main parameters involved in the process were identified and optimised. The parameters were divided into two groups, those that were independent and those having an interaction. The parameters of the carrier/kerosene volumetric proportion and stirring rate were optimised individually due to their nature. The optimal values of these parameters were 0.5 and 500 min?1, respectively, for a constant carrier/kerosene ratio and stirring rate in the designed experiments using the response surface method (RSM). The four parameters of TBP/Aliquat 336, chromium concentration in the feed phase, feed and product pH were optimised using RSM; it was observed that the TBP/Aliquat 336 ratio, feed pH, pH of the stripping phase and interaction of this parameter with feed concentration have the most important effects on the removal of Cr(VI). The optimal levels of these parameters were 0.61, 71.75 mg L?1, 3.5 and 12.66 for the ratio of TBP/Aliquat 336, feed chromium concentration, pH of the feed and pH of the product, respectively. An experimental removal rate of 94.63 % at the optimized levels was obtained.  相似文献   
90.
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