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51.
Apostolos Hadjidimos 《Journal of Mathematical Analysis and Applications》1977,59(3):573-586
The purpose of this paper is to show the equivalence of Alternating Direction Preconditioning and Extrapolated Alternating Direction Implicit methods in the case of two-level one-parameter optimized schemes as far as convergence rates are concerned, and also to give optimum parameters for the numerical solution of the self-adjoint second-order elliptic partial differential equation and the biharmonic equation. 相似文献
52.
Iordanis Tzanidis Feidias Bairamis Dr. Lamprini Sygellou Dr. Konstantinos S. Andrikopoulos Prof. Apostolos Avgeropoulos Prof. Ioannis Konstantinou Prof. Dimitrios Tasis 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(29):6643-6651
Nanoscale two-dimensional nanostructures have shown great potential as functional components in photocatalysis. Here, investigations on the synthesis of heterostructured hybrids, comprised of 0D CdS nanoparticles as semiconductor and 2D/2D graphene/MoSx as co-catalyst, are reported. The approach involves a rapid microwave-assisted reaction in autoclave conditions, by adopting either a one-step or a two-step protocol. The chemical speciation of the nanocomposites was found to depend strongly on the compounding conditions of the precursor substances. The photocatalytic activity was assessed by monitoring the photodegradation rate of 4-nitrophenol in solution using simulated solar light irradiation. The photocatalytic activity of the hybrids may be attributed to a combination of beneficial characteristics, strongly related to the chemical speciation of the composite components. Moreover, intimate contacts of the latter result in efficient heterojunctions. Overall, the present study provides valuable insight into the development of functional heterostructured photocatalysts comprised of two-dimensional nanomaterials. 相似文献
53.
Synthesis,characterization and self‐assembly of well‐defined linear heptablock quaterpolymers
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Christos Ntaras George Polymeropoulos George Zapsas Konstantinos Ntetsikas George Liontos Apostolos Karanastasis Dimitrios Moschovas Sofia Rangou Charlotte Stewart‐Sloan Nikos Hadjichristidis Edwin L. Thomas Apostolos Avgeropoulos 《Journal of Polymer Science.Polymer Physics》2016,54(15):1443-1449
Two well‐defined heptablock quaterpolymers of the ABCDCBA type [Α: polystyrene (PS), B: poly(butadiene) with ~90% 1,4‐microstructure (PB1,4), C: poly(isoprene) with ~55% 3,4‐microstructure (PI3,4) and D: poly(dimethylsiloxane) (PDMS)] were synthesized by combining anionic polymerization high vacuum techniques and hydrosilylation/chlorosilane chemistry. All intermediates and final products were characterized by size exclusion chromatography, membrane osmometry, and proton nuclear magnetic resonance spectroscopy. Fourier transform infrared spectroscopy was used to further verify the chemical modification reaction of the difunctional PDMS. The self‐assembly in bulk of these novel heptablock quarterpolymers, studied by transmission electron microscopy and small angle X‐ray scattering, revealed 3‐phase 4‐layer alternating lamellae morphology of PS, PB1,4, and mixed PI3,4/PDMS domains. Differential scanning calorimetry was used to further confirm the miscibility of PI3,4 and PDMS blocks. It is the first time that PDMS is the central segment in such multiblock polymers (≥3 chemically different blocks). © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1443–1449 相似文献
54.
55.
Polymer hydrogels have attracted much interest in recent years based on numerous applications mainly in biotechnology and medicine. For the knowledge‐based design and development of new materials for these and similar applications, it is essential to understand better the hydration properties of hydrogels and of polymers in general. With this term, we mean the particular organization of water in the hydrogel, which determines the properties of the water component, typically different than those of bulk water, and the impact of water on the properties of the polymer matrix itself. In this review, we focus on recent work with hydrogels based on poly(hydroxyethyl acrylate), mostly copolymers with a second hydrophobic polymer and silica nanocomposites. The combination of water sorption/diffusion, thermal and dielectric studies, by fully exploiting the capabilities of each individual technique, proves essential in providing significant information on particular aspects of hydration, such as water uptake, water organization, and diffusion coefficients; glass transition and plasticization; water and polymer dynamics; protonic conductivity, and in revealing interesting correlations between these particular aspects. In the outlook similarities and differences to other related systems, such as protein‐water and polymer solutions in non‐polar solvents, are stressed in the perspective of a broader study. © 2012 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2013 相似文献
56.
Dionysios Soulis Marianna Trigazi George Tsekenis Chrysoula Chandrinou Apostolos Klinakis Ioanna Zergioti 《Molecules (Basel, Switzerland)》2020,25(21)
Despite the fact that a considerable amount of effort has been invested in the development of biosensors for the detection of pesticides, there is still a lack of a simple and low-cost platform that can reliably and sensitively detect their presence in real samples. Herein, an enzyme-based biosensor for the determination of both carbamate and organophosphorus pesticides is presented that is based on acetylcholinesterase (AChE) immobilized on commercially available screen-printed carbon electrodes (SPEs) modified with carbon black (CB), as a means to enhance their conductivity. Most interestingly, two different methodologies to deposit the enzyme onto the sensor surfaces were followed; strikingly different results were obtained depending on the family of pesticides under investigation. Furthermore, and towards the uniform application of the functionalization layer onto the SPEs’ surfaces, the laser induced forward transfer (LIFT) technique was employed in conjunction with CB functionalization, which allowed a considerable improvement of the sensor’s performance. Under the optimized conditions, the fabricated sensors can effectively detect carbofuran in a linear range from 1.1 × 10?9 to 2.3 × 10?8 mol/L, with a limit of detection equal to 0.6 × 10?9 mol/L and chlorpyrifos in a linear range from 0.7 × 10?9 up to 1.4 × 10?8 mol/L and a limit of detection 0.4 × 10?9 mol/L in buffer. The developed biosensor was also interrogated with olive oil samples, and was able to detect both pesticides at concentrations below 10 ppb, which is the maximum residue limit permitted by the European Food Safety Authority. 相似文献
57.
D. Georgopoulos S. Kripotou E. Argyraki A. Kyritsis P. Pissis 《Molecular Crystals and Liquid Crystals》2015,611(1):197-207
The isothermal crystallization kinetics of 4-n-pentyl-4–cyanobiphenyl (5CB) has been studied with Differential Scanning Calorimetry (DSC) and Dielectric Relaxation Spectroscopy (DRS). 5CB is a well characterized material which makes it ideal for a dielectric and thermal comparative study. The effect that isothermal crystallization exerts on the behavior of relaxation processes α and δ by cooling the isotropic liquid below the nematic phase or through the process of cold crystallization by heating it from the supercooled state is explored by comparing the DRS and DSC. Furthermore, by employing the Avrami equation, we compare the ability to probe the crystallization with each technique. 相似文献
58.
Apostolos Thoma 《manuscripta mathematica》1991,70(1):261-266
We prove that smooth monomial curves of degree greater than three are not set theoretic complete intersections on a wide class
of surfaces, called bihonogeneous surfaces. 相似文献
59.
The Linear Complementarity Problem (LCP), with an H+?matrix coefficient, is solved by using the new “(Projected) Matrix Analogue of the AOR (MAAOR)” iterative method; this new method constitutes an extension of the “Generalized AOR (GAOR)” iterative method. In this work two sets of convergence intervals of the parameters involved are determined by the theories of “Perron-Frobenius” and of “Regular Splittings”. It is shown that the intervals in question are better than any similar convergence intervals found so far by similar iterative methods. A deeper analysis reveals that the “best” values of the parameters involved are those of the (projected) scalar Gauss-Seidel iterative method. A theoretical comparison of the “best” (projected) Gauss-Seidel and the “best” modulus-based splitting Gauss-Seidel method is in favor of the former method. A number of numerical examples support most of our theoretical findings. 相似文献
60.
For the diatomic aluminum nitride (AlN), we have constructed potential energy curves for 45 states employing multi-reference variational methods and quantitative basis sets. Thirty-six states are relatively strongly bound, five present local minima, and four are of repulsive nature. Almost all states are of intense multi-reference character rendering their calculation and interpretation quite problematic. Our tentative assignment of the ground state is 3Pi, while a 3Sigma- state is above by less than 1 kcal/mol. Our best estimate for the binding energy of the X3Pi state is D0 = 56.0 +/- 0.5 kcal/mol at re = 1.783 A, in good agreement with the experimental values of D = 66 +/- 9 kcal/mol and re = 1.7864 A. The binding energy of the A3Sigma- state is very similar to the X state because they both correlate to the ground-state atoms, but the bond distance of the former is 0.13 A longer. The first seven states can be tagged as follows: X3Pi, A3Sigma-, a1Sigma+, b1Pi, c1Delta, B3Sigma+, and d1Sigma+, a rather definitive order with the exception of X and A states. 相似文献