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81.
Consider a finite state irreducible Markov reward chain. It is shown that there exist simulation estimates and confidence intervals for the expected first passage times and rewards as well as the expected average reward, with 100% coverage probability. The length of the confidence intervals converges to zero with probability one as the sample size increases; it also satisfies a large deviations property.  相似文献   
82.
This paper describes a new multilevel procedure that can solve the discrete Navier–Stokes system arising from finite volume discretizations on composite grids, which may consist of more than one level. SIMPLE is used and tested as the smoother, but the multilevel procedure is such that it does not exclude the use of other smoothers. Local refinement is guided by a criterion based on an estimate of the truncation error. The numerical experiments presented test not only the behaviour of the multilevel algebraic solver, but also the efficiency of local refinement based on this particular criterion. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
83.
Our aim in this paper is to develop a theory of purity and to prove in a unified conceptual way the existence of almost split morphisms, almost split sequences and almost split triangles in abstract homotopy categories, a rather omnipresent class of categories of interest in representation theory. Our main tool for doing this is the classical Brown representability theorem.  相似文献   
84.
Segmented thermoplastic copolyether esters (TPEE's) with a partially renewable hard block containing isosorbide (ISB) and poly(ethylene glycol) (PEG) soft blocks were prepared by melt polycondensation. A range of compositions was accessible despite the relatively low reactivity of the sterically and electronically hindered ISB monomer. The small-scale reactions performed in the melt were limited in terms of achievable molar mass. This is attributed to the challenge of attaining stoichiometric balance in the feed and maintaining this balance throughout the high temperature (>200°C) reactions. Nevertheless, products were isolated that could be manipulated and melt-pressed into specimen for tensile testing. Varying the feed compositions gave rise to copolymers exhibiting a broad range of mechanical properties (elastic modulus from 1–66 MPa). These characteristics are consistent with a segmented polymer architecture with morphological features similar to commercially available TPEE counterparts. These results pave the way for more responsibly sourced building blocks being incorporated into materials with high market value potential.  相似文献   
85.
This review is a brief account on the application of a novel methodology to the quality control and authentication of extra-virgin olive oil. This methodology is based on the derivatization of the labile hydrogens of functional groups, such as hydroxyl and carboxyl groups, of olive oil constituents with the phosphorus reagent 2-chloro-4,4,5,5-tetramethyldioxaphospholane, and the use of the (31)P chemical shifts to identify the phosphitylated compounds. Various experimental aspects such as pertinent instrumentation, sample preparation, acquisition parameters and properties of the phosphorus reagent are reviewed. The strategy to assign the (31)P signals of the phosphitylated model compounds and olive oil constituents by employing 1D and 2D NMR experiments is presented. Finally, the capability of this technique to assess the quality and the genuineness of extra-virgin olive oil and to detect fraud is discussed.  相似文献   
86.
In this paper, we continue the research by Serletis [Random walks, breaking trend functions, and the chaotic structure of the velocity of money, J. Bus. Econ. Stat. 13 (1995) 453-458] and Serletis and Shintani [Chaotic monetary dynamics with confidence, J. Macroeconomics 28 (2006) 228-252] by applying the method of detrended fluctuation analysis (DFA)—introduced by Peng et al. [Mosaic organization of DNA nucleotides, Phys. Rev. E 49 (1994) 1685-1689] and adapted to the analysis of long-range correlations in economic data by Uritskaya [Forecasting of magnitude and duration of currency crises based on analysis of distortions of fractal scaling in exchange rate fluctuations, Noise and fluctuations in econophysics and finance, Proc. SPIE 5848 (2005) 17-26; Fractal methods for modeling and forecasting of currency crises, in: Proceedings of the fourth International Conference on Modeling and Analysis of Safety and Risk in Complex Systems, SPbSU Press, St.Petersburg, 2005, pp. 210-215]—to investigate the dynamical structure of United States money and velocity measures. We use monthly data over the time period from 1959:1 to 2006:2, at each of the four levels of monetary aggregation, M1, M2, M3, and MZM, making comparisons among simple-sum, Divisia, and currency equivalent (CE) methods of aggregation. The results suggest that the sum and Divisia monetary aggregates are more appropriate for measuring long-term tendencies in money supply dynamics while the CE aggregates are more sensitive measures of short-term processes in the economy.  相似文献   
87.
Sharpening work of the first two authors, for every proportion λ∈(0,1) we provide exact quantitative relations between global parameters of n-dimensional symmetric convex bodies and the diameter of their random ⌊λn⌋-dimensional sections. Using recent results of Gromov and Vershynin, we obtain an “asymptotic formula” for the diameter of random proportional sections.  相似文献   
88.
Auslander-Reiten Triangles, Ziegler Spectra and Gorenstein Rings   总被引:1,自引:0,他引:1  
We investigate (existence of) Auslander—Reiten triangles in a triangulated category in connection with torsion pairs, existence of Serre functors, representability of homological functors and realizability of injective modules. We also develop an Auslander—Reiten theory in a compactly generated triangulated category and we study the connections with the naturally associated Ziegler spectrum. Our analysis is based on the relative homological theory of purity and Brown's Representability Theorem. Our main interest lies in the structure of Auslander—Reiten triangles in the full subcategory of compact objects. We also study the connections and the interplay between Auslander—Reiten theory, pure-semisimplicity and the finite type property, Grothendieck groups, and we give applications to derived categories of Gorenstein rings.  相似文献   
89.
The enzyme catalysed esterification of starch and fatty acids with terminal triple bonds is described. This material can be used as an acceptor for azide containing molecules, through azide/alkyne cycloaddition. The potential is illustrated by the production of fluorescently-labelled starch, and a biotinylated derivative which can bind streptavidin.  相似文献   
90.
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