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361.
Anupam Saha Somdeb Jana Tarun K. Mandal 《Journal of polymer science. Part A, Polymer chemistry》2016,54(18):3019-3031
Peptide–polymer conjugates are versatile class of biomaterials composed of a peptide block covalently linked with a synthetic polymer block. This report demonstrates the synthesis of peptide‐poly(tert‐butyl methacrylate) (Peptide‐PtBMA) conjugates of varying molecular weights via a “grafting from” atom transfer radical polymerization (ATRP) technique using as‐synthesized peptide‐based initiator in toluene. Peptide‐PtBMA conjugate is soluble in many organic solvents and undergoes self‐assembly into micro/nanospheres in DMF/THF as observed from both FESEM and DLS results. The conjugate micro/nanospheres are nothing but the composite micelles formed by the secondary aggregation of primary micelles generated initially in these organic solvents. The hydrolysis of tert‐butyl groups of Peptide‐PtBMA conjugate leads to the formation of peptide‐poly(methacrylic acid) (Peptide‐PMA) conjugate. The circular dichroism (CD) analysis exhibits the presence of β‐sheet conformation of peptide moiety in synthesized conjugates. The formed Peptide‐PMA conjugate is soluble in water and owing to its amphiphilic character, the conjugate molecules self‐assemble into spherical micelles as well as worm‐like micelles upon increasing the concentration of conjugate in water. However, the sodium salt of Peptide‐PMA conjugates (Peptide‐PMAS) self‐assembles into only spherical swollen micelles in water at higher (pH ~10). The critical aggregation concentrations (CACs) of both Peptide‐PMA and Peptide‐PMAS micelles are measured by fluorescence spectroscopy. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 3019–3031 相似文献
362.
Jonathan D. Yuen Mingfeng Wang Jian Fan Dennis Sheberla Moureen Kemei Natalie Banerji Mariateresa Scarongella Sebastian Valouch Toan Pho Rajeev Kumar Eneida C. Chesnut Michael Bendikov Fred Wudl 《Journal of polymer science. Part A, Polymer chemistry》2015,53(2):287-293
The first observation that PBBTPD, a low bandgap, ambipolar conjugated donor-acceptor (DA) polymer based on benzobisthiadiazole (BBT), possesses an open-shell singlet ground state as well as a thermally accessible triplet state is described. Similarly, interesting electronic behavior in semiconducting organic DA oligomers based on BBT is also observed. Theoretical predictions have suggested that such behavior is due to the biradicaloid character of BBT and we provide experimental evidence indicating that these predictions are correct. Furthermore, the open shell character strengthens as the conjugation length increases, as observed in the BBT-based polymer, PBBTPD. We show that this biradicaloid structure is observed in each BBT moiety along the chain and that therefore PBBTPD is in fact a polyradicaloid. This observation will most likely aid in the development of better n-type polymeric acceptors for organic semiconductor applications. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 287–293 相似文献
363.
Titanium ferricyanide gel is found to possess good ion-exchange capacity, mechanical and chemical stability, and selectivity. An Araldite-based membrane of this compound can be used to estimate K+ ions in the concentration range 10–1–10–4
M. The sensor has a very short response time and remains stable for 2 to 3 months. There is no serious interference by bivalent and multivalent ions. Among the monovalent cations only Na+ and NH
4
+
may cause significant interference. 相似文献
364.
Wang J. Wang J. -M. Banerji S. K. Bajpai R. K. 《Applied biochemistry and biotechnology》1995,51(1):693-703
Applied Biochemistry and Biotechnology - Pentachlorophenol (PCP) is a widely used wood-treating chemical that is applied to wood under pressure in the form of concentrated solution in solvents that... 相似文献
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László?KótaiEmail author István?Sajó Judit?Fodor Piroska?Szabó Emma?Jakab Gyula?Argay Sándor?Holly István?Gács Kalyan?K.?Banerji 《Transition Metal Chemistry》2005,30(8):939-943
Compositions and chemical identities of compounds formed in silver–permanganate–pyridine–water systems, as well as of their
recrystallization products obtained from benzene–acetone solutions, have been elucidated. Three compounds: Agpy2MnO4 (1), 7Agpy2MnO4*Agpy4MnO4 (Agpy2.25MnO4) (2) and Agpy2MnO4 * 0.5py (Agpy2.5MnO4) (3) were isolated. The compositions of the products obtained by a method described previously [1] for the preparation of ‘Agpy2MnO4’ (1*) and ‘Agpy2.5MnO4’ (2*) were determined and the constituent compounds identified. It has been established that the instability of compound (3) is due to the presence of the benzene, substituting for pyridine at the solvate sites. The benzene, however, is released
at room temperature, disrupting the crystal lattice of (3), and the whole process leads to the loss of the solvate pyridine and to the formation of (1). 相似文献
369.
Methylthymol blue reacts very sensitively with palladium(II) to form two complexes. The 1:1 complex has λmax at 530 nm in acidity range 0.02 to 0.05 M with respect to perchloric acid and 1:2 (metal reagent ratio) complex at 500 nm in pH range 6.8 to 7.5. Optimum conditions including the range for adherence to Beer's law, effect of pH, effect of excess reagent and sensitivity are reported for the photometric determination of palladium using methylthymol blue. 相似文献
370.
Avijit Banerji Debasish Bandyopadhyay Bidyut Basak Alain Neuman 《Tetrahedron letters》2006,47(23):3827-3830
A series of cycloadducts possessing unusual flipping modes have been isolated from the 1,3-dipolar cycloaddition of 3,4,5,6-tetrahydropyridine N-oxide to piperidides of cinnamic acid and para-substituted cinnamic acids and these were analyzed by X-ray crystallography to reveal novel solid-state structures. The presence of two different flippomers arising due to flipping of the six/five bicyclic ring was confirmed both in solid state and in solution. This is the first observation of 1,3-dipolar cycloadducts having two different flippomers arising due to flipping of the isoxazolidine ring. 相似文献