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111.
Tests are described for differentiation between neutral, basic, and acidic amino acids based on the formation of nickel dimethylglyoxime precipitate from an equilibrium mixture containing Ni2+, dimethylglyoxime and Ni2+, dimethylglyoxime-glycine. A highly sensitive and specific test for lysine is described, based on the formation of nickel dimethylglyoxime precipitate in a drop of the equilibrium mixture, by the reaction of the volatile amino aldehyde, produced by the oxidative deamination-decarboxylation of lysine. Other basic amino acids, i.e., arginine and histidine do not interfere, and the test can be applied for lysine in a mixture with other amino acids. 相似文献
112.
The Nd3+ complexes of β-diketonates have been studied earlier, 1–3 but those of aromatic acids have not been studied in detail. The present communication reports the study of two of such complexes. 相似文献
113.
This report presents details of the development of a new crossed molecular beams apparatus designed and fabricated to carry
out high sensitivity ion translational energy spectrometric investigations of the potential energy surfaces of small molecular
species. The translational energy spectrometer is used to carry out experimental studies of ion-neutral reactions resulting
in charge stripping of CS+ radicals and dissociation of metastable CO2+ dications. These results are interpreted in the light of high-levelab initia molecular orbital calculations of the pertinent molecular potential energy functions. New results for the double ionisation
energy of CS and the kinetic energy released upon dissociation of specific electronic states of CO2+ are presented. 相似文献
114.
Lu Q Keskar G Ciocan R Rao R Mathur RB Rao AM Larcom LL 《The journal of physical chemistry. B》2006,110(48):24371-24376
Density gradient centrifugation is a high-resolution technique for the separation and characterization of large molecules and stable complexes. We have analyzed various nanotube structures by preparative centrifugation in sodium metatungstate-water solutions. Bundled, isolated and acid-treated single-walled nanotubes (SWNTs) and multiwall nanotubes (MWNTs) formed sharp bands at well-defined densities. The structure of the material in each band was confirmed by transmission electron microscopy and Raman spectroscopy. Our data suggest respective densities of 1.87, 2.13, 1.74, and 2.1 g/cm(3) for bundled, isolated, and acid-treated SWNTs and MWNTs. These measured results compare well with their calculated densities. 相似文献
115.
Let be a finite simple graph. For , the difference of , where is the neighborhood of and is called the critical difference of . is called a critical set if equals the critical difference and is the intersection of all critical sets. is the union of all critical independent sets. An independent set is an inclusion minimal set with if no proper subset of has positive difference.A graph is called a König–Egerváry graph if the sum of its independence number and matching number equals .In this paper, we prove a conjecture which states that for any graph the number of inclusion minimal independent set with is at least the critical difference of the graph.We also give a new short proof of the inequality .A characterization of unicyclic non-König–Egerváry graphs is also presented and a conjecture which states that for such a graph , the critical difference equals , is proved.We also make an observation about using Edmonds–Gallai Structure Theorem as a concluding remark. 相似文献
116.
117.
This note presents improved approximation guarantees for the requirement cut problem: given an n-vertex edge-weighted graph G=(V,E), and g groups of vertices X1,…,Xg⊆V with each group Xi having a requirement ri between 0 and |Xi|, the goal is to find a minimum cost set of edges whose removal separates each group Xi into at least ri disconnected components. We give a tight Θ(logg) approximation ratio for this problem when the underlying graph is a tree, and show how this implies an O(logk⋅logg) approximation ratio for general graphs, where . 相似文献
118.
119.
Hanle technique is used for the lifetime measurement of the atomic excited states. Field dependent Hanle signal is Lorentzian under ideal conditions. Any departure from ideal situation is reflected in the shape of the Hanle signal resulting in erroreous measurements. The effect of one such factor, a finite interaction cross section, is discussed here. 相似文献
120.
Abstract The Raman spectra of a crystalline powder of InCl3 and of a de-ionized water solution show the presence of four bands at 300.0, 289.2, 115.6 and 87.1 cm?1, thus suggesting that InCl3 is not a perfectly planar molecule. 相似文献