Selection of Polymorphic Structure in Dihydroxystearic Acid/Octyl dihydroxystearate/RBD Palm Kernel Olein & Medium Chain Triglycerides in Cosmetic and Personal Care Formulation

Dihydroxystearic acid (DHSA) and octyl dihydroxystearate (DHSA‐octyl ester) have been successfully prepared from palm oleic acid. Preliminary results showed that these compounds are suitable in personal care and cosmetics products. The objective is to study the phase behaviors in ternary system of DHSA/DHSA‐octyl ester/RBD palm kernel olein (RBDPKOo) and medium chain triglycerides (MCT) at 85°C. The phase changes were observed through polarizing light while the formation of texture was confirmed using polarizing microscope combination with heating. From the ternary phase diagram, results showed that all ratios of DHSA/DHSA‐octyl ester were completely in two‐phase region with various concentrations of RBDPKOo/MCT. Needles and spherulite textures were found in this system. The viscosity and thixotropy of these mixtures were also determined using rheometer. DHSA and DHSA‐octyl ester has a melting point of 84.4°C and 64.3°C, respectively.     

Falkner-Skan equation for flow past a moving wedge with suction or injection

The characteristics of steady two-dimensional laminar boundary layer flow of a viscous and incompressible fluid past a moving wedge with suction or injection are theoretically investigated. The transformed boundary layer equations are solved numerically using an implicit finite-difference scheme known as the Keller-box method. The effects of Falkner-Skan power-law parameter (m), suction/injection parameter (f0) and the ratio of free stream velocity to boundary velocity parameter (λ) are discussed in detail. The numerical results for velocity distribution and skin friction coefficient are given for several values of these parameters. Comparisons with the existing results obtained by other researchers under certain conditions are made. The critical values off ₀,m and λ are obtained numerically and their significance on the skin friction and velocity profiles is discussed. The numerical evidence would seem to indicate the onset of reverse flow as it has been found by Riley and Weidman in 1989 for the Falkner-Skan equation for flow past an impermeable stretching boundary.     

Cardinality enhancement of spectral/spatial modified double weight code optical code division multi-access system by PIIN suppression

A new two-dimensional (2-D) optical code division multiple access (OCDMA) scheme to increase the achievable system capacity is proposed. The code exhibits good cross-correlation property time and wavelength shift. Performances are analyzed on code size and correlation properties affecting two important system parameters, bit error rate (BER) as a function of cardinality generated and optical power transmission requirement. The proposed system can effectively suppress phase-induced intensity noise (PIIN) and has multi-access interference (MAI) cancellation property. Results in a good agreement indicate that 2-D modified double weight (MDW) offers 163.7% and 336.2% larger cardinality compare to 2-D perfect difference code (PDC) and 2-D modified quadratic congruence (MQC) code. By increasing spatial code (N) and keeps similar code length system performance can be further optimized. 2-D MDW (M = 45, N = 18) accommodates 252.2% and 18.3% cardinality increment and low effective transmitted power (P_sr) at −17.9 dBm, compare to 2-D MDW (M = 247, N = 3) and (M = 84, N = 9) at 10⁻⁹ BER error floor. The architecture of the spectral/spatial MDW OCDMA system with property of MAI cancellation is presented.     

MHD flow and heat transfer over a radially stretching/shrinking disk

A steady magnetohydrodynamic (MHD) flow past a radially stretching or shrinking disk is investigated. The governing partial differential equations are transformed into a set of ordinary (similarity) differential equations by a similarity transformation. These equations along with the corresponding boundary conditions are solved numerically using the boundary value problem solver (bvp4c) in Matlab. The effects of magnetic field and suction on the shear stress and the heat transfer are analyzed and discussed. It is found that both parameters affect more in the shrinking region. The increase in the magnetic parameter results in the increase of the skin friction coefficient but decrease in the local Nusselt number.The skin friction coefficient and the local Nusselt number increase as suction increases.     

Thermal boundary layer flow over a stretching sheet in a micropolar fluid with radiation effect

In the present paper, we study the effects of radiation on the thermal boundary layer flow induced by a linearly stretching sheet immersed in an incompressible micropolar fluid with constant surface temperature. Similarity transformation is employed to transform the governing partial differential equations into ordinary ones, which are then solved numerically using the Runge-Kutta-Fehlberg method. Results for the local Nusselt number as well as the temperature profiles are presented for different values of the governing parameters. It is found that the heat transfer rate at the surface decreases in the presence of radiation. Comparison with known results for certain particular cases is excellent.     

Mixed convection boundary layer flow past a wedge with permeable walls

The effects of suction/injection on steady laminar mixed convection boundary layer flow over a permeable horizontal surface of a wedge in a viscous and incompressible fluid is considered in this paper. The similarity solutions of the governing boundary layer equations are obtained for some values of the suction/injection parameter f ₀, the constant exponent m of the wall temperature as well as the mixed convection parameter λ. The resulting system of nonlinear ordinary differential equations is solved numerically for both assisting and opposing flow regimes using an implicit finite-difference scheme known as the Keller-box method. Numerical results for the reduced skin friction coefficient, the local Nusselt number, and the velocity and temperature profiles are obtained for various values of parameters considered. Dual solutions are found to exist for the case of opposing flow.     

Analysis on International Competitiveness of Service Trade in the Guangdong–Hong Kong–Macao Greater Bay Area Based on Using the Entropy and Gray Correlation Methods

Based on the analysis and measurement of the overall situation, import and export structure and international competitiveness of the various sectors of service trade in the Guangdong–Hong Kong–Macao Greater Bay Area, with the help of MATLAB and Gray System Modeling software, the synergy degree model was established to quantitatively analyze the synergy level of service trade in the Greater Bay Area with the help of grey correlation analysis method and entropy weight method. The results show that the overall development trend of service trade in the Guangdong–Hong Kong–Macao Greater Bay Area is good. The service trade industries in different regions are highly complementary and have a high degree of correlation. The potential for the coordinated development of internal service trade is excellent, and the overall situation of service trade in the Greater Bay Area is in a stage of transition from a moderate level of synergy to a high level of synergy. The Greater Bay Area can achieve industrial synergy by accelerating industrial integration and green transformation, establishing a coordinated development mechanism, sharing market platform, strengthening personnel security, and further enhancing the international competitiveness of service trade. The established model better reflects the current coordination of service trade in the Guangdong–Hong Kong–Macao Greater Bay Area and has good applicability. In the future, more economic, technological, geographic, and policy data and information can be comprehensively used to study the spatial pattern, evolution rules, and mechanisms of coordinated development in the broader area.     

Mössbauer studies of heterobimetallic and heterotrimetallic compounds containing iron and tin

A series of ferrocene derivatives was prepared and studied by⁵⁷Fe and¹¹⁹Sn Mössbauer spectroscopy, as well as by other techniques such as NMR and IR spectroscopies. These complexes can be divided into three types: mercurated, organotin derivatives of ferrocene, and bi- and trimetallic derivatives of 1,1-bis(diphenylphosphino)ferrocene. Iron did not show great variation in its Mössbauer parameters in the compounds, in spite of their diversity; tin, however, gave important Mössbauer data for the elucidation of bonding and structural features of the complexes.     

Uniform suction/blowing effect on flow and heat transfer due to a stretching cylinder

The present paper presents a numerical solution of flow and heat transfer outside a stretching permeable cylinder. The governing system of partial differential equations is converted to ordinary differential equations by using similarity transformations, which are then solved numerically using the Keller-box method. The main purpose of the present study is to investigate the effects of the governing parameters, namely the suction/injection parameter, Prandtl number, and Reynolds number on the velocity and temperature profiles as well as the skin friction coefficient and the Nusselt number. The results are shown graphically. The values of the skin friction coefficient and the Nusselt number are presented in tables.     

Physicochemical characterization of natural-like branched-chain glycosides toward formation of hexosomes and vesicles

Synthetic branched-chain glycolipids have become of great interest in biomimicking research, since they provide a suitable alternative for natural glycolipids, which are difficult to extract from natural resources. Therefore, branched-chain glycolipids obtained by direct syntheses are of utmost interest. In this work, two new branched-chain glycolipids are presented, namely, 2-hexyldecyl β(α)-D-glucoside (2-HDG) and 2-hexyldecyl β(α)-D-maltoside (2-HDM) based on glucose and maltose, respectively. The self-assembly properties of these glycolipids have been studied, observing the phase behavior under thermotropic and lyotropic conditions. Due to their amphiphilic characteristics, 2-HDG and 2-HDM possess rich phase behavior in dry form and in aqueous dispersions. In the thermotropic study, 2-HDG formed a columnar hexagonal liquid crystalline phase, whereas in a binary aqueous system, 2-HDG formed an inverted hexagonal liquid crystalline phase in equilibrium with excess aqueous solution. Furthermore, aqueous dispersions of the hexagonal liquid crystal could be obtained, dispersions known as hexosomes. On the other hand, 2-HDM formed a lamellar liquid crystalline phase (smectic A) in thermotropic conditions, whereas multilamellar vesicles have been observed in equilibrium with aqueous media. Surprisingly, 2-HDM mixed with sodium dodecyl sulfate or aerosol OT induced the formation of more stable unilamellar vesicles. Thus, the branched-chain glycolipids 2-HDG and 2-HDM not only provided alternative nonionic surfactants with rich phase behavior and versatile nanostructures, but also could be used as new drug carrier systems in the future.