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121.
122.
Demonstration of the Bessel-X pulse propagating with strong lateral and longitudinal localization in a dispersive medium 总被引:1,自引:0,他引:1
We report experiments on ultrashort pulses that maintain their strong lateral and longitudinal localization in a bulk linear highly dispersive medium. The diameter of the central peak and the temporal width of the field autocorrelation function of the pulses were 20mum and 210 fs, respectively, and the spatiotemporal structure was preserved in the course of 7-cm propagation in the sample. The pulses were obtained with a computer hologram designed for generating the Bessel beam and can be applied in femtosecond laser optics. 相似文献
123.
T. Dergez F. Könczöl N. Farkas J. Belőgyi D. Lõrinczy 《Journal of Thermal Analysis and Calorimetry》2005,80(2):445-449
Summary The heat capacity of contractile proteins actin and myosin was studied in psoas muscle of rabbit in strongly and weakly binding state of myosin to actin as a function of temperature by DSC. Deconvolution of the unfolding scans makes possible to characterize the structural domains of the macromolecules. We tried to approach the unfolding process in different intermediate state of ATP hydrolysis. The thermal transitions were calorimetrically irreversible, therefore the two-state irreversible model that describes fairly well the denaturation of different proteins was used for evaluation of the denaturation processes in muscle fibers in strongly (rigor, ADP) and weakly binding states (ATP·Vi, ADP·AlF4) of myosin to actin. Deconvolution resulted in four transitions, the first three transition temperatures were almost independent of the intermediate states of muscle, the last transition temperature was shifted to higher temperature, when the buffer solution was manipulated. The mean values in strongly binding states were Tm1=52.9±0.7°C, Tm2=57.9±0.7°C, Tm3=63.7±1.0°C and Tm4=67.8±0.7°C, but the last transition increased to higher temperature depending on the Pi analogue. 相似文献
124.
125.
G. Nenartaviciene K. Tõnsuaadu D. Jasaitis A. Beganskiene A. Kareiva 《Journal of Thermal Analysis and Calorimetry》2007,90(1):173-178
In this study the formation of chromium substituted YBa2Cu4O8 (Y-124) superconductors has been investigated by TG/DTA measurements. The YBa2(Cu1−xCrx)4O8 ceramics with nominal compositions of x=0.01, 0.03, 0.05, 0.10 and 0.20 have been prepared by an aqueous sol-gel method using aqueous mixtures of the corresponding
metal acetates and nitrates. Homogeneous precursor gels were obtained by complexing metal ions with tartaric acid. To assist
the interpretation of the results obtained the synthesis products were additionally characterized by X-ray powder diffraction
(XRD) and resistivity measurements. It was determined that doping the YBa2Cu4O8 phase with chromium has a strong effect on the phase purity and superconducting properties of the synthesis products. 相似文献
126.
A methodology for the worst case measurement uncertainty estimation for analytical methods which include an instrumental quantification step, adequate for routine determinations, is presented. Although the methodology presented should be based on a careful evaluation of the analytical method, the resulting daily calculations are very simple. The methodology is based on the estimation of the maximum value for the different sources of uncertainty and requires the definition of limiting values for certain analytical parameters. The simplification of the instrumental quantification uncertainty estimation involves the use of the standard deviation obtained from control charts relating to the concentrations estimated from the calibration curves for control standards at the highest calibration level. Three levels of simplification are suggested, as alternatives to the detailed approach, which can be selected according to the proximity of the sample results to decision limits. These approaches were applied to the determination of pesticide residues in apples (CEN, EN 12393), for which the most simplified approach showed a relative expanded uncertainty of 37.2% for a confidence level of approximately 95%. 相似文献
127.
128.
The conventional assignment of pH reference buffer standards, pH(S), is achieved by means of a series of procedures that follow from measurement of Harned cell potentials for an electrolyte solution which is the buffer solution of interest. An intermediate step is assessment of the acidity function p( a(H) gamma(Cl))(0), the extrapolated value of a linear representation of the dependence of p( a(H) gamma(Cl)) on m(Cl) for at least three different molalities, m(Cl), of added alkali chloride (0.005; 0.010; 0.015 mol kg(-1) KCl). This experimental value can be compared with a theoretically expected value calculated from the dissociation constants of the buffer species. Whereas these calculations always give negative slopes for diprotic and triprotic acids and zero slope for monoprotic acids, experimental values with negative or positive slopes can be obtained for well fitting straight lines obtained for buffer solutions with ionic strengths from 0.0025 to 0.144 mol kg(-1). Such disagreement between theoretically and experimentally obtained values introduce an extra source of uncertainty in the establishment of pH(S) and on its traceability chain. In this work examples are presented and discussed for which the discrepancy between expected and experimental values leads to different intercept p( a(H) gamma(Cl))(0). 相似文献
129.
Vinay Deepak HS Joy A Suryaprakash N Ramanathan KV 《Magnetic resonance in chemistry : MRC》2004,42(4):409-413
A novel method for assigning the resonances in the 13C NMR spectrum of a static liquid crystalline sample in its nematic phase is proposed. The method is based on the fact that the carbon chemical shifts in the isotropic phase and in the oriented phase under static and off-magic angle spinning (OMAS) conditions are uniquely related by the tensorial property of the CSA tensor, requiring just one OMAS spectrum and the assignment in the isotropic phase. A computational procedure is proposed to take into account deviations arising out of non-ideal experimental conditions and the assignments are made by identifying the minimum in the differences in the frequencies between calculated and experimental line positions. Practical implementation of the method has also been demonstrated in the case of the liquid crystal N-(4-ethoxybenzylidene)-4-n-butylaniline. 相似文献
130.
A method for the identification and quantification of underivatised steryl sulphates in invertebrates by liquid chromatography
(LC) coupled with tandem mass spectrometry (MS) involving a single cleanup step has been developed. Negative electrospray
ionisation and positive and negative atmospheric-pressure chemical ionisation (APCI) spectra of steryl sulphate showed pseudomolecular
ions ([M+H–H2SO4]+or [M–H]−). Collision-induced dissociation (CID) was efficient only in positive APCI. LC-MS in negative APCI was least susceptible
to interference and possible differences in response factors. The detection limits (signal-to-noise ratio of 3) based on cholest-5-enyl-3-sulphate
in positive and negative APCI modes are 3.66 and 0.73 pmol μL−1, respectively. Calibration plots and response factors for cholest-5-enyl-3-sulphate relative to the internal standard, cholecalciferyl-3-sulphate,
in both positive and negative polarities, were linear in the concentration range from 1.22 to 16.4 pmol μL−1 with good coefficients of determination (R
2>0.98). It is suggested that the structure elucidation of steryl sulphates is best achieved in CID positive APCI mode, whereas
their quantification should be carried out using negative APCI. 相似文献