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921.
The reaction of [AuCl(P-N)], in which P-N represents a heterofunctional phosphine ligand, with pentafluorothiophenol, HSC(6)F(5), gives the thiolate gold derivatives [Au(SC(6)F(5))(P-N)] (P-N = PPh(2)py (1), PPh(2)CH(2)CH(2)py (2), or PPhpy(2) (3)). Complex [Au(SC(6)F(5))(PPh(2)py)] (1) reacts with [Au(OTf)(PPh(2)py)] in a 1:1 or 1:2 molar ratio to afford the di- or trinuclear species [Au(2)(μ-SC(6)F(5))(PPh(2)py)(2)]OTf (4) and [Au(3)(μ(3)-SC(6)F(5))(PPh(2)py)(3)](OTf)(2) (5), with the thiolate acting as a doubly or triply bridging ligand. The reactivity of the mononuclear compounds [Au(SC(6)F(5))(P-N)] toward silver or copper salts in different ratios has been investigated. Thus, the treatment of [Au(SC(6)F(5))(P-N)] with Ag(OTf) or [Cu(NCMe)(4)]PF(6) in a 1:1 molar ratio gives complexes of stoichiometry [AuAg(OTf)(μ-SC(6)F(5))(P-N)] (P-N = PPh(2)py (6), PPh(2)CH(2)CH(2)py (7), or PPhpy(2) (8)) or [AuCu(μ-SC(6)F(5))(P-N)(NCMe)]PF(6) (P-N = PPh(2)py (9), PPh(2)CH(2)CH(2)py (10), or PPhpy(2) (11)). These complexes crystallize as dimers and display different coordination modes of the silver or copper center, depending on the present functionalized phosphine ligand. The treatment of [Au(SC(6)F(5))(PPh(2)py)] with silver and copper compounds in other molar ratios has been carried out. In a 2:1 ratio, the complexes [Au(2)M(μ-SC(6)F(5))(2)(μ-PPh(2)py)(2)]X (M = Ag, X = OTf (12); M = Cu, X = PF(6) (13)) are obtained. The same reaction in a 4:3 molar ratio affords the species [Au(4)M(2)(μ-SC(6)F(5))(3)(μ-PPh(2)py)(4)]X(3) (M = Ag, X = OTf (14); M = Cu, X = PF(6) (15)). The crystal structures of some of these complexes reveal different interactions among the metallic d(10) centers. The complexes display dual emission. The band at higher energy has been attributed to intraligand (IL) transitions, and the one at lower energy has been assigned to a ligand to metal (LM) charge transfer process. The latter emission is modulated by the heterometal (silver or copper). 相似文献
922.
Fourmigué M Reinheimer EW Assaf A Jeannin O Saad A Auban-Senzier P Alemany P Rodríguez-Fortea A Canadell E 《Inorganic chemistry》2011,50(9):4171-4181
An efficient synthetic procedure for the preparation of unsymmetrically substituted tetrathiafulvalene (TTF) donors has been used to obtain the trimethylene-tetrathiafulvalene (tTTF) donor with high purity. Good quality crystals of the two (tTTF)(2)X (X = Br, I) salts have been obtained by electrocrystallization. The two salts are isomorphous and contain tTTF layers which are built from (tTTF)(2) dimeric units. Both systems are low-dimensional antiferromagnets with the highest Ne?el temperatures for TTF based radical cation salts: ≈ 35 K (Br salt) and ≈43 K (I salt). The resistivity is found to substantially decrease with pressure although both salts still have activated conductivity at 25 kbar. First-principles Density Functional Theory (DFT) calculations have been used to investigate the relative strength of the three different types of magnetic interactions in the tTTF layers as well as the potential magnetic ground states. These calculations successfully predict the nature of the ground state and suggest a possible correlation between structural details and Ne?el temperatures for the bromine and iodine salts. Remarkably, the calculated antiferromagnetic ground state can be predicted from the nesting properties of the Fermi surface for the hypothetical Pauli paramagnetic metallic state. 相似文献
923.
Cepeda J Balda R Beobide G Castillo O Fernández J Luque A Pérez-Yáñez S Román P Vallejo-Sánchez D 《Inorganic chemistry》2011,50(17):8437-8451
Detailed structural, magnetic, and luminescence studies of six different crystalline phases obtained in the lanthanide/pyrimidine-4,6-dicarboxylate/oxalate system have been afforded: {[Ln(μ-pmdc)(μ-ox)(0.5)(H(2)O)(2)]·3H(2)O}(n) (1-Ln), {[Ln(μ-pmdc)(μ-ox)(0.5)(H(2)O)(3)]·2H(2)O}(n) (2-Ln), {[Ln(μ(3)-pmdc)(μ-ox)(0.5)(H(2)O)(2)]·~2.33H(2)O}(n) (3-Ln), {[Ln(2)(μ(3)-pmdc)(μ(4)-pmdc)(μ-ox)(H(2)O)(3)]·5H(2)O}(n) (4-Ln), {[Ln(μ(3)-pmdc)(μ-ox)(0.5)(H(2)O)(2)]·H(2)O}(n) (5-Ln), and [Ln(pmdc)(1.5)(H(2)O)(2.5)] (6-Ln). The slow generation of the oxalate (ox) anion, obtained from the in situ partial hydrothermal decomposition of the pyrimidine-4,6-dicarboxylate (pmdc) ligand, allows us to obtain good shaped single crystals, while direct addition of potassium oxalate provides the same compounds but as polycrystalline samples. The crystal structures of all compounds are based on the double chelation established by the pmdc and ox ligands to provide distorted 2D honeycomb layers that, in some cases, are fused together, leading to 3D systems, by replacing some of the coordinated water molecules that complete the coordination sphere of the lanthanide by uncoordinated carboxylate oxygen atoms of the pmdc. The presence of channels occupied by crystallization water molecules is also a common feature with the exception of compounds 5-Ln. It is worth noting that compounds 3-Ln present a commensurate crystal structure related to the partial occupancy of the crystallization water molecules placed within the channels. Topological analyses have been carried out, showing a previously nonregistered topology for compounds 4-Ln, named as jcr1. The crystal structures are strongly dependent on the lanthanide ion size and the temperature employed during the hydrothermal synthesis. The lanthanide contraction favors crystal structures involving sterically less hindranced coordination environments for the final members of the lanthanide series. Additionally, reinforcement of the entropic effects at high temperatures directs the crystallization process toward less hydrated crystal structures. The magnetic data of these compounds indicate that the exchange coupling between the lanthanide atoms is almost negligible, so the magnetic behavior is dominated by the spin-orbit coupling and the ligand field perturbation. The luminescence properties that exhibit the compounds containing Nd(III), Eu(III), and Tb(III) have been also characterized. 相似文献
924.
Mole RA Stride JA Henry PF Hoelzel M Senyshyn A Alberola A Gómez Garcia CJ Raithby PR Wood PT 《Inorganic chemistry》2011,50(6):2246-2251
We report the magnetic structure of two of the magnetically ordered phases of Co(3)(OH)(2)(C(4)O(4))(2)·3H(2)O, a coordination polymer that consists of a triangular framework decorated with anisotropic Co(II) ions. The combination of neutron diffraction experiments and magnetic susceptibility data allows us to identify one phase as displaying spin idle behavior, where only a fraction of the moments order at intermediate temperatures, while at the lowest temperatures the system orders fully. This novel magnetic behavior is discussed within the framework of a simple Hamiltonian and representational analysis and rationalizes this multiphase behavior by considering the combination of frustration and anisotropy. 相似文献
925.
The α-alkylidene β-ketoesters 2-carbethoxycyclopentenone (1a) and ethyl 2-benzoylacrylate (1b) react with 1,2-dimethylbutadiene (2) (Diels-Alder), N-benzyl-N-(cyclohexylethynyl)-4-methylbenzenesulfonamide (3) (Ficini reaction), ethynyl(phenyl)sulfane (4) ([2 + 2] cycloaddition), and 1,2,5-trimethyl-1H-pyrrole (5) (Michael addition) in the presence of copper(I) (6) or copper(II) triflate (7) (1-2 mol %) in dichloromethane. This convenient protocol converts 1a and 1b to the corresponding cycloaddition (8-10) or Michael addition (11) products in good yields after reaction times of 0.5-3 h without requiring purified solvents or inert gas atmosphere. 相似文献
926.
Two relevant, recently reported, ruthenium-based complexes to be used as sensitizers in Gra?tzel photovoltaic cells are theoretically studied. The UV/vis absorption spectra have been computed within the time-dependent density functional theory formalism. The obtained excitation energies are compared with the experimental results, and the nature of the transition is analyzed in terms of the electronic density. A preliminary study on the performance of different functionals against the equation of motion coupled cluster is performed on a smaller model system. 相似文献
927.
Conformational preferences of methanediol, dimethoxymethane, methanediamine, and fluoromethanol in the presence of solvents of diverse polarity (water, acetone, and chloroform), modeled with the polarizable continuum model, were analyzed within the framework of the Quantum Theory of Atoms in Molecules. The results indicate that the hydrogens bonded to the anomeric carbon experience the largest reorganization of electron density upon conformational change, as was obtained from previous calculations in the gas phase. When the water solvation is simulated by explicit inclusion of water molecules, the electron density reorganization involved in the cluster formation is significantly different for each conformer of methanediol. As a consequence, similar depletions of electron population are displayed by the hydrogens of hydroxyl and methylene groups in the cluster obtained for the most stable conformer of methanediol, with regard to that built for the completely antiperiplanar conformer. 相似文献
928.
Mascaros PA Bazzicalupi C Bianchi A Giorgi C Valero MD Garzón RL Salido ML Valtancoli B 《Chemical communications (Cambridge, England)》2011,47(10):2814-2816
The synergistic action of the different binding groups of the polyfunctional HL receptor leads to the recognition of ADP over ATP in water, with a selectivity coefficient of up to 116, a phenomenon which is unprecedented in the context of synthetic receptors in water. The recognition is mostly due to the good matching between H(3)L(2+) and the protonated forms of ADP. 相似文献
929.
Alberola A Carter E Constantinides CP Eisler DJ Murphy DM Rawson JM 《Chemical communications (Cambridge, England)》2011,47(9):2532-2534
The β-sheet structure associated with chlorinated aromatics (d(Cl···Cl)≈ 4.0 ?) has been implemented to drive formation of π-stacked structures of dithiadiazolyl radicals. Both title compounds exhibit an increase in paramagnetism above 150 K but solid-state EPR studies indicate that the origin of the paramagnetism in these two systems is different. 相似文献
930.
Barceló-Oliver M Estarellas C Terrón À García-Raso Á Frontera A 《Chemical communications (Cambridge, England)》2011,47(16):4646-4648
We have recently communicated the resemblance of 1-hexyluracil in the crystal state with a lipid bilayer (CrystEngComm, 2010, 12, 362-365). Treatment of this molecule with silver nitrate yields a model, using a non-essential metal ion, of a uracil quartet with geometric parameters comparable to those previously found in RNA strands. 相似文献