Compounds labelled with short-lived beta(+)-emitting radionuclides and some applications in life sciences. The importance of time as a parameter.

Some examples of recent development of the synthesis of compounds labelled with short-lived beta(+)-emitting radionuclides will be discussed with an emphasis on the importance of time in selecting a synthetic strategy. Furthermore the use of such labelled compounds to monitor certain processes in areas within the field of analytical chemistry and in various applications in drug development will be presented.     

Beneficial effects of word final stress in segmenting a new language: evidence from ERPs

Background

How do listeners manage to recognize words in an unfamiliar language? The physical continuity of the signal, in which real silent pauses between words are lacking, makes it a difficult task. However, there are multiple cues that can be exploited to localize word boundaries and to segment the acoustic signal. In the present study, word-stress was manipulated with statistical information and placed in different syllables within trisyllabic nonsense words to explore the result of the combination of the cues in an online word segmentation task.

Results

The behavioral results showed that words were segmented better when stress was placed on the final syllables than when it was placed on the middle or first syllable. The electrophysiological results showed an increase in the amplitude of the P2 component, which seemed to be sensitive to word-stress and its location within words.

Conclusion

The results demonstrated that listeners can integrate specific prosodic and distributional cues when segmenting speech. An ERP component related to word-stress cues was identified: stressed syllables elicited larger amplitudes in the P2 component than unstressed ones.

     

Elastocaloric effect associated with the martensitic transition in shape-memory alloys

The elastocaloric effect in the vicinity of the martensitic transition of a Cu-Zn-Al single crystal has been studied by inducing the transition by strain or stress measurements. While transition trajectories show significant differences, the entropy change associated with the whole transformation (DeltaS_(t)) is coincident in both kinds of experiments since entropy production is small compared to DeltaS_(t). The values agree with estimations based on the Clausius-Clapeyron equation. The possibility of using these materials for mechanical refrigeration is also discussed.     

Polystyrene-supported (R)-2-piperazino-1,1,2-triphenylethanol: a readily available supported ligand with unparalleled catalytic activity and enantioselectivity

A very active and highly enantioselective catalytic resin, designed for minimal perturbation of the catalytic center by the polymer matrix, has been assembled in two steps from (S)-triphenylethylene oxide, piperazine, and Merrifield resin and tested in the enantioselective ethylation of aldehydes. 1-Arylpropanols of 94-95% ee are obtained in high yield by the use of only 2 mol % of catalytic resin at 0 degrees C for 4 h.     

Neighborhood filters and PDE’s

Denoising images can be achieved by a spatial averaging of nearby pixels. However, although this method removes noise it creates blur. Hence, neighborhood filters are usually preferred. These filters perform an average of neighboring pixels, but only under the condition that their grey level is close enough to the one of the pixel in restoration. This very popular method unfortunately creates shocks and staircasing effects. In this paper, we perform an asymptotic analysis of neighborhood filters as the size of the neighborhood shrinks to zero. We prove that these filters are asymptotically equivalent to the Perona–Malik equation, one of the first nonlinear PDE’s proposed for image restoration. As a solution, we propose an extremely simple variant of the neighborhood filter using a linear regression instead of an average. By analyzing its subjacent PDE, we prove that this variant does not create shocks: it is actually related to the mean curvature motion. We extend the study to more general local polynomial estimates of the image in a grey level neighborhood and introduce two new fourth order evolution equations.This work has been partially financed by the Centre National d’Etudes Spatiales (CNES), the Office of Naval Research under grant N00014-97-1-0839, the Ministerio de Ciencia y Tecnologia under grant MTM2005-08567. During this work, the first author had a fellowship of the Govern de les Illes Balears for the realization of his PhD.     

Renaissance notions of number and magnitude

In the 16th and 17th centuries the classical Greek notions of (discrete) number and (continuous) magnitude (preserved in medieval Latin translations of Euclid's Elements) underwent a major transformation that turned them into continuous but measurable magnitudes. This article studies the changes introduced in the classical notions of number and magnitude by three influential Renaissance editions of Euclid's Elements. Besides providing evidence of earlier discussions preparing notions and arguments eventually introduced in Simon Stevin's Arithmétique of 1585, these editions document the role abacus algebra and Renaissance views on the history of mathematics played in bridging the gulf between discrete numbers and continuous magnitudes.     

Electronic structure of AgNbO3 and NaNbO3 studied by X-ray photoelectron spectroscopy

The XPS examinations of the AgNbO₃ and NaNbO₃ single crystals and ceramics allowed estimate their average composition as Ag_1.1Nb_0.9O₃ and Na_1.2Nb_0.9O_2.9. The valence bands of the AgNbO₃ compound, formed mainly of the Nb 4d, Ag 4d and O 2p states, show an energy gap about 3 eV while for the NaNbO₃ compound consist of the O 2p states hybridized with the Nb 3d states and show an energy gap about 4 eV. The chemical shifts of these compounds suggest a mixed ionic and covalent character of the bonds. The broadening of the core level lines of AgNbO₃ suggests a stronger structural disorder in comparison with NaNbO₃ compound.     

On the Set of Cycle Lengths in a Hamiltonian Graph with a Given Maximum Degree

Let n and be two integers such that 2n–1. We describe the set of cycle lengths occurring in any hamiltonian graph G of order n and maximum degree . We conclude that for the case this set contains all the integers belonging to the union [3,2–n+2][n–+2,+1], and for it contains every integer between 3 and +1. We also study the set of cycle lengths in a hamiltonian graph with two fixed vertices of large degree sum. Our main results imply that the stability s(P) for the property of being pancyclic satisfies      

Scaling Algebras for Charged Fields and Short-Distance Analysis for Localizable and Topological Charges

The method of scaling algebras, which has been introduced earlier as a means for analyzing the short-distance behavior of quantum field theories in the setting of the model-independent, operator algebraic approach, is extended to the case of fields carrying superselection charges. In doing so, consideration will be given to strictly localizable charges (DHR-type superselection charges) as well as to charges which can only be localized in regions extending to spacelike infinity (BF-type superselection charges). A criterion for the preservance of superselection charges in the short-distance scaling limit is proposed. Consequences of this preservance of superselection charges are studied. The conjugate charge of a preserved charge is also preserved, and for charges of DHR-type, the preservance of all charges of a quantum field theory in the scaling limit leads to equivalence of local and global intertwiners between superselection sectors.Communicated by Klaus Fredenhagensubmitted 21/01/03, accepted 26/02/04     

Self-regulation of E x B flow shear via plasma turbulence

The momentum balance has been applied to the ExB flow in the edge region of a reversed field pinch (RFP) configuration. All terms, including those involving fluctuations, have been measured in stationary condition in the edge region of the Extrap-T2R RFP experiment. It is found that the component of the Reynolds stress driven by electrostatic fluctuations is the term playing the major role in driving the shear of the ExB flow to a value marginal for turbulent suppression, so that the results are in favor of a turbulence self-regulating mechanism underlying the momentum balance at the edge. Balancing the sheared flow driving and damping terms, the plasma viscosity is found anomalous and consistent with the diffusivity due to electrostatic turbulence.