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801.
Antonella Fiacca Nikolas Matzakos S. Papageorgiou Raffaella Servadei 《Czechoslovak Mathematical Journal》2003,53(1):135-159
In this paper we study nonlinear elliptic boundary value problems with monotone and nonmonotone multivalued nonlinearities. First we consider the case of monotone nonlinearities. In the first result we assume that the multivalued nonlinearity is de_ned on all
. Assuming the existence of an upper and of a lower solution, we prove the existence of a solution between them. Also for a special version of the problem, we prove the existence of extremal solutions in the order interval formed by the upper and lower solutions. Then we drop the requirement that the monotone nonlinearity is defined on all of
. This case is important because it covers variational inequalities. Using the theory of operators of monotone type we show that the problem has a solution. Finally, in the last part we consider an eigenvalue problem with a nonmonotone multivalued nonlinearity. Using the critical point theory for nonsmooth locally Lipschitz functionals we prove the existence of at least two nontrivial solutions (multiplicity theorem). 相似文献
802.
E. Di Pace A. M. Fichera P. Laurienzo M. Malinconico E. Martuscelli N. Perenze M. G. Volpe 《Journal of Polymer Science.Polymer Physics》1994,32(9):1643-1651
A new series of poly(ether-alkyl)oxadiazoles of general formula: with m = 3, 4, and 5 has been obtained from the corresponding polyhydrazides through thermal cyclization reaction. The polymers were characterized by infrared spectroscopy, differential scanning calorimetry, wide-angle x-ray analysis, and optical microscopy. The polymers were crystalline, with a crystalline texture and structural parameters strongly dependent on the value of m. The Tm's and Tg's value decreased with increasing number of CH2. © 1994 John Wiley & Sons, Inc. 相似文献
803.
Marina Scandola David E. Games Carlo Costa Graziella Allegri Antonella Bertazzo Ornella Curcuruto Pietro Traldi 《Journal of heterocyclic chemistry》1994,31(1):219-224
Various alkaloids obtained from the methanol extracts of the roots of Securidaca Longipedunculata Fres. were studied using supercritical fluid chromatography/mass spectrometry. This hyphenated method and parallel unimolecular and collisionally activated decomposition experiments on electron impact-generated molecular ions gave information on the structure of compounds. The presence of the ergoline skeleton in some of them was assigned. 相似文献
804.
Antonella Buraggina 《Annali dell'Universita di Ferrara》1982,38(1):249-262
We provide sufficient conditions for the connectedness of the Hartshorne-Rao module of integral subcanonical curves and of
the first cohomology module for rank two vector bundles on projective space.
Sunto Si danno condizioni sufficienti per la connessità del modulo di Hartshorne-Rao di una curva integra sottocanonica e del primo modulo di coomologia di un fibrato vettoriale di rango due sullo spazio proiettivo.相似文献
805.
We investigate transverse effects in collective atomic recoil lasing (CARL), where a cold atomic sample is lightened by a far detuned laser beam resonant with the internal atomic transition. The gradient force of the scattered radiation field produces a collective self-focusing on the atoms, which could be observed in a Bose-Einstein condensate stored in a bidirectional optical ring cavity or in the superradiant CARL-BEC regime. 相似文献
806.
Armando Marzotto Dore Augusto Clemente Antonella Ciccarese Giovanni Valle 《Journal of chemical crystallography》1993,23(2):119-131
With the aim to obtain further insight into the nature of the Ni(II)-nitrogen bond in complexes with nucleobases, we have synthesized two novel Ni(II) ternary complexes constituted by Ni(II), tris(2-aminoethyl)amine (tren) and neutral adenine (AdH) or imidazole (ImH). The reaction of NiCl2·6H2O with tren and imidazole yields the ternary [Ni(tren)(ImH)(H2O)]Cl2·H2O complex and the same reaction with adenine instead of imidazole gives the ternary [Ni(tren)(AdH)Cl]Cl complex. The complexes have been studied by spectrophotometric and spectroscopic measurements and by X-ray diffraction. The ternary complex of adenine is monoclinic, space groupC2/c, and exhibits a pseudo-octahedral geometry, being Ni(II) coordinated to the four nitrogen atoms of the tetradentate tren ligand, to a Cl– ion and to the pyrimidine N3 site of a neutral adenine. Such an exclusive Ni-N3 bonding [2.081(4)Å] is now reported for the first time. The ternary complex of imidazole is monoclinic, space groupP21/n. Its pseudo-octahedral geometry is similar to that found in the above adenine complex although a water molecule instead of a Cl– ion is now present in the coordination sphere. In fact, Ni(II) is coordinated to tetradentate tren, to the imidazole N1 nitrogen and to a water molecule. Electronic and1H NMR spectra in solution indicate that the octahedral structures found in the solid state are substantially maintained in solution. Furthermore, the present investigation suggests that the adenine Ni-N3 and imidazole Ni-N1 bonds have the same chemical nature, involving mainly - and only partially-bonding. The Ni-N3 bonding is discussed in connection with biological implications and possible applications. 相似文献
807.
The present review deals with novel developments in immunosensors destined for final application in food analysis. In this perspective particular emphasis will be given to the most important approaches which recently have been used for immunosensor construction and assembling. For this reason, electrochemical, surface plasmon resonance (SPR) and quartz crystal microbalance (QCM) techniques will be explored in detail and recent and practical examples on food matrices will be reviewed. Objective of this survey is to give a general overview of the possible application of immunosensors to the food analysis field. 相似文献
808.
Cametti M Dalla Cort A Colapietro M Portalone G Russo L Rissanen K 《Inorganic chemistry》2007,46(22):9057-9059
The isolation of complexes 2 and 3, unambiguously characterized by single-crystal X-ray diffraction, demonstrates that nucleophilic additions to the aluminum-coordinated imino bond of salophen complex 1 can be achieved under very mild conditions. 相似文献
809.
van Axel Castelli V Dalla Cort A Mandolini L Pinto V Schiaffino L 《The Journal of organic chemistry》2007,72(14):5383-5386
The Et3N-assisted addition of benzenethiol to enones in chloroform is catalyzed with high turnover efficiency by the phenyl-substituted uranyl-salophen compound 3. Catalytic data show a close adherence to a quatermolecular mechanism involving reaction of a base-activated thiol with a reversibly formed complex of enone and metal catalyst, with a complication of product inhibition due to the formation of a product-catalyst complex. The role of the binding energy made available by interactions with the aromatic sidearm of the catalyst is discussed in terms of catalyst-substrate and catalyst-transition state complementarity. 相似文献
810.
We report here a convenient and simple solid-phase synthesis of N-nosyl-N-methyl-alpha-amino acids and N-Fmoc-N-methyl-alpha-amino acids, important building blocks for the synthesis of conformationally restricted and protease-resistant natural peptides and peptide analogues. The methodology involves the use of 2-chlorotrityl chloride resin to temporarily protect the carboxylic group of alpha-amino acids and of diazomethane as the reagent to methylate the sulfonamidic function. The approach developed is particularly efficient also with alpha-amino acids bearing appropriately protected functionalized side chains. 相似文献