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91.
Merceron N Miqueu K Baceiredo A Bertrand G 《Journal of the American Chemical Society》2002,124(24):6806-6807
(Amino)(phosphino)carbenes are stable due to the donation of the nitrogen lone pair, the phosphino group remains strongly pyramidalized. Reactions can be performed selectively at the carbene center, but also at the phosphorus center leading to new stable carbenes. These difunctional molecules can be considered as hybrid ligands. 相似文献
92.
A strong electric susceptibility is measured as a function of temperature in a molecular dimer which is weakly bound by a pair of hydrogen bonds. This system is a remarkable example where the dominant term in the susceptibility is due to a vibration induced electric dipole. As a consequence, the averaged square of the dipole moment varies linearly with the temperature and the susceptibility does not follow the usual 1/T Curie law. this spectacular effect demonstrates the importance of dynamics to interpret the properties of weakly bound complexes. 相似文献
93.
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95.
We examine the robustness of ultrashort optical vortices propagating freely in the atmosphere. We first approximate the stability regions of femtosecond spinning pulses as a function of their topological charge. Next, we numerically demonstrate that atmospheric optical vortices are capable of conveying high power levels in air over hundreds of meters before they break up into filaments. 相似文献
96.
Luis A.?CaffarelliEmail author Ki-Ahm?Lee Antoine?Mellet 《Archive for Rational Mechanics and Analysis》2004,172(2):153-190
This paper is concerned with a class of singular equations modelling the combustion of premixed gases in periodic media. The model involves two parameters: the period of the medium |L| and a singular parameter related to the activation energy. The existence of pulsating travelling fronts for fixed and |L| was proved by Berestycki & Hamel in [BH]. In the present paper, we investigate the behaviour of such solutions when
More precisely, we establish that pulsating travelling fronts behave like travelling waves, when the period |L| is small and . We also study the convergence of the solution, as goes to zero (and |L| is fixed), toward a solution of a free boundary problem. 相似文献
97.
Antoine?AyacheEmail author Murad S.?Taqqu 《Journal of Fourier Analysis and Applications》2003,9(5):451-471
Consider the fractional Brownian motion process $B_H(t), t\in [0,T]$,
with parameter $H\in (0,1)$.
Meyer, Sellan and Taqqu have developed
several random wavelet representations for
$B_H(t)$, of the form $\sum_{k=0}^\infty
U_k(t)\epsilon_k$ where $\epsilon_k$ are Gaussian random
variables and where the functions $U_k$ are not random. Based on the
results of Kühn and Linde, we say that the
approximation $\sum_{k=0}^n U_k(t)\epsilon_k$ of $B_H(t)$
is optimal if
$$
\displaystyle
\left( E \sup_{t\in [0,T]} \left| \sum_{k=n}^\infty U_k(t)
\epsilon_k\right|^2 \right)^{1/2} =O
\left( n^{-H} (1+\log n)^{1/2} \right),
$$
as $n\rightarrow\infty$. We show that the random wavelet
representations given in Meyer, Sellan and
Taqqu are optimal. 相似文献
98.
Coron A Vanhamme L Antoine JP Van Hecke P Van Huffel S 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2001,152(1):26-40
Suppressing the solvent peak is important in many applications of biomedical NMR spectroscopy in order to quantify the metabolites with a great accuracy. Among the postprocessing methods proposed in the literature, many deal with the concept of filtering. However, several proposals lack a theoretical perspective and some have not been explicitly applied to quantification problems. The present article is intended to bridge this gap: five methods are analyzed from a theoretical perspective. Subsequently the different methods are applied to the same set of data, and then the latter are quantified using the model fitting method AMARES. With our set, the scheme proposed by T. Sundin et al. (J. Magn. Reson. 139(2), 189-204 (1999)) proved to be the most reliable method. 相似文献
99.
BACKGROUND: Supracricoid partial laryngectomy (SCPL) results in laryngeal preservation in more than 95% of patients with T2 glottic carcinoma. Postsurgical glottic function is characterized by an absence of vocal cords, and phonation quality is a key post-SCPL quality-of-life factor. OBJECTIVE: This investigation was designed to enhance post-SCPL vocal function, study anatomic function of the post-SCPL larynx, and correlate anatomic findings with perceptual and instrumented measurements of voice. METHOD: Twenty-five patients were included. All had undergone SCPL with cricoepiglottopexy for T2 glottic carcinoma. All patients were evaluated by laryngostroboscopic examination, voice sample recording, and instrumented voice analysis with the aim of gaining further insight into postoperative larynx function. Laryngostroboscopic parameters such as laryngeal occlusion, epiglottic length, arytenoid movement, and vibratory area were assessed. The perceptual evaluation was based on the GRBAS scale. Acoustic and aerodynamic parameters were recorded, including fundamental frequency (F0), intensity, jitter, shimmer, signal-to-noise ratio (SNR), oral airflow (OAF), maximum phonation time (MPT), and estimated subglottic pressure (ESGP). Nonparametric tests were used to compare laryngostroboscopic parameters with instrumented measurements and perceptual evaluations of voice quality. RESULTS: Correlations were established among occlusion, epiglottic length, and general grade of dysphonia. Oral air flow (P = 0.006) was found to be correlated with occlusion. Voice roughness was correlated with the presence of a clearly identifiable vibratory area (P = 0.003), whereas these vibratory areas were correlated with shimmer (P = 0.041), OAF (P = 0.001), and SNR (P = 0.001). The number of preserved arytenoids was not identified as a voice quality factor (P = 0.423). CONCLUSION: This study highlighted correlations between the laryngostroboscopic examination results and the perceptive and instrumented measurements of voice. Glottis occlusion and epiglottis length were found to be key factors for postoperative voice quality. These results should help to advance technical development on surgical techniques to enhance voice results. 相似文献
100.
The condensation reaction between polymerised formaldehyde and a ketone possessing a methylene group α to the carbonyl function, in the presence of a polystyrene (1) or fluorinated (2) ion-exchange catalyst, leads to the corresponding 1,3-dioxane and is characterized by excellent yield and selectivity. 相似文献