全文获取类型
收费全文 | 8272篇 |
免费 | 435篇 |
国内免费 | 195篇 |
专业分类
化学 | 5052篇 |
晶体学 | 85篇 |
力学 | 343篇 |
综合类 | 25篇 |
数学 | 1301篇 |
物理学 | 2096篇 |
出版年
2023年 | 83篇 |
2022年 | 195篇 |
2021年 | 204篇 |
2020年 | 220篇 |
2019年 | 213篇 |
2018年 | 199篇 |
2017年 | 167篇 |
2016年 | 295篇 |
2015年 | 250篇 |
2014年 | 285篇 |
2013年 | 576篇 |
2012年 | 540篇 |
2011年 | 585篇 |
2010年 | 366篇 |
2009年 | 316篇 |
2008年 | 429篇 |
2007年 | 373篇 |
2006年 | 366篇 |
2005年 | 333篇 |
2004年 | 220篇 |
2003年 | 239篇 |
2002年 | 206篇 |
2001年 | 176篇 |
2000年 | 159篇 |
1999年 | 125篇 |
1998年 | 76篇 |
1997年 | 70篇 |
1996年 | 84篇 |
1995年 | 58篇 |
1994年 | 93篇 |
1993年 | 71篇 |
1992年 | 85篇 |
1991年 | 70篇 |
1990年 | 63篇 |
1989年 | 55篇 |
1988年 | 51篇 |
1987年 | 44篇 |
1986年 | 44篇 |
1985年 | 66篇 |
1984年 | 68篇 |
1982年 | 65篇 |
1981年 | 58篇 |
1980年 | 61篇 |
1979年 | 54篇 |
1978年 | 63篇 |
1977年 | 57篇 |
1976年 | 52篇 |
1975年 | 41篇 |
1974年 | 43篇 |
1973年 | 41篇 |
排序方式: 共有8902条查询结果,搜索用时 0 毫秒
71.
72.
73.
Van Bang Le 《Periodica Mathematica Hungarica》1993,27(2):105-124
For a finite or infinite graphG, theGallai graph (G) ofG is defined as the graph whose vertex set is the edge setE(G) ofG; two distinct edges ofG are adjacent in (G) if they are incident but do not span a triangle inG. For any positive integert, thetth iterated Gallai graph
t
(G) ofG is defined by (
t–1(G)), where 0(G):=G. A graph is said to beGallai-mortal if some of its iterated Gallai graphs finally equals the empty graph. In this paper we characterize Gallai-mortal graphs in several ways. 相似文献
74.
We adapted the genetic algorithm to minimize the AMBER potential energy function. We describe specific recombination and mutation operators for this task. Next we use our algorithm to locate low energy conformation of three polypeptides (AGAGAGAGA, A9, and [Met]-enkephalin) which are probably the global minimum conformations. Our potential energy minima are –94.71, –98.50, and –48.94 kcal/mol respectively. Next, we applied our algorithm to the 46 amino acid protein crambin and located a non-native conformation which had an AMBER potential energy 150 kcal/mol lower than the native conformation. This is not necessarily the global minimum conformation, but it does illustrate problems with the AMBER potential energy function. We believe this occurred because the AMBER potential energy function does not account for hydration. 相似文献
75.
ω-Acyloxy n-butylidenetriphenylphosphoranes give α-acyl n-butylidenetriphenylphosphoranes by intermolecular condensation in t-BuOH, and 3,4-dihydro-(2H)-pyrans by intramolecular condensation in toluene. The α-acyl n-butylidene phosphoranes, which are the tautomeric form of α-acyloxaphosphanes, do not lead to cyclobutylketones but to dihydropyrans. 相似文献
76.
Bernard Demerseman Pascale Le Coupanec Pierre H. Dixneuf 《Journal of organometallic chemistry》1985,287(3):C35-C38
13C NMR measurements were performed on [Re3(μ-H)3(CO)10]2? at various temperatures and field strengths. Selective decoupling allowed assignments of the carbonyl resonances. Spin-lattice relaxation time measurements indicated that two mechanisms, scalar coupling and chemical shielding anisotropy, contribute to the relaxation of carbon-13. Variable temperature experiments revealed that more than one mechanism is responsible for the fluxional behaviour. 相似文献
77.
The composition of the essential oil of Bifora radians, an aldehyde-producing weed, has been investigated by capillary gas chromatography, coupled gas chromatography – mass spectrometry, on-line catalytic hydrogenation and coupled gas chromatography – infrared spectrometry. The nineteen compounds identified included eighteen aldehydes: seven alkanals (C6, C9, C10, C11, C12, C13, and C14), ten alkenals, including five (E)-2-alkenals (C12, C13, C14, C15, and C16), and one (E,E)-2,4-alkadienal (C13). Typical Bifora odors were attributed to three major (E)-2-alkenals, C12, C13, and C14. 相似文献
78.
De Wasch K Le Bizec B De Brabander H André F Impens S 《Rapid communications in mass spectrometry : RCM》2001,15(16):1442-1447
In previous work (Le Bizec et al., Rapid Commun. Mass Spectrom. 2000; 14: 1058), it was demonstrated that a boar meal intake could lead to possible false accusations of abuse of 17beta-nortestosterone in antidoping control. The aim of the present study was to identify and quantify endogenous 19-norsteroids in boar edible tissue at concentrations that can alter the steroid urinary profile in humans, and lead to excretion of 19-norandrosterone (19-NA) and 19-noretiocholanolone (19-NE). The samples were analysed in two laboratories. The methodologies used for extraction and detection (GC/MS(EI) and LC/MS/MS(APCI+)) are compared and discussed. 19-Norandrostenedione (NAED), 17beta- and 17alpha-nortestosterone (bNT, aNT), and 17beta- and 17alpha-testosterone (bT, aT) were quantified. The largest concentrations of NAED and bNT were observed in testicles (83 and 172 microg/kg), liver (17 and 63 microg/kg) and kidney (45 and 38 microg/kg). A correlation between the bNT and NAED content of a typical meal prepared with boar parts and the excreted concentrations of 19-NA and 19-NE in human urine was demonstrated. 相似文献
79.
E. G. Le Roux M. Peisach C. A. Pineda M. A. B. Pougnet 《Journal of Radioanalytical and Nuclear Chemistry》1988,120(1):97-104
The split-root technique was used to study the effect of varying the growth media on the elemental content of nutrient elements in the roots of grape vines. The varieties 2-1 (R99 x Jacquez) and Sauvignon blanc (Vitis vinifera) were grown in Hoagland water culture with and without added aluminium. The elemental concentrations of Mg, Al, Si, P. S, Cl, K and Ca in the dried roots were determined by PIXE. Roots grown in Al-rich media were deficient in Mg and Ca, but enriched in Al. There was a correlation between Al and Si but the uptake differed in the two varieties. 相似文献
80.
A competitive enzyme-linked immunosorbent assay (ELISA) was developed for the quantitative detection of the insect growth regulator fenoxycarb. Polyclonal rabbit antisera, raised against protein conjugates of four haptenic derivatives of fenoxycarb, were utilized in immobilized antigen-based, competitive immunoassays. With ELISA systems that were both hapten- and carrier-heterologous, most antiserum titers fell in the range of 1:1000-1:30,000. Assay conditions, including concentrations of antisera and coating antigens, were optimized. The effect of pH, organic solvents, and various blocking agents was also investigated. A hapten-homologous and two hapten-heterologous indirect ELISAs allowed fenoxycarb determination in the range of 0.1-85 ng ml−1 with apparent IC50 values of 1.2-2.8 ng ml−1. Cross-reactivities with a number of compounds (e.g. pesticides of related structure, hapten synthesis intermediates, fenoxycarb metabolite, photodegradation products) were determined, and the assay proved highly selective for fenoxycarb. In particular, no significant interference was found with selected pyrethroid and juvenile hormone analog insecticides, phenoxyacetic acid herbicides, and photodegradation products of fenoxycarb. Using spiked water samples, assay performance was validated by SPME/GC-MS. 相似文献