Homogenization of divergence-form operators with lower-order terms in random media

The probabilistic machinery (Central Limit Theorem, Feynman-Kac formula and Girsanov Theorem) is used to study the homogenization property for PDE with second-order partial differential operator in divergence-form whose coefficients are stationary, ergodic random fields. Furthermore, we use the theory of Dirichlet forms, so that the only conditions required on the coefficients are non-degeneracy and boundedness. Received: 27 August 1999 / Revised version: 27 October 2000 / Published online: 26 April 2001     

An improved On-Surface Radiation Condition for acoustic scattering problems in the high-frequency spectrum

This Note addresses the derivation of an improved On-Surface Radiation Condition for the numerical solution of the exterior Helmholtz equation at high-frequencies. This condition is built as an approximation of the Neumann-to-Dirichlet map by using a local regularization of its principal classical symbol in the gliding zone for modelling the creeping waves. The numerical simulation of this pseudodifferential operator is efficiently realized with a linear cost according to the dimension of the boundary element approximation space using suitable complex Padé approximants. A numerical example is provided. To cite this article: X. Antoine et al., C. R. Acad. Sci. Paris, Ser. I 340 (2005).     

Estimation of the bias parameter of the skew random walk and application to the skew Brownian motion

We study the asymptotic property of simple estimator of the parameter of a skew Brownian motion when one observes its positions on a fixed grid—or equivalently of a simple random walk with a bias at 0. This estimator, nothing more than the maximum likelihood estimator, is based only on the number of passages of the random walk at 0. It is very simple to set up, is consistent and is asymptotically mixed normal. We believe that this simplified framework is helpful to understand the asymptotic behavior of the maximum likelihood of the skew Brownian motion observed at discrete times which is studied in a companion paper.     

Toute forme modérément ramifiée d’un polydisque ouvert est triviale

Let k be a complete, non-Archimedean field and let X be a k-analytic space. Assume that there exists a finite, tamely ramified extension L of k such that X _L is isomorphic to an open polydisc over L ; we prove that X is itself isomorphic to an open polydisc over k. The proof consists in using the graded reduction (a notion which is due to Temkin) of the algebra of functions on X, together with some graded counterparts of classical commutative algebra results : Nakayama’s lemma, going-up theorem, basic notions about étale algebras, etc.     

Stability of Generalized Transition Fronts

We study the qualitative properties of the generalized transition fronts for the reaction–diffusion equations with the spatially inhomogeneous nonlinearity of the ignition type. We show that transition fronts are unique up to translation in time and are globally exponentially stable for the solutions of the Cauchy problem. The results hold for reaction rates that have arbitrary spatial variations provided that the rate is uniformly positive and bounded from above.     

Direct Comparison of Subvalent,Polycationic Group 13 Cluster Compounds: Lessons learned on Isoelectronic DMPE Substituted Gallium and Indium Tetracation Salts

The tetracationic, univalent cluster compounds [{M(dmpe)}₄]⁴⁺ (M=Ga, In; dmpe=bis(dimethylphosphino)ethane) were synthesized as their pf salts ([pf]⁻=[Al(OR^F)₄]⁻; R^F=C(CF₃)₃). The four-membered ring in [{M(dmpe)}₄]⁴⁺ is slightly puckered for M=Ga and almost square planar for M=In. Yet, although structurally similar, only the gallium cluster is prevalent in solution, while the indium cluster forms temperature dependent equilibria that include even the monomeric cation [In(dmpe)]⁺. This system is the first report of one and the same ligand inducing formation of isoelectronic and isostructural gallium/indium cluster cations. The system allows to study systematically analogies and differences with thermodynamic considerations and bonding analyses, but also to outline perspectives for bond activation using cationic, subvalent group 13 clusters.     

CO2 Hydroboration: Impact of the Boryl Moieties on the Reactivity of Four Bis(boryl)acetal Compounds toward 2,6-Diisopropylaniline

The hydroboration of CO₂ into bis(boryl)acetal (BBA) compounds is an important transformation, since it enabled to selectively reduce CO₂ by 4e^- and to subsequently use the BBA compounds as C₁ and C_n sources. However, the influence of the nature of the boryl moieties on the reactivity of BBA compounds has not been evaluated so far. In the present study, four BBA compounds – including two new ones – were reacted with 2,6-diisopropylaniline to afford the expected imine. Significant differences in the rate of the reaction from minutes to weeks have been observed depending on the BBA used, showing the importance of the nature of the boryl moieties. Theoretical investigations enabled to propose a mechanism involving the addition of the aniline to the BBA as the rate-determining step and to determine that the steric hindrance of the BBA compounds is the main factor driving the rate of this condensation reaction.