Fluorimetric metal ion sensing usingN-methyl-9-anthrylhydroxamic acid

We have synthesizedN-methyl-9-anthrylhydroxamic acid, which is a fluorescent analogue ofN-methylbenzohydroxamic acid. Complexation with various di- and trivalent metal ions occurs (logK from 4 to 5) in water with resulting fluorescence quenching. Because the Fe(III) and Al(III) complexes substituted rather slowly, the addition of EDTA provides a temporal method for obtaining some selectivity in the chemosensor.     

Architectural issues related to the optical implementation of an EGS network based on embedded control

Free-space optical implementations of switching networks have been proposed to circumvent many of the system-level problems that may be encountered in systems that require many high-density, high-bandwidth connections. The details of a new class of switching network (the EGS network), that is well-suited to free-space implementations, is described. The common control injection problem that plagues most free-space photonic networks, i.e. how can control information from an electronic source be injected into the network for applications that require relatively high network reconfiguration rates, is examined. A new technique for control injection, called embedded control, which permits network operation even with relatively high network reconfiguration rates is also proposed.     

Kaon condensation and lambda–nucleon loop in the relativistic mean-field approach

The possibility of kaon condensation in high-density symmetric nuclear matter is investigated including both s- and p-wave kaon–baryon interactions within the relativistic mean-field (RMF) theory. Above a certain density, we have a collective state carrying the same quantum numbers as the antikaon. The appearance of the state is caused by the time component of the axial-vector interaction between kaons and baryons. It is shown that the system becomes unstable with respect to condensation of K– pairs. We consider how the effective baryon masses affect the kaon self-energy coming from the time component of the axial-vector interaction. Also, the role of the spatial component of the axial-vector interaction on the possible existence of the collective kaonic states is discussed in connection with Λ-mixing effects in the ground state of high-density matter. Implications of condensation for high-energy heavy-ion collisions are briefly mentioned.     

Elliptic and circular dichroism effects in two-photon double ionization of atoms

An ab initio parametrization of the two-photon double ionization amplitude from an s2 subshell of an atom in a 1S state is presented and used to predict two light polarization effects on photoelectron angular distributions that do not exist in single-photon double ionization: (i) elliptic dichroism and (ii) circular dichroism at equal energy sharing. Estimates for He show large magnitudes for these effects, which provide a means for polarization control of double ionization by vacuum ultraviolet light.     

The impact of polystyrene resins in solid-phase organic synthesis

Summary A major objective of the DIVERSOMER^® technology is to provide pure and characterized compounds for biological testing in order to prevent false negatives in our libraries. On several occasions, analysis of the final products by¹H-NMR and MS, has revealed by-products from the polystyrene solid support. Subsequently, three alternative methods were studied to remove polystyrene by-products; (i) prewashing of the resin prior to execution of the synthesis; (ii) pretreatment of the resin with the cleavage conditions consistent with the solid-phase synthesis reaction scheme; and (iii) parallel purification.     

The contribution of 2N photon absorption in C(γ,2N) reactions for Eγ = 150–400 MeV

The ¹²C(γ,pn) and ¹²C(γ,pp) reactions have been studied using tagged photons of energy E_γ = 150–400 MeV. Recoil momentum distributions are compared to the results of Monte Carlo calculations based on a two-nucleon photon absorption model and two different phase space models. The ¹²C(γ,pn) data at low missing energy are consistent with absorption on 1p² and 1s1p nucleon pairs.     

Resonant shattering of neutron star crusts

The resonant excitation of neutron star (NS) modes by tides is investigated as a source of short gamma-ray burst (SGRB) precursors. We find that the driving of a crust-core interface mode can lead to shattering of the NS crust, liberating ～10{46}-10{47} erg of energy seconds before the merger of a NS-NS or NS-black-hole binary. Such properties are consistent with Swift/BAT detections of SGRB precursors, and we use the timing of the observed precursors to place weak constraints on the crust equation of state. We describe how a larger sample of precursor detections could be used alongside coincident gravitational wave detections of the inspiral by Advanced LIGO class detectors to probe the NS structure. These two types of observations nicely complement one another, since the former constrains the equation of state and structure near the crust-core boundary, while the latter is more sensitive to the core equation of state.     

Double and triple ionization of silver clusters by electron impact

The production of silver cluster cations Ag(n)(2+) (for several selected sizes in the range n = 39-119) and Ag(n)(3+) (for n = 58, 61, 67) by electron impact ionization of neutral precursors has been studied. The scaling of appearance energies with cluster radius follows the metallic droplet model but, curiously, with a slope which is estimated to be quite different from the literature values for single ionization, Ag(n)(+), as well as for the appearance of smaller Ag(n)(2+) ions. It is also found that as the electron energy increases, the yield of high-charge cations grows faster than that of singly-charged Ag(n)(+). This behavior is consistent with the power-law dependence of post-threshold ionization. The mechanisms involved in multiple ionization phenomena in clusters of noble metals are not yet fully understood and call for further experimental and theoretical examination.     

Nonlinear optical study of palladium Schiff base complex using femtosecond differential optical Kerr gate and Z-scan techniques

A femtosecond differential optical Kerr gate (DOKG) and Z-scan techniques, have been applied to investigate the third-order optical nonlinearity of composite film of the coordination complex [PdLPPh₃] (L=N-(2-pyridyl)-N′-(salicylidene)hydrazine, PPh₃=triphenylphosphine). Film exhibits superior nonlinear optical properties in the near-infrared spectral region. The nonlinear response time and third-order nonlinear optical susceptibility of complex were found to be≤90 fs and 3.9×10^?10 esu, respectively. The Z-scan result shows that saturable absorption property of the film and its nonlinear absorption coefficient of the sample was found to be ?23 cm/GW.