Surface Modified Single Molecules Free-Diffusion Evidenced by Fluorescence Correlation Spectroscopy

We report on the free diffusion of single molecule near an interface studied using fluorescence correlation spectroscopy. In particular, we show that the chemical nature of the substrate may modify the free diffusion of a widely used molecule (rhodamine 6G), thus inducing unexpected effects in fluorescence correlation spectroscopy measurements. Our results show a strong influence, up to a few micrometer from the interface, of the surface polarity. This effect is assessed through the relative weight of the two dimensions diffusion process observed close to the surface. Our results are discussed in terms of competition between surface-solvent, solvent-molecule and molecule-surface specific interactions.     

Molecular dynamics as studied by static-powder and magic-angle spinning 2H NMR

The 2H NMR magic-angle spinning (MAS) technique is compared to the static-powder quadrupole echo (QE) and Jeener-Brockaert (JB) pulse sequences for a quantitative investigation of molecular dynamics in solids. The linewidth of individual spinning sidebands of the one-dimensional MAS spectra are observed to be characteristic of the correlation time from approximately 10(-2) to approximately 10(-8) s so that the dynamic range is increased by approximately three orders of magnitude when compared to the QE experiment. As a consequence, MAS 2H NMR is found to be more sensitive to the presence of an inhomogeneous distribution of correlation times than the QE and JB experiments which rely upon lineshape distortions due to anisotropic T2 and T1Q relaxation, respectively. All these results are demonstrated experimentally and numerically using the two-site flip motion of dimethyl sulfone and of the nitrobenzene guest in the alpha-p-tert-butylcalix[4]arene-nitrobenzene inclusion compound.     

Scattering Below Critical Energy for the Radial 4D Yang-Mills Equation and for the 2D Corotational Wave Map System

Given g and f  =  gg′, we consider solutions to the following non linear wave equation :

Nonsmoothness in Machine Learning: Specific Structure,Proximal Identification,and Applications

Set-Valued and Variational Analysis - Nonsmoothness is often a curse for optimization; but it is sometimes a blessing, in particular for applications in machine learning. In this paper, we present...     

Resolvent analysis in unbounded flows: role of free-stream modes

Theoretical and Computational Fluid Dynamics - The problem of finding optimal forcing and response for unbounded base flows, exemplified by the Blasius boundary layer, is assessed by means of a...     

A Review of Fractional Order Entropies

Fractional calculus (FC) is the area of calculus that generalizes the operations of differentiation and integration. FC operators are non-local and capture the history of dynamical effects present in many natural and artificial phenomena. Entropy is a measure of uncertainty, diversity and randomness often adopted for characterizing complex dynamical systems. Stemming from the synergies between the two areas, this paper reviews the concept of entropy in the framework of FC. Several new entropy definitions have been proposed in recent decades, expanding the scope of applicability of this seminal tool. However, FC is not yet well disseminated in the community of entropy. Therefore, new definitions based on FC can generalize both concepts in the theoretical and applied points of view. The time to come will prove to what extend the new formulations will be useful.     

A Variable Metric Extension of the Forward–Backward–Forward Algorithm for Monotone Operators

We propose a variable metric extension of the forward–backward-forward algorithm for finding a zero of the sum of a maximally monotone operator and a monotone Lipschitzian operator in Hilbert spaces. In turn, this framework provides a variable metric splitting algorithm for solving monotone inclusions involving sums of composite operators. Monotone operator splitting methods recently proposed in the literature are recovered as special cases.     

Non-coercive Linear Elliptic Problems

We study here some linear elliptic partial differential equations (with Dirichlet, Fourier or mixed boundary conditions), to which convection terms (first order perturbations) are added that entail the loss of the classical coercivity property. We prove the existence, uniqueness and regularity results for the solutions to these problems.     

Increment sizes of the principal value of Brownian local time

Let W be a standard Brownian motion, and define Y(t)= ∫₀ ^t ds/W(s) as Cauchy's principal value related to local time. We determine: (a) the modulus of continuity of Y in the sense of P. Lévy; (b) the large increments of Y. Received: 1 April 1999 / Revised version: 27 September 1999 / Published online: 14 June 2000