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41.
Sodium cleaves elemental tellurium, TeX, quantitatively to Te2– 2 and Te2- in anhydrous tetrahydrofuran in the presence of catalytic amounts of naphthalene. Subsequent addition of alkylating agent affords dialkyl tellurides and dialkyl ditellurides in excellent yields. 相似文献
42.
A new alternative system for the oxidation of secondary alcohols to ketones with DMSO/N2H4.H2O/I2/H2O/CH3CN in hydrated media has been developed. The system also selectively oxidizes the secondary alcoholic groups to the corresponding ketones in the presence of primary alcoholic groups present within the same molecule in moderate to very good yields at reflux temperature. 相似文献
43.
The analytically derived predictions of a recently developed theory on phase conjugate four wave mixing (FWM) in two-level atoms [Phys. Rev. A 60, 1672 (1999)], which interprets many of the signal features as a consequence of quantum interference between the probability amplitudes for photon emission from relevant dressed states, is compared to the results that one obtains from a non-perturbative, numerical calculation of the density matrix equations. The results delineate the regimes and assumptions under which the perturbative results are valid, and it is shown that despite the simplifying assumptions that are invoked for the dressed state theory, many of its predictions are in qualitative agreement with the exact, numerical results. 相似文献
44.
D. Gautam 《Tetrahedron letters》2010,51(32):4199-4201
A stereoselective approach for the synthesis of (+)-(1R,2S,5S,7R)-2-hydroxy-exo-brevicomin from l-ascorbic acid has been described. The key steps are highly stereoselective nucleophilic addition reaction on aldehyde 8 and also a single pot transformation of 15 to (+)-(1R,2S,5S,7R)-2-hydroxy-exo-brevicomin. The later tandem reaction which involves the hydrogenation of double bond, debenzylation, MOM deprotection and bicyclic ketal formation was carried under Pd/C, H2 followed by acid treatment. 相似文献
45.
V. K. Sharma Mala N. Rao Siddharth Gautam A. K. Tripathi V. S. Kamble S. L. Chaplot R. Mukhopadhyay 《Pramana》2008,71(5):1165-1169
We report here the quasielastic neutron scattering (QENS) studies on the dynamics of propylene inside Na-Y zeolite using triple
axis spectrometer (TAS) at Dhruva reactor, Trombay. Molecular dynamics (MD) simulations performed on the system had shown
that the rotational motion involves energy larger than that involved in the translational motion. Therefore, rotational motion
was not observed in our earlier QENS studies on propylene adsorbed Na-Y zeolite using a higher resolution spectrometer at
Dhruva. Analysis of the TAS spectra revealed that the quasielastic broadening observed in propylene-loaded zeolite spectra
is due to the rotational motion of the propylene molecules. This is consistent with our simulation result. Further, the rotational
motion is found to be isotropic. The rotational diffusion coefficient has been obtained.
相似文献
46.
Combinatorial Crystal Synthesis: Structural Landscape of Phloroglucinol:1,2‐bis(4‐pyridyl)ethylene and Phloroglucinol:Phenazine 下载免费PDF全文
Ritesh Dubey Prof. Gautam R. Desiraju 《Angewandte Chemie (International ed. in English)》2014,53(48):13178-13182
A large number of crystal forms, polymorphs and pseudopolymorphs, have been isolated in the phloroglucinol‐dipyridylethylene (PGL:DPE) and phloroglucinol‐phenazine (PGL:PHE) systems. An understanding of the intermolecular interactions and synthon preferences in these binary systems enables one to design a ternary molecular solid that consists of PGL, PHE, and DPE, and also others where DPE is replaced by other heterocycles. Clean isolation of these ternary cocrystals demonstrates synthon amplification during crystallization. These results point to the lesser likelihood of polymorphism in multicomponent crystals compared to single‐component crystals. The appearance of several crystal forms during crystallization of a multicomponent system can be viewed as combinatorial crystal synthesis with synthon selection from a solution library. The resulting polymorphs and pseudopolymorphs that are obtained constitute a crystal structure landscape. 相似文献
47.
In this paper we derive a probabilistic representation of the deterministic three‐dimensional Navier‐Stokes equations based on stochastic Lagrangian paths. The particle trajectories obey SDEs driven by a uniform Wiener process; the inviscid Weber formula for the Euler equations of ideal fluids is used to recover the velocity field. This method admits a self‐contained proof of local existence for the nonlinear stochastic system and can be extended to formulate stochastic representations of related hydrodynamic‐type equations, including viscous Burgers equations and Lagrangian‐averaged Navier‐Stokes alpha models. © 2007 Wiley Periodicals, Inc. 相似文献
48.
Coefficients of characteristic polynomials (CP) of linear polyacenes (LP) have been shown to be obtainable from Pascal’s triangle
by using a graph factorisation and squaring technique. Strong subspectrality existing among the members of the linear polyacene
series has been shown from the derivation of the CP’s. Thus it has been shown that the entire eigenspectrum of ann-ring LP is included in that of (2n + 1)-ring LP. Correspondence between the eigenspectra of linear chains and LP’s is brought
out by a recently developed vertex-alternation and squaring algorithm. 相似文献
49.
50.
Gautam Borooah 《Journal of Pure and Applied Algebra》2008,212(1):281-296
We will completely characterize the commutative local rings for which Mn(R) is strongly clean, in terms of factorization in R[t]. We also obtain similar elementwise results which show additionally that for any monic polynomial f∈R[t], the strong cleanness of the companion matrix of f is equivalent to the strong cleanness of all matrices with characteristic polynomial f. 相似文献