全文获取类型
收费全文 | 584篇 |
免费 | 13篇 |
国内免费 | 1篇 |
专业分类
化学 | 388篇 |
晶体学 | 7篇 |
力学 | 7篇 |
数学 | 48篇 |
物理学 | 148篇 |
出版年
2022年 | 6篇 |
2020年 | 11篇 |
2019年 | 15篇 |
2018年 | 5篇 |
2017年 | 5篇 |
2016年 | 9篇 |
2015年 | 7篇 |
2014年 | 8篇 |
2013年 | 23篇 |
2012年 | 23篇 |
2011年 | 31篇 |
2010年 | 17篇 |
2009年 | 12篇 |
2008年 | 23篇 |
2007年 | 17篇 |
2006年 | 19篇 |
2005年 | 14篇 |
2004年 | 21篇 |
2003年 | 19篇 |
2002年 | 19篇 |
2001年 | 20篇 |
2000年 | 9篇 |
1999年 | 12篇 |
1998年 | 6篇 |
1997年 | 6篇 |
1996年 | 11篇 |
1995年 | 9篇 |
1994年 | 6篇 |
1992年 | 7篇 |
1990年 | 8篇 |
1989年 | 6篇 |
1988年 | 9篇 |
1987年 | 5篇 |
1986年 | 9篇 |
1985年 | 8篇 |
1984年 | 15篇 |
1983年 | 6篇 |
1982年 | 11篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1976年 | 9篇 |
1975年 | 6篇 |
1973年 | 5篇 |
1969年 | 6篇 |
1968年 | 5篇 |
1967年 | 6篇 |
1933年 | 4篇 |
1931年 | 5篇 |
排序方式: 共有598条查询结果,搜索用时 31 毫秒
11.
R. Hempelmann C. J. Carlile D. Beyer Ch. Kaps 《Zeitschrift für Physik B Condensed Matter》1994,95(1):49-53
Using pulsed neutrons of 19.8 Å wavelength a quasielastic line broadening as low as 0.03 eV (FWHM) has been observed due to Na+ diffusion in the glass Na2O·2SiO2. From the linewidths a Na+ self-diffusion coefficient of 3.1·10–8 cm2/s at 420°C was obtained in excellent agreement with the diffusion coefficient determined for the same sample batch using22Na radioactive tracers. The experimental Q dependence of the quasielasic linewidths gives a hint for deviations from a purely random walk in an ionic glass. 相似文献
12.
13.
14.
Summary The international motions of a single cyclohexane molecule are studied by molecular dynamics calculations. Classical trajectories are calculated by integrating Newton's equation of motion. The potential functions used are essentially the same as in Allinger's MM2 program which is widely applied for calculations on conformational energies of organic molecules.Geometries and relative energies are reported for all stable low energy conformers and some transition states of cyclohexane. Vibrational frequencies of classical oscillations of individual bonds — computed for ethane as reference system — are close to the experimental values.Two trajectories of the molecular dynamics of cyclohexane were simulated. In the first we were able to follow the process of ring inversion: chair twisted forms inverted chair. The reaction path is analysed in detail and compared with static approaches. The second trajectory shows the correlated reorientation of the possible twisted forms alone. This process is known as pseudorotation.Dedicated to Prof. Dr. Karl Schlögl 相似文献
15.
16.
Structure of N-Benzoylthiobenzamide N-Benzoylthiobenzamide forms two polymorphic modifications of which the crystal and molecular structures have been determined by X-ray structure analysis. In both modifications the molecules exist as NH tautomeres, but there are differences with regard to their rotameric configurations. In the monoclinic modification both symmetry independent molecules have a Z,Z′ configuration. The triclinic modification also contains two symmetry independent molecules, but now a Z,Z′ and an E,Z′ configuration exist. All four molecules deviate appreciably from planarity. The results of both structure determinations are compared with each other and with the structure of monothiodibenzoylmethane. 相似文献
17.
The S 2p, N 1s and C 1s electron binding energies of some substituted thiourea derivatives, isothiouronium salts, thiazolthiones, 1,3,5-thiadiazin-2-thiones and 1,3,5-thiadiazinium salts have been measured using the X-ray photoelectron spectroscopy (ESCA). From binding energy shifts information concerning the charge distribution on the atoms in the molecules was obtained. The positive charge of the isothiouronium salts was found to concentrate on carbon and nitrogen atoms. The charge of the 1,3,5-thiadiazinium cations was found to be delocalized demonstrating the pseudoaromatic character of the electronic system. 相似文献
18.
Zusammenfassung Die Synthese der Titelverbindungen3 (R
1=R
2=C2H5;n-C4H9) durch Reaktionen von N-(N,N-Diethylthiocarbamoyl)-benzimidoylchlorid (2) mit Natriumdialkyldithiocarbamaten (1) in Aceton wird beschrieben. Die niedrigen Ausbeuten (bis 25% d.Th.) sind durch Nebenreaktionen bedingt. Die Strukturen der Verbindungen werden durch IR-,1H-NMR-,13C-NMR-und Massenspektren bestätigt. Nebenreaktionen werden13C-NMR-spektroskopisch verfolgt und die Ergebnisse diskutiert.
S-(N-(thiocarbamoyl)benzimido)dithiocarbamic esters
Summary The synthesis of the title compounds3 (R 1=R 2=C2H5;n-C4H9) by reactions of N-(N,N-diethylthiocarbamoyl)benzimidechloride (2) with sodiumdialkyldithiocarbamates (1) in acetone is described. The low yields (<25%) are caused by the occurrence of side reactions. The structures of the compounds were confirmed by IR,1H and13C NMR, and mass spectroscopy. Side reactions were detected by13C NMR spectroscopy; the results are discussed.相似文献
19.
Liu H Yang S Balteanu I Balaj OP Fox-Beyer BS Beyer MK Bondybey VE 《Rapid communications in mass spectrometry : RCM》2004,18(13):1479-1481
A route to efficient generation of C6H4+*, potentially the benzyne radical cation, is presented. Laser vaporization of Mg+* and supersonic expansion in helium doped with o-, m-, or p-C6H4F2 yields, among other ions, o-, m-, p-C6H4F2Mg+* complexes, but no C6H4+*. Collision-induced dissociation experiments show that the o-C6H4F2Mg+* complex can be converted into C6H4+* in a mildly energetic collision, with a center-of-mass energy around 1-2 eV. These conditions can also be reached in the ion source when argon is used as a carrier gas. In this way, mass spectra containing the desired m/z 76 peak, i.e. C6H4+*, are obtained. 相似文献
20.
A single-crystal and solution ESR study of bis(N,N-diethyl-N′-benzoylthioureato)Cu(II) is reported. The bonding situation in this complex, which contains a S2O2 coordination sphere with S atoms in cis-position, is considered. 相似文献