Pedicelloside,nouveau phtalide isole de gentiana pedicellata wall.

The title compound, isolated from $\text{Gentiana pedicellata}$ leaves, is a new alkyl-3-phthalide characterized by an acylated side chain. It has been identified by spectral analysis as [3-(1-β-D-glucosyloxy)-2-hydroxy]benzoyl 3-(3-phthalidyl)-propyl ester.     

Polyazaphosphorus macrocycles: Synthesis,reactivity, complexation

A general synthesis of various polyazaphosphorus macrocycles involving [1 + 1], [2 + 2], or [3 + 3] cyclocondensations is reviewed, as well as the attempted synthesis of cryptands. Selective reduction (imino functions) methylation (PS groups), silylation (PO groups) are reported. Preparations of some macrocycle complexes are described.     

Method of Calculation of a Shape Parameter for Ovaloid Molecules

The nonsphericity parameter γrelated to the Isihara shape factor for ovaloid polymers f by the relation f = (γ/4) + (1/4) is calculated through an expansion of the radius of the molecule in spherical harmonics. The limitations of the method when applied to polymers with high f are discussed.     

Validity of the Geometric Model of Ovaloid Polymers Based on Simpler Molecules

The shape parameter obtained from the geometric model of Ishihara and Hayashida for ovaloid polymers, together with the scaled-particle theory, are applied to a mixture of methane and ethylene. The results are in good agreement with the experimental values, indicating the validity of the model and suggesting application to other polymer properties.     

Impedance-effects in capacity estimation

Formulas for the capacity of an unsignalized intersection for traffic streams which are subordinated to two or more streams of higher priority are developed. The case of only two conflicting streams analysed by Tanner (1962) is extended. The process at the intersection is modelled as a priority queuing system with Poisson input and service times depending on the work load.     

Surjectivité de l'application restriction à un compact dans des classes de fonctions ultradifférentiables

Résumé Etant donnée {M _p } _p0 une suite de réels strictement positifs, on considère la classe de CarlemanC{p!M _p } (resp. BeurlingB{p!M _p }) des fonctionsf indéfiniment dérivables sur ⁿ . SoitE un sous ensemble compact de ⁿ ; on peut associer à la classeC{p!M _p } (resp.B{p!M _p }) la classe des jets de Whitney surE,C _E {p!M _p }, (resp.B _E {p!M _p }) et on a une application de restriction naturelle deC{p!M _p } dansC _E {p!M _p } (resp.B{p!M _p } dansB _E {p!M _p }).Dans ce travail, on donne des conditions sur deux suites {M _p } _p0 et {M _p } _p0 pour que l'on ait les inclusions suivantes ou Ceci est, en quelque sorte, une généralisation du problème de prolongement de Whitney.

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