首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   9334篇
  免费   92篇
  国内免费   28篇
化学   7047篇
晶体学   177篇
力学   114篇
数学   957篇
物理学   1159篇
  2024年   37篇
  2023年   110篇
  2022年   433篇
  2021年   495篇
  2020年   313篇
  2019年   332篇
  2018年   240篇
  2017年   201篇
  2016年   364篇
  2015年   256篇
  2014年   359篇
  2013年   528篇
  2012年   565篇
  2011年   640篇
  2010年   433篇
  2009年   352篇
  2008年   511篇
  2007年   480篇
  2006年   448篇
  2005年   345篇
  2004年   309篇
  2003年   228篇
  2002年   207篇
  2001年   120篇
  2000年   89篇
  1999年   62篇
  1998年   74篇
  1997年   58篇
  1996年   75篇
  1995年   50篇
  1994年   52篇
  1993年   45篇
  1992年   37篇
  1991年   39篇
  1990年   34篇
  1989年   40篇
  1988年   28篇
  1987年   30篇
  1986年   34篇
  1985年   50篇
  1984年   28篇
  1983年   23篇
  1982年   32篇
  1981年   23篇
  1980年   24篇
  1979年   21篇
  1977年   14篇
  1976年   17篇
  1974年   13篇
  1968年   12篇
排序方式: 共有9454条查询结果,搜索用时 0 毫秒
11.
We study how massive ghost-free gravity \(f(R)\) -modified theories, MGFTs, can be encoded into generic off-diagonal Einstein spaces. Using “auxiliary” connections completely defined by the metric fields and adapted to nonholonomic frames with associated nonlinear connection structure, we decouple and integrate in certain general forms the field equations in MGFT. Imposing additional nonholonomic constraints, we can generate Levi-Civita, LC, configurations and mimic MGFT effects via off-diagonal interactions of effective Einstein and/or Einstein–Cartan gravity with nonholonomically induced torsion. We show that imposing nonholonomic constraints it is possible reproduce very specific models of massive \(f(R)\) gravity studied in Cai et al. (arXiv:1307.7150, 2013), Klusoňet al. (Phys Lett B 726:918, 2013), Nojiri and Odintov (Phys Lett B 716:377, 2012) and Nojiri et al. (JCAP 1305:020, 2013). The cosmological evolution of ghost-free off-diagonal Einstein spaces is investigated. Certain compatibility of MGFT cosmology to small off-diagonal deformations of \(\Lambda \) CDM models is established.  相似文献   
12.
Here, we describe the reliable method for the detection and quantitation of a pheomelanin component in melanin pigments. Synthetic melanins with various contents of pheomelanin-type structural units were thermally degraded, and the multiple reaction monitoring mode was applied to detect the pheomelanin markers in the pyrolysates by GC/MS/MS. The method allowed the specific detection and quantitation of a pheomelanin component in melanin with the incorporation of pheomelanin-type units as low as 0.05%. Considering highly universal character of the pheomelanin markers, the method could be applied for structural studies of natural melanin pigments being mixtures of eumelanin and pheomelanin.  相似文献   
13.
5-Dimethylamino-1-sulfonyl naphthalene (DNS, commonly referred as dansyl) is a functionality, bearing well-established properties in directing the fragmentation, by mass spectrometry (MS), of the corresponding ionized sulfonylated derivatives. This property is shared also by its labeled analogs. The use of d(0)/d(6) DNS derivatives is now exploited in the application of the well-established isotope dilution mass spectrometric approach in the assay of complex mixtures. A new method for the quantitation of amino acids (AAs) in beverages is therefore presented, which relies on liquid chromatographic separation of their N-dansylated derivatives followed by comparative electrospray tandem MS/MS of the d(0)/d(6) isobaric mixtures. Labeled and unlabeled DNS derivatives of the selected AAs are readily available by microwave-assisted synthetic protocols. The novelty of the method is represented by the use of heavy and light DNS-isotopologue providing suitable reporter groups. Multiple-reaction monitoring has been applied in the assay of AAs in wine, pineapple juice and bergamot juice with good-to-excellent results as proved by both relative standard deviation, lower than 15%, and by the accuracy values in the range 90-110%.  相似文献   
14.
The effect of the vibrational strain amplitude on the Young’s modulus and ultrasound absorption (internal friction) of a SiC/Si biomorphic composite prepared by pyrolysis of sapele wood followed by infiltration of silicon were investigated. The studies were conducted in air and in vacuum by the acoustic resonance method with the use of a composite vibrator in longitudinal vibrations at frequencies of about 100 kHz. Measurements performed on sapele wood-based bio-SiC/Si samples revealed a substantial effect of adsorption-desorption of molecules contained in air on the effective elasticity modulus and elastic vibration decrement. Microplastic characteristics of the SiC/Si composites prepared from wood of different tree species were compared.  相似文献   
15.
16.
The basis set superposition error is investigated in terms of the first-order symmetry adapted perturbation theory (SAPT). The analysis of the first-order SAPT contribution to the interaction energy reveals the origin of the basis set truncation effects at both the one-electron and many-electron levels of approximation. This helps to formulate the necessary conditions which ensure that the calculated interaction energy is free of the basis set superposition contributions. At the level of the one-electron approximation used for both the interacting system and its subsystems a part of the basis set truncation errors can be eliminated by using what is called the dimer-centred basis set. In order to remove all contributions which arise from the symmetrization of the product of wave functions of the subsystems one needs to redefine their reference states. This means that for the interacting system represented by a single HF determinant, the subsystems must be considered at the level of full CI in the orbital space spanned by all occupied orbitals used to describe the dimer. Then, the interaction energy becomes completely free of the basis set superposition contributions. These general considerations are exemplified by calculations of the first-order SAPT interaction energy in helium and H2 dimers at different levels of approximation for monomers. Also the convergence of the calculated energies to the complete basis set limit is investigated.  相似文献   
17.
Results on the coherent dissociation of relativistic 9C nuclei in a nuclear track emulsion are described. These results include the charge topology and kinematical features of final states. Events of 9C → 33He coherent dissociation are identified.  相似文献   
18.
Zusammenfassung Tabakmosaikvirus hoher spezifischer Aktivität, das am Phosphor und/oder Kohlenstoff markiert war, wurde biosynthetisch hergestellt. Damit wurde jeweils ein Blatt einer Pflanze von Nicotiana tabacum infiziert und der etwaige Transport von intaktem Virus durch das Leitungssystem der Pflanzen dadurch weitgehend unterbunden, daß die Leitgefäße des behandelten Blattes durchtrennt wurden.Das aus den unbehandelten Blättern der Pflanze nach 17 1/2, 48 und 72 Stdn. isolierte Virus wies im Vergleich zum eingesetzten TMV einen viel geringeren Anteil an Gesamtradiokohlenstoff im Protein auf. Dies deutet darauf hin, daß das Virus der unbehandelten Blätter höchstens zu einem sehr geringen Teil aus intakt transportiertem TMV bestehen könnte.Die nicht im TMV enthaltenen Polynukleotide der unbehandelten Blätter enthalten 7 Stdn. nach der Infektion verhältnismäßig viel32P, doch tritt derselbe innerhalb 70 Stdn. zum allergrößten Teil in niedermolekulare Verbindungen über.Die in Puffer unlöslichen Polynukleotide der unbehandelten Blätter (Blattnukleinsäure) weisen ein mit der Zeit abnehmendes Verhältnis von32P/14C auf. Auch innerhalb der Nukleinsäure (NS) des TMV dieser Blätter nimmt dieses Verhältnis zunächst ab, steigt aber später wieder an.Die angeführten Ergebnisse stehen mit der Vorstellung im Einklang, daß das Virus NS abspaltet und sowohl die systemische Infektion der Pflanze wie auch die Virusvermehrung mindestens zum Teil durch diese freie NS bewirkt wird. Die aus dem Virus stammende freie NS unterliegt zum großen Teil lebhaftem Abbau, wobei ihre Komponenten wahrscheinlich dem Aufbau normaler Blattbestandteile dienen.Mit 3 Abbildungen  相似文献   
19.
In unbounded domains we state some a priori bounds for solutions of the Dirichlet problem for linear second order elliptic differential equations in nondivergence form with discontinuous coefficients in weighted spaces. The weight function is related to the distance function from a fixed subset S of ∂Ω.  相似文献   
20.
The use of a bi-directional, as opposed to a one-way, transportation system, can increase the operational efficiency of automated guided vehicles in both manufacturing and warehousing environments. However, the full potential will only be realized if the routeing algorithms pay particular attention to the problem of collision avoidance. This paper is concerned with the development of such an algorithm. The method is based on the use of delays and deviations to avoid collisions that could arise when using the shortest routes for each vehicle, and is applicable to any transportation system which can be represented as a network with known travel times.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号