Silver Nanowires and Silanes in Hybrid Functionalization of Aramid Fabrics

New functionalization methods of meta- and para-aramid fabrics with silver nanowires (AgNWs) and two silanes (3-aminopropyltriethoxysilane (APTES)) and diethoxydimethylsilane (DEDMS) were developed: a one-step method (mixture) with AgNWs dispersed in the silane mixture and a two-step method (layer-by-layer) in which the silanes mixture was applied to the previously deposited AgNWs layer. The fabrics were pre-treated in a low-pressure air radio frequency (RF) plasma and subsequently coated with polydopamine. The modified fabrics acquired hydrophobic properties (contact angle Θ_W of 112–125°). The surface free energy for both modified fabrics was approximately 29 mJ/m², while for reference, meta- and para-aramid fabrics have a free energy of 53 mJ/m² and 40 mJ/m², respectively. The electrical surface resistance (R_s) was on the order of 10² Ω and 10⁴ Ω for the two-step and one-step method, respectively. The electrical volume resistance (R_v) for both modified fabrics was on the order of 10² Ω. After UV irradiation, the Rs did not change for the two-step method, and for the one-step method, it increased to the order of 10¹⁰ Ω. The specific strength values were higher by 71% and 63% for the meta-aramid fabric and by 102% and 110% for the para-aramid fabric for the two-step and one-step method, respectively, compared to the unmodified fabrics after UV radiation.     

Exact solutions for network rewiring models

Evolving networks with a constant number of edges may be modelled using a rewiring process. These models are used to describe many real-world processes including the evolution of cultural artifacts such as family names, the evolution of gene variations, and the popularity of strategies in simple econophysics models such as the minority game. The model is closely related to Urn models used for glasses, quantum gravity and wealth distributions. The full mean field equation for the degree distribution is found and its exact solution and generating solution are given.     

Stop coannihilation in the CMSSM and SubGUT models

Stop coannihilation may bring the relic density of heavy supersymmetric dark matter particles into the range allowed by cosmology. The efficiency of this process is enhanced by stop-antistop annihilations into the longitudinal (Goldstone) modes of the W and Z bosons, as well as by Sommerfeld enhancement of stop annihilations and the effects of bound states. Since the couplings of the stops to the Goldstone modes are proportional to the trilinear soft supersymmetry-breaking A-terms, these annihilations are enhanced when the A-terms are large. However, the Higgs mass may be reduced below the measured value if the A-terms are too large. Unfortunately, the interpretation of this constraint on the stop coannihilation strip is clouded by differences between the available Higgs mass calculators. For our study, we use as our default calculator FeynHiggs 2.13.0, the most recent publicly available version of this code. Exploring the CMSSM parameter space, we find that along the stop coannihilation strip the masses of the stops are severely split by the large A-terms. This suppresses the Higgs mass drastically for \(\mu \) and \(A_0 > 0\), whilst the extent of the stop coannihilation strip is limited for \(A_0 < 0\) and either sign of \(\mu \). However, in sub-GUT models, reduced renormalization-group running mitigates the effect of the large A-terms, allowing larger LSP masses to be consistent with the Higgs mass calculation. We give examples where the dark matter particle mass may reach \(\gtrsim 8\) TeV.     

Dilations of dynamical semi-groups

We prove the existence of isometric and unitary dilations of a class of semi-groups of completely positive maps on an algebra of operators on a Hilbert space. The result has relevance to the problem of embedding an open quantum mechanical system in a closed one.     

Addendum to: Comparison between different types of abstract integrals in riesz spaces

In [3] we did not give explicitly the definition of measurability for realvalued functions, with respect to finitely additive measures with values in a Dedekind complete Riesz space. We note that, in [3], all involved functions are intended to be measurable. We now report the definition of measurability, which we gave in [2] (Definition 3.2).     

Vowel normalization for accent: an investigation of best exemplar locations in northern and southern British English sentences

Two experiments investigated whether listeners change their vowel categorization decisions to adjust to different accents of British English. Listeners from different regions of England gave goodness ratings on synthesized vowels embedded in natural carrier sentences that were spoken with either a northern or southern English accent. A computer minimization algorithm adjusted F1, F2, F3, and duration on successive trials according to listeners' goodness ratings, until the best exemplar of each vowel was found. The results demonstrated that most listeners adjusted their vowel categorization decisions based on the accent of the carrier sentence. The patterns of perceptual normalization were affected by individual differences in language background (e.g., whether the individuals grew up in the north or south of England), and were linked to the changes in production that speakers typically make due to sociolinguistic factors when living in multidialectal environments.     

Investigating Electronic Communications in meso–meso Ethene-Bridged Unsymmetrical Diporphyrins

At the focal point of this work is the photophysical characterization of three meso–meso ethene-bridged diporphyrins featuring a diverse metallation pattern. Detailed investigations by means of cyclic voltammetry, absorption, fluorescence, and femto-/nanosecond transient absorption spectroscopy revealed the impact of open-shell nickel(II) on the electronic communication in ethene-bridged heterobimetallic diporphyrins.     

A Note on Fick’s Law with Phase Transitions

Journal of Statistical Physics - We characterize the non equilibrium stationary states in two classes of systems where phase transitions are present. We prove that the interface in the limit is a...