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61.
一个考虑形变能影响的脆断强度条件 总被引:9,自引:0,他引:9
针对常用强度理论解决复杂应力状态生断裂存在的问题,分析了由形状改变比能引起的塑性变形对脆断的影响,给出了一个新的脆断强度条件,并通过铸铁破坏试验作了验证。 相似文献
62.
Xiangrong Zhu Yang Shan Gaoyang Li Anmin Huang Zhuoyong Zhang 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,74(2):344-348
A method for the quantification of density of Chinese Fir samples based on visible/near-infrared (vis–NIR) spectrometry and least squares-support vector machine (LS-SVM) was proposed. Sample set partitioning based on joint x–y distances (SPXY) algorithm was used for dividing calibration and prediction samples, it is of value for prediction of property involving complex matrices. A stepwise procedure is employed to select samples according to their differences in both x (instrumental responses) and y (predicted parameter) spaces. For comparison, the models were also constructed by Kennard–Stone method, as well as by using the duplex and random sampling methods for subset partitioning. The results revealed that the SPXY algorithm may be an advantageous alternative to the other three strategies. To validate the reliability of LS-SVM, comparisons were made among other modeling methods such as support vector machine (SVM) and partial least squares (PLS) regression. Satisfactory models were built using LS-SVM, with lower prediction errors and superior performance in relation to SVM and PLS. These results showed possibility of building robust models to quantify the density of Chinese Fir using near-infrared spectroscopy and LS-SVM combined SPXY algorithm as a nonlinear multivariate calibration procedure. 相似文献
63.
Recent theoretical studies have suggested that the stabilizing factors for large nitrogen cages tend to favor more five-membered rings, more three-membered rings, and cylindrical structures with large numbers of layers. One of the major issues in this study of the all-nitrogen molecule is the determination of what brings about the stabilizing factors. Herein, the cylinder-shaped molecule of N72 (D3d) has been studied in detail. The geometry and energies are examined at B3LYP/cc-pVDZ, and single-point energy calculations at MP2/cc-pVDZ are carried out for the purposes of determining relative thermodynamic stability. Natural bond order (NBO) analysis and atoms in molecules (AIM) analysis are applied to investigate the bonding properties of the cage molecule. The major result of this study is the identification of intramolecular interactions, whether it is at B3LYP/cc-pVDZ or at MP2/cc-pVDZ, as the dominant stabilizing factor for the large all-nitrogen cage. The length of the cylinder-shaped molecule is about 2.2 nm. N72 (D3d) might be one novel nanomaterial which is environment friendly, and as a beeline nanotube or a beeline "nano-bar", it is expected to impact a wide range of applications. 相似文献
64.
The continuous development of solid-state electrolytes(SSEs) has stimulated immense progress in the development of all-solid-state batteries(ASSBs). Particularly, garnet-typed SSEs in formula of Li7La3Zr2O12(LLZO) are under intensive investigation to exploit their advantage in high lithium ions conductivity(>1 mS/cm), wide electrochemical window(>5 V), and good chemical electrochemical stability for lithium, which are critical factors to ensure a stable, and high performance ASSBs. This review will focus on the challenges related to LLZOs-based electrolyte, and update the recent developments in structural design of LLZOs, which are discussed in three major sections:(i) crystal structure and the lithium-ion transport mechanism of LLZO; (ii) single-site and multi-site doping of Li sites, La sites and Zr sites to enhance Li ions conductivity(LIC) and stability of LLZO; (iii) interface strategies between electrodes and LLZO to decrease interface area-specific resistance(ASR). 相似文献
65.
66.
Bromomethane-water 1:2 complexes have been theoretically studied to reveal the role of hydrogen bond and halogen bond in the formation of different aggregations. Four stable structures exist on the potential energy surface of the CH3Br(H2O)2 complex. The bromine atom acts mainly as proton acceptor in the four studied structures. It is also capable of participating in the formation of the halogen bond. The properties and characteristics of the hydrogen bond and the halogen bond are investigated employing several different quantum chemical analysis methods. Cooperative effects for the pure hydrogen bonds or the mixed hydrogen bonds with halogen bonds and the possibility of describing cooperative effects in terms of the topological analysis of the electronic density or the charge-transfer stabilization energy are discussed in detail. An atoms-in-molecules study of the hydrogen bond or the halogen bond in the bromomethane-water 1:2 complexes suggests that the electronic density topology of the hydrogen bond or the halogen bond is insensitive to the cooperative effect. The charge-transfer stabilization energy is proportional to the cooperative effect, which indicates the donor-acceptor electron density transfer to be mainly responsible for the trimer nonadditive effect. 相似文献
67.
In situ
developments of platelike spodumene–diopside grains were obtained by
controlled devitrification of the complex system Li2O–CaO–MgO–Al2O3–SiO2 glass. The crystallization mechanisms
of spodumene–diopside glass were measured by isothermal and non-isothermal
processes using classical and differential thermal analysis techniques. The
Avrami constant n was 2.0–2.1, indicating
two-dimensional crystal growth and platelike grains. The crystalline phases
precipitated first were high-quartzs.s., then transformed
to β-spodumene and diopside. The Flexural strength, fracture toughness
and thermal shock resistance (in 20°C water) increased from 145 MPa, 1.3
MPa m1/2, 800°C (pure spodumene) to 197 MPa,
2.9 MPa m1/2 and 920°C (spodumene–diopside)
with low thermal expansion coefficient (from 3∼9·10–7
to 11.8·10–7 K–1).
This mean in situ developments of platelike spodumene–diopside grains
reinforced the low thermal expansion coefficient glass-ceramics. 相似文献
68.
69.
甲基丙烯酸镁增强氢化丁腈橡胶的结构与形态和性能 总被引:5,自引:0,他引:5
用不同份量的甲基丙烯酸镁(MgMA)作增强剂,过氧化二异丙苯(DCP)作硫化剂,通过混炼和硫化过程的原位聚合制备了氢化丁腈橡胶/聚甲基丙烯酸镁(HNBR/PMgMA)纳米复合材料,用XRD、FTIR1、3C-NMR、SEM、TEM、DMA和交联密度分析等方法研究了其结构、形态和性能,并阐述了MgMA改性HNBR的相关机理.结果表明,MgMA在混炼过程中粒径明显变小,部分达到纳米级.硫化过程中发生原位自由基聚合,并部分接枝到HNBR分子链上,HNBR硫化胶和PMgMA有可能形成接枝互穿聚合物网络(接枝IPN).随着MgMA用量的增加,纳米复合材料硫化胶的定伸应力、拉伸强度、扯断伸长率、撕裂强度和热氧老化性能逐渐提高.当MgMA含量为30份时,体系的拉伸强度和扯断伸长率分别为38.5MPa和545%,并具有优异的热空气老化性能.MgMA能明显增加HNBR复合材料的储能模量,并降低其损耗因子.随着MgMA用量的增加,纳米复合材料硫化胶的总交联密度(Ve)和离子键交联密度(Ve2)增加,而共价键交联密度(Ve1)下降,表明离子键对HNBR/PMgMA纳米复合材料的力学性能起重要作用. 相似文献
70.
基于虚拟仪器和可调谐激光技术的光纤光栅传感系统 总被引:4,自引:3,他引:1
提出了一种新颖的基于虚拟仪器(VI)和可调谐激光技术的光纤光栅(FBG)传感系统,利用可调谐激光对由光纤光栅组成的传感器阵列进行波长扫描,实现了多根光栅的复用准静态解调,并结合抖动技术和反馈环结构,使得探测信号在每一根传感光栅中心波长处过零,以提高系统在测定波长偏移时的分辨力。当反馈环工作在闭环状态下时,该系统还可对单根光栅实现动态跟踪锁定,实现单根光栅的动态解调。该传感系统的数据采集采用虚拟仪器技术,通过多通道同时输入输出实现了在线实时解调。实验采用了4根光栅组成传感阵列,获得了静态多根光栅小于1με和单根光栅动态频率10 Hz时3.3 n/εHz的解调分辨力,动态应变范围在850με。 相似文献