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991.
992.
We present 2D versions of the popular triple resonance HN(CO) CACB, HN(COCA)CACB, HN(CO)CAHA, and HN(COCA) CAHA experiments, commonly used for sequential resonance assignments of proteins. These experiments provide information about correlations between amino proton and nitrogen chemical shifts and the alpha- and beta-carbon and alpha-proton chemical shifts within and between amino acid residues. Using these 2D spectra, sequential resonance assignments of H(N), N, C(alpha), C(beta), and H(alpha) nuclei are easily achieved. The resolution of these spectra is identical to the well-resolved 2D (15)N-(1)H HSQC and H(NCO)CA spectra, with slightly reduced sensitivity compared to their 3D and 4D versions. These types of spectra are ideally suited for exploitation in automated assignment procedures and thereby constitute a fast and efficient means for NMR structural determination of small and medium-sized proteins in solution in structural genomics programs. 相似文献
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Squier AH Airs RL Hodgson DA Keely BJ 《Rapid communications in mass spectrometry : RCM》2004,18(23):2934-2938
Atmospheric pressure chemical ionisation reversed-phase high-performance liquid chromatography/multistage mass spectrometry has been used to study the mass spectral fragmentation of the cyanobacterial sheath pigment scytonemin and its reduced counterpart. The two pigments exhibit characteristic fragment ions in their MS2 and MS3 spectra that are of value in confirming the identification of the structures in extracts from natural environments. 相似文献
998.
Angela Pistoia Olivier Rey 《Calculus of Variations and Partial Differential Equations》2003,18(3):243-251
Let
,
, be a bounded domain as defined by Flucher, Garroni and Müller [6], which has a singular point
such that the Robins function achieves its infimum at
. Considering the elliptic problem
in
; u = 0 on
, with p = (N + 2)/(N-2),
, and
a minimizing solution of
,
concentrates at
as
goes to zero.Received: 15 September 2002, Accepted: 5 November 2002, Published online: 16 May 2003Mathematics Subject Classification:
35J65Angela Pistoia: The author is supported by M.U.R.S.T., project Metodi variazionali e topologici nello studio di fenomeni non lineari 相似文献
999.
Sensitivity-enhanced versions of the IPAP, TROSY-anti-TROSY, and E.COSY experiments for measuring one-bond 15N-1HN couplings are presented. Together with the previously developed sensitivity-enhanced E.COSY-type HSQC experiment they comprise a suite of sensitivity-enhanced experiments that allows one to chose the optimal spectrum for accurate measurement of one-bond 15N-1HN residual dipolar couplings in proteins. Since one-bond 15N-1HN residual dipolar couplings play uniquely important roles in structural NMR, these additional methods provide further tools for improving structure determination of proteins and other biological macromolecules. 相似文献
1000.
Angela Kopp 《Annals of Physics》2007,322(6):1466-1476
We propose that quantum phase transitions are generally accompanied by non-analyticities of the von Neumann (entanglement) entropy. In particular, the entropy is non-analytic at the Anderson transition, where it exhibits unusual fractal scaling. We also examine two dissipative quantum systems of considerable interest to the study of decoherence and find that non-analyticities occur if and only if the system undergoes a quantum phase transition. 相似文献