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991.
Angel Licea-Claveríe José Manuel Cornejo-Bravo Rodolfo Salgado-Rodríguez Dolores del Rosario Santos-Rosas Eder Lugo-Medina Marco Antonio Ramos-Ibarra Karl-Friedrich Arndt 《Macromolecular Symposia》2007,254(1):292-299
Summary: Acid methacrylates containing hydrophobic aliphatic and aromatic spacers were used to prepare pH-sensitive ampholytic hydrogels and bidimensional temperature- (T) and pH-sensitive hydrogels. Their swelling behaviour was studied by changing the pH and temperature of buffer solutions. Salicylamide, salicylic acid and green fluorescent protein (GFP) as model drugs were loaded into the gels and their release kinetics studied under simulated gastric and intestinal conditions. T- and pH-sensitive hydrogels containing aliphatic spacers show sustained release of analgesics depending on pH (e.g. 7.4); while longer aliphatic spacers resulted in drug release depending on pH and temperature (T < transition T). GFP was released from temperature- and pH-sensitive ampholytic hydrogels after different lag times depending on hydrogel composition. 相似文献
992.
Angel E. Lozano Javier de Abajo Jos G. De la Campa 《Macromolecular theory and simulations》1993,2(5):815-827
A semiempirical quantum-mechanical study of structural and electronic parameters of aromatic diamines was performed using the method AM1. The diamines have been considered as condensation monomers, and the reactivities of both amino groups against acyl chlorides have been computed. The study shows that the amidation reaction is controlled mainly by the global charge on the amino group and, in a much smaller extent, by the frontier orbitals. This behaviour is consistent with the large energy gap between the HOMO 1 1 HOMO: highest occupied molecular orbital. of the diamine and the LUMO 2 2 LUMO: lowest unoccupied molecular orbital. of the acyl chloride. It has been found also that the electronic nature of the substituents, affecting the charge of the amino groups, greatly affects the carbons directly joined to these groups. This permits to correlate the reactivities with the calculated charges on these carbons: 相似文献
993.
Flavia Pennini Angelo Plastino Gustavo Luis Ferri Angel Ricardo Plastino 《Entropy (Basel, Switzerland)》2022,24(6)
We discuss novel many-fermions thermodynamics’ features. They refer to the energy cost associated to order-disorder changes. Our thermal quantum statistical scenario is controlled by suitable fermion-fermion interactions. We deal with two well-known quantum interactions that operate within an exactly solvable model. This model is able to adequately describe some aspects of fermion-dynamics, particularly level-crossings. We describe things via employment of Gibbs’ canonical ensemble strictures. We show that judicious manipulation of the energy cost associated to statistical order (disorder) variations generates useful information-quantifiers. The underlying idea is that changes in the degree of order are intimately linked to level-crossings energetic costs. 相似文献
994.
995.
Jorge F. Espeso Enrique Ferrero Jos G. De La Campa Angel E. Lozano Javier De Abajo 《Journal of polymer science. Part A, Polymer chemistry》2001,39(4):475-485
Aromatic polyamides based on a novel bis(ether‐carboxylic acid) were synthesized by the direct phosphorylation condensation method. 1,4‐Bis(4‐carboxyphenoxy)‐2,5‐di‐tert‐butylbenzene was combined with various diamines containing flexible linkages and side substituents to render a set of eight novel aromatic polyamides. The polymers were produced with high yields and moderate to high inherent viscosities (0.49–1.32 dL/g) that corresponded to weight‐average and number‐average molecular weights (by gel permeation chromatography) of 31,000–80,000 and 19,000–50,000, respectively. Except for a single example, the polyamides were essentially amorphous and soluble in a variety of common solvents such as cyclohexanone, dioxane, and tetrahydrofuran. They showed glass‐transition temperatures of 250–295 °C (by differential scanning calorimetry) and 10% weight loss temperatures above 460 °C, as revealed by thermogravimetric analysis in nitrogen. Polymer films, obtained by casting from N,N‐dimethylacetamide solutions, exhibited good mechanical properties, with tensile strengths of 83–111 MPa and tensile moduli of 2.0–2.2 GPa. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 475–485, 2001 相似文献
996.
Angel E. Lozano Jos G. De La Campa Javier De Abajo 《Journal of polymer science. Part A, Polymer chemistry》1999,37(24):4646-4655
In this article a new synthesis of 3,3′-diaminobiphenyl (3,3′-DABP) is described, along with the preparation and characterization of polyamides and polyimides based on it. Reactivity of this monomer was calculated by a molecular simulation study, using ab initio quantum-mechanical methods. Terephthaloyl and isophthaloyl chloride were used for the synthesis of polyamides, while 3,3′,4,4′-biphenylenetetracarboxylic acid dianhydride and 4,4′-(hexafluoroisopropylidene) diphthalic anhydride were used for the synthesis of polyimides. Medium to high molecular weight polymers were attained, with inherent viscosities near or higher than 1.0 dL/g, the solubility of the 3,3′-DABP polymers was much better than that of the homologous polymers from benzidine (4,4′-DABP), the glass-transition temperatures were lower, by about 40°C, and the thermal resistance, as measured by thermogravimetry, was virtually the same. Amorphous films, made from cast polymer solutions, showed excellent mechanical properties, comparable to conventional aromatic polyamides and polyimides. Theoretical calculations demonstrated that the radius of giration, end-to-end distance and density of poly(3,3′-DABP-isophthalamide) were lower than those of poly(4,4′-DABP-isophthalamide), as a consequence of the chain folding induced in the backbone by the m-substitution in 3,3′-DABP. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 4646–4655, 1999 相似文献
997.
David Ayala Angel E. Lozano Javier De Abajo Jos G. De La Campa 《Journal of polymer science. Part A, Polymer chemistry》1999,37(16):3377-3384
Polyimides derived from a new dianhydride with p-nitrophenyl pendant groups have been synthesized and their properties compared with those of a reference series, without side groups. The polymers were obtained by combination of the novel monomer with aromatic diamines, in a two-step procedure that involved the synthesis of poly(amic acid) or poly(amic silyl ester) intermediates and the cyclization of them to polyimides by thermal treatment. The introduction of the polar nitro groups caused significant increase of the Tgs. On the contrary, the thermal stability was reduced because of the breakdown of CAr—NO2 linkages around 400oC. A slight decrease in mechanical properties was observed, due to the bulkiness of the side groups, that also produced an important decrease in the strength of the β relaxation, as determined by dynamic mechanical analysis. The solubility of the current polyimides in organic solvents was as poor as that of the parent unsubstituted polymers. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 3377–3384, 1999 相似文献
998.
David Ayala Angel E. Lozano Javier De Abajo Jos G. De La Campa 《Journal of polymer science. Part A, Polymer chemistry》1999,37(6):805-814
New dianhydrides containing t‐butyl and phenyl pendant groups have been synthesized and used as monomers, together with commercial diamines, to prepare novel polyimides. The influence of the chemical structure of the monomers on their reactivity has been studied by quantum semiempirical methods. The polyimides have been characterized by FTIR and by NMR in the case of soluble polymers. The presence of pendant groups and the method used to imidize polyimide precursors greatly affected polymer properties such as solubility, glass transition temperature, thermal stability, and mechanical properties. As a rule, the novel polyimides showed better solubility in organic solvents than the parent polyimides. Glass transition temperatures in the range 250–270°C and decomposition temperatures over 520°C were observed for the set of current polymers. Tensile strengths up to 135 MPa and mechanical moduli up to 3.0 GPa were measured on films of the current polyimides. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 805–814, 1999 相似文献
999.
1000.
We review thermal–statistical considerations on the odd–even staggering effect (OES) in fermions. There is a well known OES in nuclear binding energies at zero temperature. We discuss here a thermal OES (finite temperatures) that establishes links with the order–disorder disjunction. The present thermal considerations cannot be found in the nuclear literature. 相似文献