Electric and sorption properties of controlled pore glasses

A series of controlled pore glasses (CPG) was made from the same raw glass by means of different chemical and thermal treatments. BET specific area, selectivity of cesium adsorption in relation to sodium, ionosorption capacity under dynamic conditions of these CPG were measured and potentiometric titrations carried out. ₀ vs. pH curves show i.e.p. and c.i.p. values similar to those for silica. KOH treatment leads to increase of BET specific surface but ionosorption capacity is decreased.     

Dynamics of theD-dimensional FRW-cosmological models within the superstring-generated gravity model

We study the dynamics of the generalizedD-dimensional (D = 1+3+d) Friedman-Robertson-Walker (FRW) cosmological models in the framework of an extended gravity theory obtained by adding the Gauss-Bonnet term to the standard Einstein-Hilbert action. In our discussion we extensively use methods of dynamical systems. We consider models filled in with a perfect fluid obeying the equation of statep=(–1) and vacuum but non-flat models. We present a detailed analysis of the ten dimensional model and in particular we study the vacuum case. Several phase portraits show how the evolution of this model depends on the parameter.     

Unusual solid-state conformation of D-glucitol hexa(p-chlorobenzoate)

The carbon atom chain in the molecule ofd-glucitol hexa (p-chlorobenzoate) adopts a planar, zigzag conformation in the solid state, as determined by X-ray crystallography. The preference for such conformation in the crystal can be ascribed to the stacking interactions in which an infinite number of p-chlorobenzoyloxy substituents is involved.     

Thermal Decomposition of Bi(III), Cd(II), Pb(II) and Cu(II) Thiocyanates

Thermal decomposition of Bi(SCN)₃, Cd(SCN)₂, Pb(SCN)₂ and Cu(SCN)₂ has been studied. The thermal analysis curves and the diffraction patterns of the solid intermediate and final products of the pyrolysis are presented. The gaseous products of the decomposition (SO₂ and CO₂) were detected and quantitatively determined. Thermal, X-ray and chemical analyses have been used to establish the nature of the reactions occurring at each stage in the decomposition.This revised version was published online in November 2005 with corrections to the Cover Date.     

Partial transposition and nonextendible maps

The wide class of nonextendible positive maps inC ^*-algebras [1, 3] is studied. An example is given showing that the set of nonextendible positive maps betweenC ^*-algebras and is not closed inL( ) in the weak topology.     

Laser-Rf double-resonance studies of the hyperfine structure of metastable atomic states of55Mn

The hyperfine structure (hfs) of the metastable atomic states 3d⁶4s⁶ D _{1/2, 3/2, 5/2, 7/2, 9/2} of⁵⁵Mn was measured using theABMR- LIRF method (atomicbeammagneticresonance, detected bylaserinducedresonancefluorescence). The hfs constantsA andB, corrected for second order hfs perturbations, could be derived from these measurements. The theoretical interpretation of these correctedA- andB-factors was performed in the intermediate coupling scheme taking into account the configurations 3d ⁵4s ², 3d ⁶4s and 3d ⁷. Examining the influence of the composition of the eigenvectors on the hfs parameters \(\left\langle {r^{ - 3} } \right\rangle ^{k_s k_l } \) it was found, that for the configuration 3d ⁶4s the two-body magnetic interaction should be considered in the calculation of the eigenvectors. Investigating second order electrostatic configuration interactions and relativistic effects and using calculated relativistic correction factors we obtained for the nuclear quadrupole moment of the nucleus⁵⁵Mn a value ofQ=0.33(1) barn, which is not perturbed by a shielding or antishielding Sternheimer factor. The following hfs constants have been obtained: $$\begin{gathered} A\left( {{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 882.056\left( {12} \right)MHz \hfill \\ A\left( {{3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 469.391\left( 7 \right)MHzB\left( {{3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = - 65.091\left( {50} \right)MHz \hfill \\ A\left( {{5 \mathord{\left/ {\vphantom {5 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 436.715\left( 3 \right)MHzB\left( {{5 \mathord{\left/ {\vphantom {5 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = - 46.769\left( {30} \right)MHz \hfill \\ A\left( {{7 \mathord{\left/ {\vphantom {7 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 458.930\left( 3 \right)MHzB\left( {{7 \mathord{\left/ {\vphantom {7 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 21.701\left( {40} \right)MHz \hfill \\ A\left( {{9 \mathord{\left/ {\vphantom {9 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 510.308\left( 8 \right)MHzB\left( {{9 \mathord{\left/ {\vphantom {9 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 132.200\left( {120} \right)MHz \hfill \\ \end{gathered} $$      

Einfluß der Vibration auf die Geschwindigkeit der Saccharosekristallisation

The influence of the vibration amplitude on the crystallization rate of saccharose with constant vibration frequency of 100 Hz is investigated. Supersaturation was low (1.05), temperatures 40, 60, and 80 °C. Increase of amplitudes 1 up to 4 mm positively influenced the crystallization rate (by 45%) in solutions of high purity and low temperature. At 80 °C the increase lay at about 20%. With low purity solutions no acceleration was observed. – The apparatus and methods of measuring are described.     

Cornelian Cherry (Cornus mas L.) Extracts Exert Cytotoxicity in Two Selected Melanoma Cell Lines—A Factorial Analysis of Time-Dependent Alterations in Values Obtained with SRB and MTT Assays

Despite the fact that phytochemicals of Cornaceae species have long been discussed as possible auxiliary agents in contemporary treatment, the insights on their properties remain relatively scarce. This study focuses on Cornus mas L. (Cornelian cherry), the extracts of which are reported to exert a pleiotropic effect shown in both in vivo and in vitro studies. This study aimed to explore the cytotoxic effect of extracts from fruits of red (Cornus mas L. ‘Podolski’) and yellow (Cornus mas L. ‘Yantarnyi’ and ‘Flava’) Cornelian cherries on two melanoma cell lines (A375 and MeWo). The extracts were characterized in the context of the concentration of bioactive compounds of antioxidative properties. Cytotoxicity was investigated with the use of the following two assays: SRB and MTT. An additional, alternative protocol for the SRB assay was used in this study so as to account for possible bias. Cytotoxicity was assessed as a difference in the whole time series of cell viability, instead of analyzing differences in raw values (often found in the literature). Both extracts from Cornus mas L. induced cytotoxicity in both A375 and MeWo cell lines, although the response of these cells was different. Moreover, based on this study, there is no evidence for claiming a different magnitude of cytotoxicity between these two extracts.     

Novel C60 Fullerenol-Gentamicin Conjugate–Physicochemical Characterization and Evaluation of Antibacterial and Cytotoxic Properties

This study aimed to develop, characterize, and evaluate antibacterial and cytotoxic properties of novel fullerene derivative composed of C₆₀ fullerenol and standard aminoglycoside antibiotic–gentamicin (C₆₀ fullerenol-gentamicin conjugate). The successful introduction of gentamicin to fullerenol was confirmed by X-ray photoelectron spectroscopy which together with thermogravimetric and spectroscopic analysis revealing the formula of the composition as C₆₀(OH)₁₂(GLYMO)₁₁(Gentamicin)_0.8. The dynamic light scattering (DLS) revealed that conjugate possessed ability to form agglomerates in water (size around 115 nm), while Zeta potential measurements demonstrated that such agglomerates possessed neutral character. In vitro biological assays indicated that obtained C₆₀ fullerenol-gentamicin conjugate possessed the same antibacterial activity as standard gentamicin against Staphylococcus aureus, Staphylococcus epidermidis, Pseudomonas aeruginosa, and Escherichia coli, which proves that combination of fullerenol with gentamicin does not cause the loss of antibacterial activity of antibiotic. Moreover, cytotoxicity assessment demonstrated that obtained fullerenol-gentamicin derivative did not decrease viability of normal human fibroblasts (model eukaryotic cells) compared to control fibroblasts. Thus, taking into account all of the results, it can be stated that this research presents effective method to fabricate C₆₀ fullerenol-gentamicin conjugate and proves that such derivative possesses desired antibacterial properties without unfavorable cytotoxic effects towards eukaryotic cells in vitro. These promising preliminary results indicate that obtained C₆₀ fullerenol-gentamicin conjugate could have biomedical potential. It may be presumed that obtained fullerenol may be used as an effective carrier for antibiotic, and developed fullerenol-gentamicin conjugate may be apply locally (i.e., at the wound site). Moreover, in future we will evaluate possibility of its applications in inter alia tissue engineering, namely as a component of wound dressings and implantable biomaterials.