首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3751篇
  免费   90篇
  国内免费   33篇
化学   2163篇
晶体学   63篇
力学   91篇
数学   789篇
物理学   768篇
  2022年   46篇
  2021年   71篇
  2020年   38篇
  2019年   48篇
  2018年   56篇
  2017年   64篇
  2016年   131篇
  2015年   108篇
  2014年   129篇
  2013年   295篇
  2012年   169篇
  2011年   217篇
  2010年   138篇
  2009年   155篇
  2008年   200篇
  2007年   179篇
  2006年   183篇
  2005年   142篇
  2004年   156篇
  2003年   110篇
  2002年   112篇
  2001年   56篇
  2000年   50篇
  1999年   47篇
  1998年   43篇
  1997年   60篇
  1996年   60篇
  1995年   37篇
  1994年   39篇
  1993年   43篇
  1992年   30篇
  1991年   38篇
  1990年   39篇
  1989年   40篇
  1988年   23篇
  1987年   33篇
  1986年   26篇
  1985年   43篇
  1984年   61篇
  1983年   31篇
  1982年   33篇
  1981年   36篇
  1980年   33篇
  1979年   29篇
  1978年   29篇
  1977年   39篇
  1975年   20篇
  1974年   16篇
  1973年   13篇
  1972年   16篇
排序方式: 共有3874条查询结果,搜索用时 15 毫秒
11.
12.
In this Note we first introduce the concept of pullback asymptotic compactness. Next, we establish a result ensuring the existence of a pullback attractor for a non-autonomous dynamical system under the general assumptions of pullback asymptotic compactness and the existence of a pullback absorbing family of sets. Finally, we prove the existence of a pullback attractor for a non-autonomous 2D Navier–Stokes model in an unbounded domain, a case in which the theory of uniform attractors does not work since the non-autonomous term is quite general. To cite this article: T. Caraballo et al., C. R. Acad. Sci. Paris, Ser. I 342 (2006).  相似文献   
13.
14.
We use a newly introduced concept of neocompactness to study problems from metric fixed point theory. In particular, we give a sufficient condition for a superreflexive Banach space X to have the fixed point property and obtain shorter proofs of some well-known results in that theory.  相似文献   
15.
Microspheres of Li2TiO3 were fabricated by a classical, inorganic sol-gel process from commercially available TiCl4. Elaborated process consists of the following main steps: (1) dissolving of TiCl4 in concentrated aqueous HCl and addition of LiOH; (2) formation of sol emulsion in 2-ethylhexanol-1 containing the surfactant SPAN-80 (EH); (3) gelation of emulsion drops by extraction of water with partially dehydrated EH; (4) impregnation of gel to Li:Ti molar ratio MR = 2; (5) thermal treatment at 1200°C in order to receive chloride free product. This temperature can be significantly lowered (to 750°C) by dechlorination starting solution TiCl4 by chemical treatment of the with nitric acid to form of nitrate-stabilized titania sols. Tritium release from sol-gel made Li2TiO3 microspheres were found very close to that observed for other traditional materials, however for the first sample process starts slightly earlier.  相似文献   
16.
The competitiveness of the combination and disproportionation reactions between a 1‐phenylpropyl radical, standing for a growing polystyryl macroradical, and a 2,2,6,6‐tetramethyl‐1‐piperidinyloxy (TEMPO) radical in the nitroxide‐mediated free‐radical polymerization of styrene was quantitatively evaluated by the study of the transition geometry and the potential energy profiles for the competing reactions with the use of quantum‐mechanical calculations at the density functional theory (DFT) UB3‐LYP/6‐311+G(3df, 2p)//(unrestricted) Austin Model 1 level of theory. The search for transition geometries resulted in six and two transition structures for the radical combination and disproportionation reactions, respectively. The former transition structures, mainly differing in the out‐of‐plane angle of the N? O bond in the transition structure TEMPO molecule, were correlated with the activation energy, which was determined to be in the range of 8.4–19.4 kcal mol?1 from a single‐point calculation at the DFT UB3‐LYP/6‐311+G(3df, 2p)//unrestricted Austin Model 1 level. The calculated activation energy for the disproportionation reaction was less favorable by a value of more than 30 kcal mol?1 in comparison with that for the combination reaction. The approximate barrier difference for the TEMPO addition and disproportionation reaction was slightly smaller for the styrene polymerization system than for the acrylonitrile polymerization system, thus indicating that a β‐proton abstraction through a TEMPO radical from the polymer backbone could diminish control over the radical polymerization of styrene with the nitroxide even more than in the latter system. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 232–241, 2007  相似文献   
17.
We prove that a large class of self-injective algebras of tilted type is invariant under stable equivalences of module categories.

  相似文献   

18.
19.
We study properties of ergodic projection forquantum dynamical semigroups on W *-algebras. Inparticular, we describe the normal and singular parts ofthis projection, characterize normal invariantfunctionals, and derive some conclusions for ergodicsemigroups.  相似文献   
20.
The oxygen induced faceting of the macroscopic W[1 1 1] tip has been studied for oxygen exposures in the range 0.5-31 L and annealing temperatures 800-1800 K using the field ion microscopy (FIM) technique. After annealing at temperatures lower than 800 K, higher than 1850 K or for exposures lower than 0.5 L faceting was not observed. For exposures 0.5-1.9 L and annealing temperatures 800-1600 K well developed {1 1 2} facets with sharp edges formed. For exposures higher than 2.0 L edges of the {1 1 2} facets were broadening and disappearing, what has been attributed to the formation of three-dimensional tungsten oxides. The oxides could be easily removed by annealing the tip at 1700 K, what leads to formation of sharp facet edges. On the basis of these results a modified procedure of the ultrasharp tip fabrication has been proposed.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号