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21.
Transport in Porous Media - A macroscopic model that accounts for the effect of momentum dispersion on flows in porous media is proposed. The model is based on the pore scale prevalence hypothesis... 相似文献
22.
Natalia P. Kuzmina Dmitry M. Tsymbarenko Igor E. Korsakov Zoya A. Starikova Kostantin A. Lysenko Olga V. Boytsova Andrey V. Mironov Irina P. Malkerova Andrey S. Alikhanyan 《Polyhedron》2008
The novel mixed ligand complexes [Ca(hfa)2(diglyme)(H2O)] (I), [Sr(hfa)2(diglyme)(H2O)] (II) and [Ba(hfa)2(diglyme)2] (III) (Hhfa = 1,1,1,5,5,5-hexafluoropentane-2,4-dione, diglyme = 2,5,8-trioxanonane) were synthesized by the reactions of the alkaline earth element (AEE) carbonates in n-hexane with a mixture of Hhfa and diglyme, and they were characterized by elemental analysis, 1H and 13C NMR, and FTIR spectroscopy. The crystal structures of I–III, consisting of mononuclear isolated molecules, have been determined. The thermal behavior and composition of the vapor phase have been studied for I–III by thermal analysis at low pressure and mass spectrometry using a Knudsen cell. The stability of the mixed ligand complexes [M(hfa)2(diglyme)n] to the removal of diglyme molecules under heating decreases in the row I > II ≈ III, and only I evaporates as the mixed ligand complex after water removal. 相似文献
23.
Zhenguang Wang Chuanchuan Zhang Henggang Wang Yuan Xiong Xinjian Yang Yu‐e Shi Andrey L. Rogach 《Angewandte Chemie (International ed. in English)》2020,59(25):9997-10002
Sulfur is not normally considered a light‐emitting material, even though there have been reports of a dim luminescence of this compound in the blue‐to‐green spectral region. Now, it is shown how to make red‐emissive sulfur by a two‐step oxidation approach using elemental sulfur and Na2S as starting materials, with a high photoluminescence quantum yield of 7.2 %. Polysulfide is formed first and is partially transformed into Na2S2O3 in the first step, and then turns back to elemental S in the second step. The elevated temperature and relatively oxygen‐deficient environment during the second step transforms Na2S2O3 into Na2SO3 incorporated with oxygen vacancies, thus resulting in the formation of a solid‐state powder consisting of elemental S embedded in Na2SO3. It shows aggregation‐induced emission properties, attributed to the influence of oxygen vacancies on the emission dynamics of sulfur by providing additional lower energy states that facilitate the radiative relaxation of excitons. 相似文献
24.
Panel‐based stratified cluster sampling and analysis for photovoltaic outdoor measurements 下载免费PDF全文
We study a stratified multisite cluster‐sampling panel time series approach in order to analyse and evaluate the quality and reliability of produced items, motivated by the problem to sample and analyse multisite outdoor measurements from photovoltaic systems. The specific stratified sampling in spatial clusters reduces sampling costs and allows for heterogeneity as well as for the analysis of spatial correlations due to defects and damages that tend to occur in clusters. The analysis is based on weighted least squares using data‐dependent weights. We show that this does not affect consistency and asymptotic normality of the least squares estimator under the proposed sampling design under general conditions. The estimation of the relevant variance–covariance matrices is discussed in detail for various models including nested designs and random effects. The strata corresponding to damages or manufacturers are modelled via a quality feature by means of a threshold approach. The analysis of outdoor electroluminescence images shows that spatial correlations and local clusters may arise in such photovoltaic data. Further, relevant statistics such as the mean pixel intensity cannot be assumed to follow a Gaussian law. We investigate the proposed inferential tools in detail by simulations in order to assess the influence of spatial cluster correlations and serial correlations on the test's size and power. ©2016 The Authors. Applied Stochastic Models in Business and Industry published by John Wiley & Sons, Ltd. 相似文献
25.
A quantitative analysis of the BER penalty due to deviations from the optimal decision level in systems employing optical regeneration is presented. Applying extensive Multicanonical Monte Carlo modelling we study the accumulation of BER with propagation and compare different analytical approximations of the regenerator nonlinear transfer function. 相似文献
26.
We show that pQCD factorization incorporated with pre-hadronization energy-loss effect naturally leads to flatness of the nuclear modification factor RAA for produced hadrons at high transverse momentum pT. We consider two possible scenarios for the pre-hadronization: In scenario 1, the produced gluon propagates through dense QCD medium and loses energy. In scenario 2, all gluons first decay to quark–antiquark pairs and then each pair loses energy as propagating through the medium. We show that the estimates of the energy-loss in these two different models lead to very close values and is able to explain the suppression of high-pT hadrons in nucleus–nucleus collisions at RHIC. We show that the onset of the flatness of RAA for the produced hadron in central collisions at midrapidity is about pT≈15 and 25 GeV at RHIC and the LHC energies, respectively. We show that the smallness (RAA<0.5 ) and the high-pT flatness of RAA obtained from the kT factorization supplemented with the Balitsky–Kovchegov (BK) equation is rather generic and it does not strongly depend on the details of the BK solutions. We show that energy-loss effect reduces the nuclear modification factor obtained from the kT factorization about 30–50% at moderate pT. 相似文献
27.
Andrey V. Kulizhsky 《Waves in Random and Complex Media》2017,27(2):289-307
A uniform integral representation for the wave field propagating through the statistically homogeneous multi-scale medium was obtained. It is shown that the considered expression for the field contains the limiting cases for both the Born’s approximation for the single-scattered field and a phase approximation of geometric optics method. Hybrid method formulae for calculation of the fluctuation field, taking into account the effect of backscattering enhancement can be obtained from the investigated integral representation, provided that the spectrum of inhomogeneities can be represented as a sum of two uncorrelated components: small-scale and large-scale. The paper contains the numerical simulation results of the effect of average intensity enhancement of the backscattered field in the medium containing both large- and small-scale irregularities. Unlike the hybrid method of calculation, the proposed approach does not require explicit separation of the inhomogeneities spectrum into two uncorrelated components and allows investigating the effect of the average intensity enhancement of the backscattered field in a more general situation. In particular, numerical calculations have shown that the effect of enhancement of the backscattered signal may occur in the study of the high-latitude ionosphere by method of incoherent scattering of radio waves. 相似文献
28.
Andrey V. Kuznetsov 《Central European Journal of Physics》2011,9(1):146-156
This paper formulates a four kinetic state model for fast axonal transport. The paper further develops the Smith-Simmons model
that is based on equations governing intracellular molecular-motor-assisted transport; these equations are extended by considering
four rather than three kinetic states for organelles. The model considers plus-end and minus-end-oriented organelles that
can be either free (suspended in the cytosol) or attached to microtubules (MTs) (in the latter case organelles are transported
by molecular motors). The paper then develops a method for uncoupling differential equations of the proposed model. A perturbation
solution of this problem is obtained. The effect of transition between plus-end-oriented and minus-end oriented organelles
is discussed. The accuracy of the obtained perturbation solution is evaluated by comparing the zero-order and the first-order
results with a high-accuracy numerical solution. 相似文献
29.
Degenerate band edges (DBEs) of a photonic bandgap have the form (ω-ω(D)) ∝k(2m) for integers m>1, with ω(D) the frequency at the band edge. We show theoretically that DBEs lead to efficient coupling into slow-light modes without a transition region, and that the field strength in the slow mode can far exceed that in the incoming medium. A method is proposed to create a DBE of arbitrary order m by coupling m optical modes with multiple superimposed gratings. The enhanced coupling near a DBE occurs because of the presence of one or more evanescent modes, which are absent at conventional quadratic band edges. We furthermore show that the coupling can be increased or suppressed by varying the number of excited evanescent waves. 相似文献
30.